期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 94, 页码 13671-13674出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08191f
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资金
- National Nature Science Foundation of China [21371169, 21603229]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Nature Science Foundation of Fujian Province [2016J01080]
Following the HSAB principle, the cooperative assembly of tetrahedral [Cu4I4(Ina)(4)](4-) metalloligands and 8-connecting [Zr-6(mu(3)-OH)(8)(OH)(8)](8+) building units leads to the first heterometallic cluster- based Zr-MOF (1). The results provide a successful strategy for rational design of heterometallic cluster- based Zr-MOFs.
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