期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 99, 页码 14258-14261出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08240h
关键词
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资金
- U.S. National Science Foundation [CHE-1352437, DMR-1055762, CHE-1361178]
- James D. Morrison Early Career Award
- Donors of the American Chemical Society Petroleum Research Fund [54228-ND1]
The CO2-reduction activity of two Re(I)-NHC complexes is investigated employing a silicon nanowire photoelectrode to drive catalysis. Photovoltages greater than 440 mV are observed along with excellent selectivity towards CO over H-2 formation. The observed selectivity towards CO production correlates with strong adsorption of the catalysts on the photoelectrode surface.
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