期刊
CATALYSIS TODAY
卷 264, 期 -, 页码 152-157出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2015.07.010
关键词
Cu-Beta-Nano; Thioesterificat ion; Heterogeneous catalysis; Good reusability
资金
- National Natural Science Foundation of China [U1463203 and 21476030]
- Natural Science Foundation of Zhejiang Province of China [Z14B060012]
Development of the highly active and stable heterogeneous transition metal catalysts is of great importance in synthetic chemistry. Herein, zeolite Beta nanoparticles assembled Cu catalyst (Cu-Beta-Nano) with high external surface area was directly synthesized, and it exhibits excellent catalytic activity and good recyclability in cross-coupling of aldehydes and disulfides for synthesis of thioesters. The high activity and good recyclability of the Cu-Beta-Nano catalyst should be attributed to the high external surface area of the catalyst and highly dispersed active copper species in the zeolite. (C) 2015 Elsevier B.V. All rights reserved.
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