4.7 Article

Formation of colloidal nanocrystal clusters of iron oxide by controlled ligand stripping

期刊

CHEMICAL COMMUNICATIONS
卷 52, 期 1, 页码 128-131

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07348k

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资金

  1. US National Science Foundation [CHE-1308587]
  2. National Natural Science Foundation of China [21271190]
  3. Government of Guangdong Province for Natural Science Foundation [S2012020011113]
  4. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University [2012-01]
  5. China Scholarship Council
  6. Government of Guangdong Province for industry [2012B09000026]

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We report a ligand stripping method for the creation of secondary structures of colloidal nanocrystals. Using iron oxide as an example, we demonstrate that the use of diols as stripping agents allows the controllable removal of the original capping ligands and induces aggregation of nanocrystals into well-defined clusters.

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