4.7 Article

Competing antiferromagnetic orders in the double perovskite Mn2MnReO6 (Mn3ReO6)

期刊

CHEMICAL COMMUNICATIONS
卷 52, 期 32, 页码 5558-5560

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01290f

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资金

  1. EPSRC
  2. STFC
  3. Royal Society
  4. Engineering and Physical Sciences Research Council [EP/G030332/1, EP/C528506/1, EP/J00099X/1, EP/K014331/1, EP/G048584/1] Funding Source: researchfish
  5. EPSRC [EP/G048584/1, EP/G030332/1, EP/J00099X/1, EP/C528506/1, EP/K014331/1] Funding Source: UKRI

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The new double perovskite Mn2MnReO6 has been synthesised at high pressure. Mn2+ and Re6+ spins order antiferromagnetically through two successive transitions that are coupled by magnetoelastic effects, as order of the Mn spins at 109 K leads to lattice distortions that reduce frustration prompting Re order at 99 K.

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