Article
Chemistry, Physical
Peng Yan, Yi Cheng
Summary: Methane steam reforming is expected to be the dominant method for hydrogen production in the future. The use of a membrane reactor can significantly save energy and achieve process and equipment compactness, especially for decentralized applications. This study focuses on the design of a particle-based packed-bed membrane reactor and investigates its operational window and design challenges through experimental and computational approaches, with a particular emphasis on the scale of the reactor and catalyst activity. The results reveal the optimal operation conditions for maximizing hydrogen flux and identify catalyst activity as the key limiting factor for further process intensification.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Multidisciplinary
Haris Qayyum, Izzat Iqbal Cheema, Mohsin Abdullah, Muhammad Amin, Imtiaz Afzal Khan, Eui-Jong Lee, Kang Hoon Lee
Summary: This study developed a one-dimensional model of an adiabatic packed bed reactor used for chemical looping reforming (CLR) in gPROMS Model Builder 4.1.0 (R). The effects of variations in temperature, pressure, gas mass velocity, nickel oxide concentration, reactor length, and particle diameter on the performance of the CL-SMR process were investigated through thermodynamic and parametric analysis.
FRONTIERS IN CHEMISTRY
(2023)
Article
Thermodynamics
Zhihong Wu, Zhigang Guo, Jian Yang, Qiuwang Wang
Summary: In this study, methane steam reforming in a packed bed reactor integrated with a diverging tube was investigated numerically to improve efficiency. The results showed that the integration of a diverging tube led to a reduction in average temperature, a decrease in pressure drop, and an increase in outlet mass flow. Both flow disturbance and thermal resistance increased as the inclination angle rose. The overall heat transfer coefficient was highest at an inclination angle of 3 degrees, increasing by 9.0% compared to a normal packed bed reactor. The integration of a diverging tube improved hydrogen yield, which increased with the inclination angle. Considering catalyst usage, flow loss, and outlet hydrogen mass flow, the highest efficiency of hydrogen production was achieved at an inclination angle of 3 degrees, increasing by 34.0%.
ENERGY CONVERSION AND MANAGEMENT
(2023)
Article
Thermodynamics
Zhihong Wu, Zhigang Guo, Jian Yang, Qiuwang Wang
Summary: In this study, the effects of different pitch of internal helical heat fins on methane steam reforming in a packed bed reactor were investigated. It was found that larger pitch increased the outlet mass flow and velocity disturbance by 9.5% and 382.3% respectively, but also brought higher flow resistance. The internal helical heat fins improved the fluid temperature and reduced the thermal resistance, with a temperature increase of 19.2 K and a thermal resistance decrease of 43.1% compared to the normal packed bed. The highest efficiency was achieved when the pitch was 120 mm, with an increase of 42.3%. Although the internal helical heat fins increased the reactor cost due to structural complexity, the total cost decreased. The lowest total cost was achieved when the pitch was 120 mm, with a decrease of 24.6% to about 1.6 USD/kg.
Article
Engineering, Environmental
M. Mateen Shahid, Syed Zaheer Abbas, Fahad Maqbool, Sergio Ramirez-Solis, Valerie Dupont, Tariq Mahmud
Summary: The study investigated the impact of three different types of sorbents on sorption-enhanced steam methane reforming (SE-SMR) process and found the optimum operating conditions. CaO sorbent showed the best performance at 900K and 3 bar, with 82% CH4 conversion and 85% H-2 purity; LZC and HTC sorbents performed well at 773K and 5 bar.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Somasree Roychowdhury, Mohamed Mukthar Ali, Swati Dhua, T. Sundararajan, G. Ranga Rao
Summary: This study focuses on the dual performance of Rh/CeO2/g-Al2O3 catalyst in steam reforming of ethanol (SRE) and thermochemical water splitting (TCWS). The catalyst shows optimal temperature range for high hydrogen production and higher selectivity towards CO and CH4 at low temperatures, and it is also active for TCWS at relatively low temperatures. The proposed reaction pathways for both SRE and TCWS on this catalyst have been presented in the study.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Ja-Ryoung Han, Jong Min Lee
Summary: This study proposes a multi-objective optimization approach to design a steam methane reforming (SMR) reactor and maximize the efficiency of the hydrogen production process. Only 50 iterations were performed, identifying three Pareto optimal designs with significant reactor size reductions and slight variations in process efficiency compared to the reference case. The results offer practical insights for planning on-site distributed hydrogen production systems and demonstrate the possibility of increasing overall process efficiency with a reduced reactor size.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Jimin Zhu, Xiaoti Cui, Samuel Simon Araya
Summary: This study conducts a numerical simulation of methanol steam reforming reactions in a commercial packed-bed reactor with CuO/ZnO/Al2O3 catalyst. The results show that the inlet temperature of burner gas and tube diameter have significant effects on the temperature distribution and the formation of hot spots in the reformer tubes.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Jingyu Wang, Shangshang Wei, Qiuwang Wang, Bengt Sunden
Summary: This paper investigates the transport phenomena in an industrial-scale steam methane reforming reactor through transient numerical simulations and emphasizes the importance of temperature distribution and mass flow rate in hydrogen production. The dynamic matrix control (DMC) scheme is proposed to manipulate the outlet hydrogen mole fraction, showing a reduction in overshoot and minimal input variable changes. The study demonstrates the potential of combining CFD modeling with controller design for real applications.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Environmental Sciences
Chalempol Khajonvittayakul, Vut Tongnan, Netiwat Namo, Chutamat Phonbubpha, Navadol Laosiripojana, Matthew Hartley, Unalome Wetwatana Hartley
Summary: In this study, the effects of NiO on different types of supports, CZO and LSCF, were investigated. It was found that 40%Ni-CZO (x = 0.9) showed slightly better catalytic performance compared to 40%Ni-LSCF, likely due to their equal number of active sites and smaller crystallite size. The catalyst with the best performance was 5%Ni-CZO (x = 0.9), achieving high toluene conversion, H-2 yield, CO selectivity, and CO2 selectivity at the optimum reaction temperature of 700 degrees C.
Article
Chemistry, Physical
Xu Qingli, Zhang Zhengdong, Liao Lifang, Lan Ping, Wang Rui, Chen Shoutao, Li Pize, Zhang Chenyang
Summary: The study found that temperature, space velocity, and water-to-carbon ratio play a crucial role in affecting hydrogen yield and carbon conversion during glycerol steam reforming for hydrogen production. The utilization of a two-stage fixed-bed catalytic reaction system can increase hydrogen yield and carbon conversion compared to a single-stage fixed-bed reactor, while also extending the life of the Nickel-based catalyst.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Engineering, Environmental
Valeria Tacchino, Paola Costamagna, Silvia Rosellini, Valter Mantelli, Alberto Servida
Summary: The multi-scale model integrates microscopic, mesoscopic, and macroscopic levels for a comprehensive modeling of a steam methane reforming reactor. It allows for detailed study of phenomena inside the reactor, provides a foundation for fault detection and control purposes.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Chien-Hung Chen, Ching-Tsung Yu
Summary: The study investigated the effect of regeneration conditions on cyclic sorption-enhanced steam reforming of ethanol using columnar Ni-Ca catalysts in a fixed-bed reactor. Results showed that the regeneration temperature significantly impacted both the CO2 desorption rate and the durability of the CaO sorbent, while the type of purge gas had negligible effect on the CO2 capture performance of the Ni-Ca catalyst. Regeneration with air purging led to coke decomposition and a slight decline in the activity of the Ni catalyst due to cyclic Ni redox.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Fahad Maqbool, Syed Z. Abbas, Sergio Ramirez-Solis, Valerie Dupont, Tariq Mahmud
Summary: This study derived kinetic rates for 12 commonly used reforming catalysts based on conversion data obtained from literature, and studied the effects of variables such as temperature, pressure, S/C ratio, and G(s) on the performance of the SMR process. A comparative study was performed for the 12 catalysts, revealing that the choice of catalyst should depend on the operating conditions.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Energy & Fuels
Pouya Barnoon, Davood Toghraie, Babak Mehmandoust, Mohammad Ali Fazilati, S. Ali Eftekhari
Summary: This study investigates a steam reactor powered by propane fuel in proton exchange membrane fuel cells, and examines the control of reaction rate by velocity and temperature fields within the reformer. It is found that the reaction rate can be adjusted by the velocity and temperatures of the hot gases, achieving complete propane consumption at a temperature of 900 K.
Article
Engineering, Chemical
Bhanu Vardhan Reddy Kuncharam, Benjamin A. Wilhite
Article
Energy & Fuels
Shalini Damodharan, Bhanu Vardhan Reddy Kuncharam, Benjamin A. Wilhite
Article
Engineering, Chemical
Daejin Kim, David Donohue, Bhanu Kuncharam, Christine Duval, Benjamin A. Wilhite
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2010)
Review
Chemistry, Physical
S. Nirmal Kumar, Srinivas Appari, Bhanu Vardhan Reddy Kuncharam
Summary: This paper reviews literature on developments in sulfur-resistant systems and discusses the basics of sulfur poisoning mechanisms and a framework of sulfur tolerance methodologies in syngas production.
CATALYSIS SURVEYS FROM ASIA
(2021)
Article
Cell Biology
Yash T. Katakia, Niyati P. Thakkar, Sumukh Thakar, Ashima Sakhuja, Raghav Goyal, Harshita Sharma, Rakshita Dave, Ayushi Mandloi, Sayan Basu, Ishan Nigam, Bhanu V. R. Kuncharam, Shibasish Chowdhury, Syamantak Majumder
Summary: The research suggests that dynamic chromatin modifications may trigger inflammatory and apoptotic responses in endothelial cells, and epigenetic reprogramming could potentially enhance outcomes in cardiovascular diseases associated with endothelial inflammation.
JOURNAL OF CELLULAR PHYSIOLOGY
(2022)
Review
Biotechnology & Applied Microbiology
Priya Tanvidkar, Srinivas Appari, Bhanu Vardhan Reddy Kuncharam
Summary: The use of Mixed Matrix Membranes (MMMs) for CO2/CH4 separation, which disperses inorganic fillers in the polymer matrix, offers a new approach to improving separation performance but faces challenges such as uneven filler dispersion and strong interaction between filler and polymer.
REVIEWS IN ENVIRONMENTAL SCIENCE AND BIO-TECHNOLOGY
(2022)
Article
Polymer Science
Priya Tanvidkar, Aditya Jonnalagedda, Bhanu Vardhan Reddy Kuncharam
Summary: In this study, Mixed Matrix Membranes (MMMs) of UiO-66-NH2 nanoparticles dispersed in Cellulose Acetate (CA) were prepared. Detailed characterization and testing revealed that the MMMs have defects-free, voids-free structures with a better filler polymer interface. The MMMs showed improved CO2 permeability while retaining the CO2/CH4 selectivity. Among them, the 10 wt.% UiO-66-NH2/CA MMM exhibited the best gas separation performance.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Biology
Yash T. Katakia, Satyadevan Kanduri, Ritobrata Bhattacharyya, Srinandini Ramanathan, Ishan Nigam, Bhanu Vardhan Reddy Kuncharam, Syamantak Majumder
Summary: The angle of blood vessel bifurcation is an important determinant of atherosclerosis and endothelial dysfunction, as it can alter hemodynamics and impact endothelial structure and function.
COMMUNICATIONS BIOLOGY
(2022)
Article
Environmental Sciences
Priya Tanvidkar, Aditya Jonnalagedda, Bhanu Vardhan Reddy Kuncharam
Summary: In this study, biodegradable cellulose acetate (CA) based mixed matrix membranes (MMMs) with varying weight percentages (2-20 wt.%) of ZIF-8 were tested for CO2 separation from a model biogas mixture. MMMs with 5% and 10% ZIF-8 content showed the best performance, with CO2 permeabilities of 9.65 Barrer and 9.5 Barrer, approximately two times higher than pure CA, and CO2/CH4 selectivities of 10.37 and 15.3.
ENVIRONMENTAL TECHNOLOGY
(2023)
Article
Engineering, Environmental
Priya Tanvidkar, Bharat Nayak, Bhanu Vardhan Reddy Kuncharam
Summary: Biogas upgradation is important for improving its energy value and reducing corrosion. Membrane-based CO2 separation, particularly using mixed matrix membranes (MMMs), is explored to enhance CO2 separation in this study. The dual filler MMMs prepared with acid-functionalized multi-walled carbon nano-tubes (f-MWCNTs) and amine-functionalized metal-organic framework (UiO-66-NH2) showed superior gas separation performance compared to the base polymer and single filler MMMs. The CO2 permeability and CO2/CH4 selectivity of 0.01wt% f-MWCNTs@10wt%UiO-66-NH2/CA MMMs were significantly higher than those of other membranes. The acid-functionalized MWCNTs-based dual filler MMMs exhibited better performance compared to the non-functionalized MWCNTs-based MMMs.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2023)
Article
Polymer Science
Aditya Jonnalagedda, Bhanu Vardhan Reddy Kuncharam
Summary: This study investigates the preparation and performance of mixed matrix membranes (MMMs) in membrane separation. The amine functionalization of ZIF-8 is explored for enhanced CO2 gas permeation without sacrificing CO2/CH4 selectivity. The experimental results show that the MMMs modified with 10% ZIF-8 demonstrate the highest CO2 permeability, while those modified with 15% NH2-ZIF-8 exhibit the highest CO2/CH4 selectivity.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Engineering, Environmental
Suryaprakash Shailendrakumar Shukla, Ramakrishna Chava, Srinivas Appari, A. Bahurudeen, Bhanu Vardhan Reddy Kuncharam
Summary: This paper provides a comprehensive review of the thermochemical conversion of rice husk into value-added products, including the use of various techniques such as gasification, slow pyrolysis, and fast pyrolysis. The paper also discusses the utilization of rice husk ash in construction materials and soil remediation.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Proceedings Paper
Materials Science, Multidisciplinary
Neha Jadhav, S. Nirmal Kumar, Priya S. Tanvidkar, Bhanu Vardhan Reddy Kuncharam
MATERIALS TODAY-PROCEEDINGS
(2020)
Correction
Chemistry, Applied
Jia Liu, Juntong Dong, Xiaodan Li, Teng Xu, Zhenguo Li, Jeffrey Dankwa Ampah, Mubasher Ikram, Shihai Zhang, Chao Jin, Zhenlong Geng, Tianyun Sun, Haifeng Liu
FUEL PROCESSING TECHNOLOGY
(2024)
Article
Chemistry, Applied
Seba Alareeqi, Daniel Bahamon, Kyriaki Polychronopoulou, Lourdes F. Vega
Summary: This study explores the potential application of single-atom-alloy (SAA) catalysts in bio-oils hydrodeoxygenation refining using density functional theory (DFT) and microkinetic modeling. It establishes the relationships between stability, adsorptive properties, and activity structures for bio-oil derivatives, providing guidance for the synthesis of cost-effective SAA combinations.
FUEL PROCESSING TECHNOLOGY
(2024)
Article
Chemistry, Applied
Bin Hu, Wen -Ming Zhang, Xue-Wen Guo, Ji Liu, Xiao Yang, Qiang Lu
Summary: This study explored the pyrolysis behaviors and mechanisms of different monosaccharides, including arabinose, galactose, galacturonic acid, and glucuronic acid. The roles of structural differences in these monosaccharides were analyzed, and it was found that glucuronic acid undergoes a special C-C bond breaking reaction during pyrolysis. The findings provide a deep understanding of the pyrolysis chemistry of hemicellulose and the role of different branches.
FUEL PROCESSING TECHNOLOGY
(2024)
Review
Chemistry, Applied
Youwei Zhi, Donghai Xu, Guanyu Jiang, Wanpeng Yang, Zhilin Chen, Peigao Duan, Jie Zhang
Summary: Hydrothermal carbonization (HTC) is an effective method for the harmless disposal of municipal sludge (MS) and offers potential applications for the obtained products. Optimizing reaction conditions, coupling with other waste materials, and combining different processes can improve the performance of HTC. Furthermore, HTC contributes to energy recovery and enhances the quality of life cycle assessment.
FUEL PROCESSING TECHNOLOGY
(2024)
Article
Chemistry, Applied
Jia Wang, Jianchun Jiang, Dongxian Li, Xianzhi Meng, Arthur J. Ragauskas
Summary: This study presents a scalable process for converting holocellulose and cellulosic wastes into advanced oxygen-containing biofuels with high furan, cyclic ketone, and ethanol content. By combining hydropyrolysis and vapor-phase hydrodeoxygenation using Pd/Al2O3 as a catalyst, the researchers achieved high yields and conversions. The integrated process holds great promise for biomass waste conversion into advanced biofuels.
FUEL PROCESSING TECHNOLOGY
(2024)
Article
Chemistry, Applied
Florian Held, Jannis Reusch, Steffen Salenbauch, Christian Hasse
Summary: The accurate prediction and assessment of soot emissions in internal combustion engines are crucial for the development of sustainable powertrains. This study presents a detailed quadrature-based method of moments (QMOM) soot model coupled with a state-of-the-art flow solver for the simulation of gasoline engines. The model accurately describes the entire cause-and-effect chain of soot formation, growth and oxidation. Experimental validation and engine cycle simulations are used to identify the root cause of observed soot formation hotspots.
FUEL PROCESSING TECHNOLOGY
(2024)