期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 83, 页码 12314-12317出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05304a
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资金
- Board of Research in Nuclear Sciences, Department of Atomic Energy, New Delhi [35/14/01/2015-BRNS/10110]
- Council of Scientific and Industrial Research
The first thiourea catalysed asymmetric [3+2] cycloaddition reaction between azomethine imines and malanonitriles was developed. Using this novel synthetic strategy, hybrid molecules containing N,N-bicyclic pyrazolidinones fused with enaminonitriles were synthesized in good yields with excellent enantioselectivities (up to 98% ee).
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