期刊
CHEMBIOCHEM
卷 17, 期 18, 页码 1689-1692出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cbic.201600228
关键词
acidity; LMW thiols; mycothiol; redox chemistry; thiol pK(a)
资金
- Leverhulme Trust Research Grant [RPG-2012-506]
- Flanders Institute for Biotechnology (VIB)
- Flanders IWT grant (Agentschap voor Innovatie door Wetenschap en Technologie)
The thiol pK(a) and standard redox potential of mycothiol, the major low-molecular-weight thiol cofactor in the actinomycetes, are reported. The measured standard redox potential reveals substantial discrepancies in one or more of the other previously measured intracellular parameters that are relevant to mycothiol redox biochemistry.
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