期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 85, 页码 12590-12593出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07083c
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资金
- National Institutes of Health [EB 016062]
- National Science Foundation [CHE-1465067]
- Wayne State University
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1465067] Funding Source: National Science Foundation
Photochemical control over irreversible inhibition was shown using Ru(II)-caged inhibitors of cathepsin L. Levels of control were dependent on where the Ru(II) complex was attached to the organic inhibitor, reaching > 10 : 1 with optimal placement. A new strategy for photo-releasing Ru(II) fragments from inhibitor-enzyme conjugates is also reported.
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