期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 3, 页码 489-492出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07390a
关键词
-
资金
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21133011, 21373246, 21522309]
A simple iron-catalyzed aerobic oxidative C-C sigma-bond cleavage of ketones has been developed. Readily available and environmentally benign air is used as the oxidant. This reaction avoids the use of noble metal catalysts or specialized oxidants, chemoselectively yielding carbon chain-shortened aldehydes, ketones and 1,2-dicarbonyl compounds without overoxidation.
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