期刊
EUROPEAN POLYMER JOURNAL
卷 134, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2020.109805
关键词
Biobased epoxy; High performance; Reconfigurability; Self-deploy; 3D smart structure
资金
- China Postdoctoral Science Foundation [2019M662256]
- National Key Research and Development Program of China [2016YFB1100900]
- STS Project of Fujian-CAS [2018T3011, 2019T3016, 2019T3018]
- Open Project Program of Fujian Universities and Colleges Engineering Research Center of Soft Plastic Packaging Technology for Food
Fabricating biobased reconfigurable high performance epoxy resins for self-deployable 3D smart structures is an interesting issue with great challenge. Herein, a biobased trifunctional epoxy monomer (tris(2-methoxy-4-(oxiran-2-ylmethyl)phenyl) phosphate, TMOPP) was derived from eugenol and cured by 4,4'-dithiodianiline (DTDA) to form the dynamic cross-linked TMOPP/DTDA resin. The integrated properties including thermal, mechanical and flame retardancy of TMOPP/DTDA resin are studied systemically. Compared with commercial epoxy resin (diglycidyl ether of bisphenol A (DGEBA)/DTDA), TMOPP/DTDA resin has higher glass transition temperature (217 degrees C) and tensile strength (95.2 MPa), while these properties are superior to those of biobased dynamic cross-linked epoxy resins reported in literatures. TMOPP/DTDA resin also shows excellent flame retardancy with UL-94 V-0 rating. The trifunctional aromatic structure of TMOPP and the compact cross-linked structure of TMOPP/DTDA resin play a principle role in the outstanding performances. At the same time, permanent shape reconfigurability and self-deployable ability of TMOPP/DTDA resin was exhibited by the transformation from planar film into a 3D rocking chair structure. These results provide a new method to produce biobased reconfigurable high performance epoxy resin in a simple and sustainable way, while expand the application of dynamic cross-linked epoxy resins in self-deployable 3D smart structures.
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