期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 23, 页码 4329-4332出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00133e
关键词
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资金
- SERB, Department of Science and Technology
- UGC, New Delhi
- NIPER S. A. S. Nagar
A palladium-catalyzed regioselective C-2 arylation of 7-azaindoles, indoles, and pyrroles with arenes has been developed. This study unveils that a critical substrate dependent acid concentration is essential for achieving exclusive C-2 selectivity as well as mono-arylation in pyrroles. Incongruent to the literature, the protocol uses a reduced volume (at least 5 times) of arenes for workable access to C-2 arylated heterocycles.
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