Article
Engineering, Environmental
Calvin He, Boyue Lian, Jinxing Ma, Changyong Zhang, Yuan Wang, Hengliang Mo, T. David Waite
Summary: A novel design for a flow-electrode capacitive deionization system using tubular electrodes was proposed, showing high efficiency in salt removal. Computational fluid dynamics modeling was used to optimize the design by maximizing high potential gradient and high hydraulic flow regions.
Article
Energy & Fuels
Marzena Iwaniszyn, Katarzyna Sindera, Anna Gancarczyk, Bartosz Leszczynski, Mateusz Korpys, Mikolaj Suwak, Andrzej Kolodziej, Przemyslaw J. Jodlowski
Summary: In this study, the flow and transport properties of three raised expanded metal meshes with different mesh sizes were experimentally tested. Empirical equations for the Nusselt number and Fanning friction factor were developed. Simple computational fluid dynamics models were used to simulate the pressure drop and heat transfer coefficients within the meshes. The Performance Efficiency Criterion (PEC) was applied to compare the raised expanded metal meshes with other reactor packings.
Article
Engineering, Environmental
Gustavo Corte Tedesco, Peterson Bueno Moraes
Summary: This study aimed to develop an innovative design of a PC/PEC system through the use of a 3-D honeycomb-type photoanode, computational fluid dynamic simulations, 3D-printing of a polyamide prototype, and hydraulic bench-tests. The results provide insights for the application of photochemical and photoelectrochemical techniques in environmental remediation.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Environmental Sciences
Qian Guo, Chao Lei, Wenqian Chen, Binbin Huang
Summary: This study presents a photoelectrochemical strategy using semiconducting nanoparticles to overcome challenges in current photochemical technology. By forming numerous nanobipolar electrodes, efficient charge separation is achieved, enabling advanced oxidation processes for water remediation with significantly improved activity and photogeneration quantum efficiency. The strategy also demonstrates a wide application range for removing different refractory organic pollutants with strong tolerance for supporting electrolyte.
Article
Environmental Sciences
Juan F. Cisneros, Fabiola Cobos, Manuel Raul Pelaez-Samaniego, Usman Rehman, Ingmar Nopens, Andres Alvarado
Summary: This study evaluated and compared the efficiency of five IDS configurations using CFD simulations, finding that the novel configuration C4 resulted in the highest granulation volume, better promoting granulation in UASB reactors.
Article
Chemistry, Applied
M. Jaramillo-Gutierrez, J. A. Pedraza-Avella, I Gonzalez, E. P. Rivero, M. R. Cruz-Diaz
Summary: The liquid flow pattern in a Tubular Electrochemical Reactor (T-ECR) was evaluated with concentric cylindrical expanded meshes as electrodes and shower sprinkler type inlet/outlet distributors. Theoretical results were found to match experimental curves, aiding in the development of design equations. Incorporating inlet/outlet distributors in a T-ECR significantly improves liquid flow behavior, making it a good alternative for reactor design.
REVISTA MEXICANA DE INGENIERIA QUIMICA
(2022)
Article
Engineering, Multidisciplinary
Orlando Giraldo-Bolivar, Luis Lara-Valencia, Carlos Graciano
Summary: This paper presents an experimental study on the compressive strength of concrete cylinders reinforced with expanded metal meshes. The investigation shows that the orientation of the expanded metal meshes can enhance the compressive strength of the concrete specimens.
Article
Chemistry, Applied
M. I. Jaramillo-Gutierrez, J. S. Velasco-Rueda, J. A. Pedraza-Avella
Summary: The photoelectrocatalytic oxidation of an anionic surfactant in synthetic oilfield wastewater using a S,N-TiO2/Ti electrode was studied. Results showed that at high IOS concentrations, IOS adsorption played a main role, while at low concentrations, both IOS adsorption and H2O adsorption were important for the oxidation process.
TOPICS IN CATALYSIS
(2021)
Article
Engineering, Chemical
Carolina Otero, Adriana Urbina, Eligio P. Rivero, Francisca A. Rodriguez
Summary: Electrodeionization (EDI) is a beneficial technology for desalination of brackish water. This paper presents an experimental study and mathematical modeling of an EDI process, analyzing the current density distribution and its impact on ion removal and performance. The model is capable of describing the effects of concentration and cell voltage changes on current density and desalination rate.
Article
Engineering, Chemical
Fernando F. Rivera, Eligio P. Rivero, Federico Castaneda-Zaldivar
Summary: A comprehensive two-dimensional macroscopic model was described to analyze an electrodialysis system for nitrate removal. The model focuses on quantifying the effects of diffusion and migration on mass transport. The study found that an increase in flow rate does not significantly affect flux values, while the externally applied current is the only experimental parameter with considerable influence.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Jose Angel Barragan, Juan Roberto Aleman Castro, Alejandro Aaron Peregrina-Lucano, Moises Sanchez-Amaya, Eligio P. Rivero, Erika Roxana Larios-Duran
Summary: The study aimed to design and develop an efficient leaching process for recovering copper, silver, and lead from e-waste by conducting fundamental and theoretical thermodynamic analysis and optimizing operation parameters via the response surface methodology (RSM). Thermodynamic predictions were made using Pourbaix diagrams, allowing for the determination of spontaneous leaching reaction conditions. The response surface methodology was then used to develop a semiempirical model for optimizing leaching efficiency by considering stirring speed and solid/liquid ratio.
Article
Engineering, Chemical
Arturo Ortega, Luis F. Arenas, Joep J. H. Pijpers, Diana L. Vicencio, Juan C. Martinez, Francisca A. Rodriguez, Eligio P. Rivero
Summary: Research on flow batteries based on water dissociation and acid-base neutralization reactions at bipolar membranes aims for low-cost and environmentally friendly technology, but high round-trip efficiency remains a challenge. This study investigates critical factors using fundamental models in a laboratory scale acid-base flow battery, incorporating transport mechanisms and modeling charging and discharging processes. Model parameters are well-established, predicting current-potential behavior closely matching experimental data and providing insights for future full-scale modeling of acid-base flow batteries.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Engineering, Environmental
Martin R. Cruz-Diaz, Alejandra Laureano, Francisca A. Rodriguez, Luis F. Arenas, Joep J. H. Pijpers, Eligio P. Rivero
Summary: Manifolds play a critical role in influencing the flow pattern within membrane stacks. Various strategies were employed to predict the residence time distribution (RTD) curves in spacer-filled channels, showing that the division manifold generated experimental RTD curves with multiple peaks. The study highlights the importance of considering the effect of dividing and combining manifolds on the overall RTD curve of electrolytes in membrane channels.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Electrochemistry
Jose Angel Barragan, Martin Tesillo-Perales, Juan Roberto Aleman Castro, Erika Roxana Larios-Duran, Eligio P. Rivero
Summary: This study focuses on the optimization of electrochemical reactors for metal recovery using hydrodynamic and mass transfer models with CFD. A validated 3D model was developed to describe the hydrodynamics of the reactor, and response surface methodology (RSM) was used to optimize the reactor operation. Experimental results showed that the proposed method was effective in recovering metal ions under optimized conditions.
ELECTROCHIMICA ACTA
(2022)
Article
Electrochemistry
Isidro J. Gonzalez-Panzo, Martin R. Cruz-Diaz, Eligio P. Rivero
Summary: Understanding the behavior of bipolar membranes in multi-ion solutions is crucial for their use in acid-base flow batteries. A steady-state model of the bipolar membrane is proposed, considering various factors such as water dissociation, acid-base neutralization reactions, and catalytic activity. Experimental current-voltage curves were used to validate the model. The numerical solution provides a comprehensive view of the conductivity, ion concentration, and potentials across the bipolar membrane.
ELECTROCHIMICA ACTA
(2023)
Article
Electrochemistry
Andres Cortes-Contreras, Erika Roxana Larios-Duran, R. Antano-Lopez, Eligio P. Rivero, Jose Angel Barragan
Summary: The growing e-waste generation exceeds the capacity for proper recycling or disposal. This study proposes a novel approach to recover metal ions in both electrodes simultaneously using electrochemical methods. The process utilizes a leached solution from e-waste with high copper concentration and low content of nickel, iron, silver, and lead. Thermodynamic analysis and experimental validation were conducted to predict and confirm the simultaneous electrochemical process of metal ions. A codeposit of copper-silver with concurrent recovery of lead oxide on the anode was achieved.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Gustavo Aparicio-Mauricio, L. Jimenez-Lima, Eligio P. Rivero, Martin R. Cruz-Diaz
Summary: This study proposes a three-dimensional mathematical model for an alkaline organic redox flow battery, taking into account the influence of inlet and outlet manifolds on battery performance. Simulation results show that the model accurately predicts polarization curves at different states of charge using a specific redox couple. The study also reveals that the inlet manifold causes electrolyte flow maldistribution, which can lead to a shorter battery lifespan and reduced charge-discharge efficiency.
JOURNAL OF POWER SOURCES
(2023)
Article
Electrochemistry
Jose Angel Barragan, Erika Roxana Larios-Duran, Alejandro Aaron Peregrina-Lucano, Eligio P. Rivero
Summary: This work proposes a method for the electrochemical recovery of metal ions from emulated e-waste leached solutions using paired cathodic and anodic reactions. The study successfully achieved the deposition and recovery of copper-silver and lead dioxide. The experimental results showed that the composition of the bimetallic deposit varied with different current densities, while lead dioxide deposition occurred at any current density. The energetic performance of the electrochemical reactor was evaluated using cell voltage, cathode, and anode potential.
ELECTROCHIMICA ACTA
(2023)
Article
Engineering, Chemical
Eligio P. Rivero, Isidro J. Gonzalez-Panzo, Arturo Zavala-Vazquez, Erik Rosado-Tamariz, Rodolfo Munoz-Quezada, Mario R. Diaz-Guillen, Martin R. Cruz-Diaz
Summary: There is a growing interest in using electromembrane processes in sustainable applications. In this study, a free and porous flow model was developed to analyze the fluid dynamics in spacer-filled channels, manifolds, and stacks used in acid base flow batteries. The model closely follows experimental pressure drop results and highlights the significant impact of spacer design on the entrance and exit zones.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Chemistry, Applied
M. Jaramillo-Gutierrez, J. A. Pedraza-Avella, I Gonzalez, E. P. Rivero, M. R. Cruz-Diaz
Summary: The liquid flow pattern in a Tubular Electrochemical Reactor (T-ECR) was evaluated with concentric cylindrical expanded meshes as electrodes and shower sprinkler type inlet/outlet distributors. Theoretical results were found to match experimental curves, aiding in the development of design equations. Incorporating inlet/outlet distributors in a T-ECR significantly improves liquid flow behavior, making it a good alternative for reactor design.
REVISTA MEXICANA DE INGENIERIA QUIMICA
(2022)
Article
Materials Science, Multidisciplinary
J. G. Diaz, J. Leon-Becerra, A. D. Pertuz, O. A. Gonzalez-Estrada, M. I. Jaramillo-Gutierrez
Summary: This study demonstrates the estimation of volumetric fiber content using image processing techniques, which is essential for predicting the mechanical properties of composites. By analyzing images of carbon, Kevlar, and fiberglass fiber bundles, the method successfully separates fibers from matrix to establish accurate Vf values, validating the proposed approach.
MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS
(2021)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)