期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 77, 页码 11547-11550出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05128f
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资金
- National Natural Science Foundation of China [21402005, 21372025]
- National Basic Research Program of China [2013CB328905]
- Fundamental Research Funds for the Central Universities [buctrc201402]
- Public Hatching Platform for Recruited Talents of Beijing University of Chemical Technology
Cationic rearrangement reactions usually follow Markovnikov's rule to give more substituted carbocations as stable intermediates. During our study on sulfur mediated allylic C-H amination of olefins, very rare cases of anti-Markovnikov rearrangement from secondary carbocations toward primary carbocations or primary triflates were observed.
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