4.1 Article

Human hair catalyzed selective reduction of nitroarenes to amines

期刊

CANADIAN JOURNAL OF CHEMISTRY
卷 98, 期 5, 页码 244-249

出版社

CANADIAN SCIENCE PUBLISHING
DOI: 10.1139/cjc-2019-0444

关键词

human hair; catalyst; reduction; nitro; amine

资金

  1. Iran National Science Foundation (INSF) [97021804]
  2. Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2013-43446-P, CTQ2014-51912-REDC]
  3. Spanish Ministerio de Economia, Industria y Competitividad, Agencia Estatal de Investigacion (AEI)
  4. Fondo Europeo de Desarrollo Regional (FEDER, EU) [CTQ2016-76782-P, CTQ2016-81797-REDC]
  5. Generalitat Valenciana [PROMETEOII/2014/017]
  6. University of Alicante

向作者/读者索取更多资源

Nowadays, there is great demand to use natural, cheap, and biodegradable materials as catalysts in different organic reactions. In this work, we use human hair as a completely biodegradable, renewable, and available material for the reduction of nitroarenes in aqueous media at 50 degrees C. Using this new catalyst, structurally different aromatic nitro compounds, as well as heterocyclic compounds, are reduced to corresponding amines in high to excellent yields. The presented catalytic system is applicable for large-scale reduction of nitroarenes.

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