期刊
CATALYSIS LETTERS
卷 146, 期 7, 页码 1283-1290出版社
SPRINGER
DOI: 10.1007/s10562-016-1751-4
关键词
Cyclohexanone; h-WO3 nanorods; Catalysis; Hydrothermal method
资金
- National Natural Science Foundation of China (NSFC) [91534102, 21176054, 21271058]
- Science and Technology Project of Anhui Province [1501021013]
- Intelligent Manufacturing Institute of Hefei University of Technology [IMICZ2015104]
Cyclohexanone is an important intermediate for the fabrication of synthetic polymers such as Nylon in chemical industry. A green synthesis of cyclohexanone under mild conditions using environmental friendly oxidants and non-precious catalysts is highly desired. Herein, one-dimensional crystalline h-WO3 nanorods have been synthesized via a facile hydrothermal method. The h-WO3 nanorods are assembled by the closely packed and highly aligned thin nanowires with the lengths up to 10 mu m and diameters of about 10 nm, growing along the [001] direction. The h-WO3 nanorods are used as the catalyst for the first time in the selective oxidation of cyclohexanol to cyclohexanone by aqueous hydrogen peroxide. The effective catalysis by h-WO3 nanorods remarkably increases the yield of cyclohexanone from 3.1 to 78.6 %, under the mild conditions (80 A degrees C, ambient pressure). With a high recyclability, the h-WO3 nanorods have shown great potentials in green chemistry for the synthesis of cyclohexanone by the catalytic oxidation of cylohexanol.
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