期刊
INORGANIC CHEMISTRY
卷 59, 期 7, 页码 4626-4633出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b03733
关键词
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资金
- NSFC [21674014, U1862115, 21690064]
- Fundamental Research Funds for the Central Universities [DUT18GJ201]
A two-state reactivity scenario has been computationally disclosed for dinitrogen activation by a diniobium tetrahydride. Remarkably, it is revealed that alkali metal cations play a crucial role via alkali center dot center dot center dot N coordination interaction, which is capable of decreasing the activation barriers of N-H formation and subsequent H-2 elimination in particular. Furthermore, the effect of various alkali metal cations has also been investigated systematically.
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