期刊
CERAMICS INTERNATIONAL
卷 46, 期 12, 页码 20201-20206出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.05.100
关键词
KBNN ceramics; Vacancy defects; Electrical properties; Ferroelectric photovoltaic devices
资金
- National Council of Scientific and Technological Development (CNPq) [303314/2016-8]
- Minas Gerais Research Foundation (FAPEMIG) [PPM-00661-16, APQ-02875-18]
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
- Sao Paulo Research Foundation (FAPESP) [2018/24352-7]
KNbO3-based ferroelectric materials have been largely investigated as a result of many interesting physical properties that make them suitable for designing multifunctional electronic components. In particular, ferroelectric (1-x)KNbO3-xBaNi(1/2)Nb(1/2)O(3-delta) (KBNN) solid solutions have received special attention for optical applications, including for high-performance photovoltaic devices. In this work, KBNN ceramics were produced via conventional solid-state sintering, followed by a comprehensive study of their (micro)structural, electrical and optical properties. The processed data are analyzed and discussed in terms of the effect from structural oxygen-vacancy defects in such materials and from the grain size, in the specific case of the observed electrical response. Overall, the results suggest these perovskite-structured semiconducting ferroelectric oxides as a good alternative for solar cell applications.
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