Nickel‐Catalyzed Cross‐Coupling of Sulfonamides With (Hetero)aryl Chlorides

PhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines

(2019) Joseph Tassone et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Catalyzed Deamination of Primary Sulfonamides: A Platform for Late-Stage Functionalization

(2019) Patrick S. Fier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sulfonamide Synthesis through Electrochemical Oxidative Coupling of Amines and Thiols

(2019) Gabriele Laudadio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of (R)-Boc-2-methylproline via a Memory of Chirality Cyclization. Application to the Synthesis of Veliparib, a Poly(ADP-ribose) Polymerase Inhibitor

(2019) Lawrence Kolaczkowski et al.   JOURNAL OF ORGANIC CHEMISTRY

PAd2-DalPhos Enables the Nickel-Catalyzed C-N Cross-Coupling of Primary Heteroarylamines and (Hetero)aryl Chlorides

(2019) Jillian Clark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfonamide derivatives as multi-target agents for complex diseases

(2019) Sinem Apaydın et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

LiCl-Accelerated Multimetallic Cross-Coupling of Aryl Chlorides with Aryl Triflates

(2019) Liangbin Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemically-Mediated, Nickel-Catalyzed Synthesis of N-(Hetero)aryl Sulfamate Esters

(2019) J. Miles Blackburn et al.   ORGANIC LETTERS

Nickel-Catalyzed C–N Cross-Coupling of Ammonia, (Hetero)anilines, and Indoles with Activated (Hetero)aryl Chlorides Enabled by Ligand Design

(2019) Ryan T. McGuire et al.   ACS Catalysis

Selective Late-Stage Sulfonyl Chloride Formation from Sulfonamides Enabled by Pyry-BF4

(2019) Alejandro Gómez-Palomino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal‐Free Aryl Cross‐Coupling Directed by Traceless Linkers

(2019) Veit G. Haensch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reductive Cleavage of Secondary Sulfonamides: Converting Terminal Functional Groups into Versatile Synthetic Handles

(2019) Patrick S. Fier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Throughput Discovery and Evaluation of a General Catalytic Method for N-Arylation of Weakly Nucleophilic Sulfonamides

(2019) Joseph Becica et al.   ORGANIC LETTERS

Nickel(II)-Catalyzed Synthesis of Sulfinates from Aryl and Heteroaryl Boronic Acids and the Sulfur Dioxide Surrogate DABSO

(2019) Pui Kin Tony Lo et al.   ACS Catalysis

Pd-Catalyzed Cross-Coupling Reactions Promoted by Biaryl Phosphorinane Ligands

(2019) Summer D. Laffoon et al.   ACS Catalysis

Sulfonamidation of Aryl and Heteroaryl Halides through Photosensitized Nickel Catalysis

(2018) Taehoon Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols

(2018) Preston M. MacQueen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of Diazaphospholidine/Diazaphospholene-Based Bisphosphines in Room-Temperature Nickel-Catalyzed C(sp2)–N Cross-Couplings of Primary Alkylamines with (Hetero)aryl Chlorides and Bromides

(2018) Alexandre V. Gatien et al.   ACS Catalysis

Bisphosphines: A Prominent Ancillary Ligand Class for Application in Nickel-Catalyzed C–N Cross-Coupling

(2018) Christopher M. Lavoie et al.   ACS Catalysis

Elucidating the Mechanism of Aryl Aminations Mediated by NHC-Supported Nickel Complexes: Evidence for a Nonradical Ni(0)/Ni(II) Pathway

(2018) Silvia G. Rull et al.   ACS Catalysis

A Pharmaceutical Industry Perspective on Sustainable Metal Catalysis

(2018) John D. Hayler et al.   ORGANOMETALLICS

Modifications to the Aryl Group of dppf-Ligated Ni σ-Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki–Miyaura Coupling Reactions

(2018) Megan Mohadjer Beromi et al.   ORGANOMETALLICS

Evaluating 1,1′-Bis(phosphino)ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C–N Cross-Coupling of (Hetero)aryl Chlorides

(2017) Jillian S. K. Clark et al.   ORGANOMETALLICS

Oxidative Addition of Aryl Electrophiles to a Prototypical Nickel(0) Complex: Mechanism and Structure/Reactivity Relationships

(2017) Sonia Bajo et al.   ORGANOMETALLICS

Thieme Chemistry Journals Awardees – Where Are They Now? Efficient Cross-Coupling of Secondary Amines/Azoles and Activated (Hetero)Aryl Chlorides Using an Air-Stable DPEPhos/Nickel Pre-Catalyst

(2017) Mark Stradiotto et al.   SYNLETT

Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature

(2017) Joseph P. Tassone et al.   ACS Catalysis

Photo- and Electrochemical Valorization of Carbon Dioxide Using Earth-Abundant Molecular Catalysts

(2017) Alonso Rosas-Hernández et al.   Topics in Current Chemistry

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Ni-Catalyzed Amination Reactions: An Overview

(2016) Mario Marín et al.   CHEMICAL RECORD

Nickel-Catalyzed N-Arylation of Primary Amides and Lactams with Activated (Hetero)aryl Electrophiles

(2016) Christopher M. Lavoie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis

(2016) Emily B. Corcoran et al.   SCIENCE

Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design

(2016) Christopher M. Lavoie et al.   Nature Communications

CN Coupling of Indoles and Carbazoles with Aromatic Chlorides Catalyzed by a Single-Component NHC-Nickel(0) Precursor

(2015) Silvia G. Rull et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

BippyPhos: A Single Ligand With Unprecedented Scope in the Buchwald-Hartwig Amination of (Hetero)aryl Chlorides

(2013) Sarah M. Crawford et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fluorophore-Labeled Cyclooxygenase-2 Inhibitors for the Imaging of Cyclooxygenase-2 Overexpression in Cancer: Synthesis and Biological Studies

(2013) Atul Bhardwaj et al.   ChemMedChem

Carboxylic Acid (Bio)Isosteres in Drug Design

(2013) Carlo Ballatore et al.   ChemMedChem

Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates

(2013) Nathaniel H. Park et al.   ORGANIC LETTERS

Synthesis of Celecoxib and Structural Analogs- A Review

(2012) Sureshbabu Dadiboyena et al.   CURRENT ORGANIC CHEMISTRY

Mild Pd-CatalyzedN-Arylation of Methanesulfonamide and Related Nucleophiles: Avoiding Potentially Genotoxic Reagents and Byproducts

(2011) Brandon R. Rosen et al.   ORGANIC LETTERS

Copper-MediatedN-Heteroarylation of Primary Sulfonamides: Synthesis of Mono-N-heteroaryl Sulfonamides

(2010) Jonathan Baffoe et al.   ORGANIC LETTERS

Pd-Catalyzed N-Arylation of Secondary Acyclic Amides: Catalyst Development, Scope, and Computational Study

(2009) Jacqueline D. Hicks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross coupling of 3-bromopyridine and sulfonamides (R1NHSO2R2·R1=H, Me, alkyl; R2=alkyl and aryl) catalyzed by CuI/1,3-di(pyridin-2-yl)propane-1,3-dione

(2009) Xiaojun Han   TETRAHEDRON LETTERS

2-(Trimethylsilyl)ethanesulfonyl amide as a new ammonia equivalent for palladium-catalyzed amination of aryl halides

(2008) Prakash Anjanappa et al.   TETRAHEDRON LETTERS