期刊
CERAMICS INTERNATIONAL
卷 42, 期 16, 页码 18303-18311出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2016.08.158
关键词
Vacuum sintering; LiFePO4/C; Porous structure; Lithium-ion battery
资金
- National Natural Science Foundation of China [51364021]
- Natural Science Foundation of Yunnan Province [2014FA025]
LiFePO4/C (LFP/C) composite as a cathode material for lithium-ion battery was synthesized by solid-state reaction under vacuum sintering condition (20-5 Pa). The effects of vacuum sintering temperature and time on the phase composition, morphological structure, and electrochemical performance of LFP/C composite were investigated by X-ray diffraction, scanning electron microscopy, galvanostatic charge discharge cycling test, and electrochemical impedance spectroscopy. The synthetic LFP/C composite possessed uniform particle-size distribution with porous architecture upon sintering at 650 degrees C for 12 h and thus exhibited the highest discharge capacity and best cycle performance. The complete decomposition of citric acid at a suitable temperature under vacuum condition resulted in the formation of porous structure. Compared with atmospheric argon sintering, vacuum sintering method led to the formation of porous architecture, the porous sample showed excellent cycle performance with less than 2% capacity loss after 80 cycles at 0.2 C, and reached the discharge specific capacity of 87.6 mAh g(-1) at 10 C rate, these are better than that of atmospheric argon sintering. The LFP/C composite prepared under vacuum sintering also reduced the optimum sintering temperature by nearly 100 degrees C compared with that prepared under atmospheric argon sintering. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据