Article
Chemistry, Physical
Naresh Eedugurala, Michael E. Steelman, Paramasivam Mahalingavelar, Daniel J. Adams, Kevin S. Mayer, Chih-Ting Liu, Anthony Benasco, Guorong Ma, Xiaodan Gu, Michael K. Bowman, Jason D. Azoulay
Summary: Open-shell conjugated polymers offer new opportunities to integrate the spin degree of freedom within emerging technologies. This study demonstrates a high-spin conjugated polymer composed of alternating benzo[1,2-b:4,5-b']dithiophene donors and a new, strongly electron-withdrawing 6,7,8,9-tetrachloro-[1,2,5]thiadiazolo[3,4-b]phenazine acceptor. The use of annulation and chlorination facilitates a transition between closed-shell aromatic and high-spin quinoidal forms, resulting in reduced bandgap, high electron affinity, delocalization of spin density, and n-type conduction. These insights allow for the development of a broader range of open-shell conjugated polymers and enable manipulation of important properties.
CHEMISTRY OF MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Jiyoul Lee, Joel Luke, Hyungju Ahn, Doyeon Kim, Chang-Hui Jin, Mun Ho Kim, Yong Sun Won, Minho Yoon, Ji-Seon Kim
Summary: Understanding the charge transport in donor-acceptor (D-A) type copolymers is crucial for designing high-mobility polymers. In this study, the charge transport properties of three D-A type copolymers based on cyclopentadithiophene (CDT) were investigated. It was found that CDT-PTz exhibited the best charge transport, with the lowest energetic disorder and a hole mobility of 0.79 +/- 0.01 cm(2) V-1 s(-1) in field-effect transistors. The structural properties of CDT-PTz, including a rigid and planar backbone structure and a strong intramolecular dipole moment, were attributed to noncovalent N-S interactions and the strong electron-withdrawing PTz acceptor unit. These properties resulted in strong intermolecular interactions and enhanced pi-pi stacking, leading to improved mobility in CDT-PTz.
ADVANCED ELECTRONIC MATERIALS
(2022)
Review
Chemistry, Applied
Dunshuai Qu, Ting Qi, Hui Huang
Summary: This article systematically reviews the polymerization methods of A-A-type polymers and the recent advancements applied in OFETs and PSCs, providing constructive guidance for the further development of high-performance n-type polymer materials by analyzing the synthesis and the relationship between device performances and polymer molecular structures.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Nanoscience & Nanotechnology
Mei-Nung Chen, Shu-Wei Chang, Suhendro Purbo Prakoso, Yen-Ting Li, Kai-Lin Chen, Yu-Cheng Chiu
Summary: This study proposes a mechanism for the photorecovery behavior of photoresponsive nonvolatile OFET memories. It confirms that excitons generated in a charged electret dominate the photorecovery behavior. The use of photoactive electret PFO demonstrates rapid photoinduced recovery under UV light and reliable switching ability between electrical charge trapping and optical recovery cycles.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Computer Science, Information Systems
Junjie Xing, Shixian Qin, Binglin Lai, Bowen Li, Zhida Li, Guocheng Zhang
Summary: The rapid development of electronics and materials science has driven the progress of various electronic devices, and the new generation of electronic devices, represented by wearable smart products, has introduced transparent new demands on the devices. The ability of biological synapses to enhance or inhibit information when it is transmitted is thought to be the biological mechanism of artificial synaptic devices. Inspired by biologically powerful neural networks, it is important to simulate biological synaptic functions on a single electronic device, and organic artificial synaptic transistors are artificially intelligent and very suitable artificial synaptic devices.
Article
Materials Science, Multidisciplinary
Dong Il Kim, Na Yeon Kwon, Sang-Hun Lee, Min Ju Cho, Jeongyong Kim, Dong Hoon Choi, Jinsoo Joo
Summary: pi-Conjugated p-type PBDB-T and n-type N2200 macromolecular units are bonded to generate ambipolar copolymer for achieving donor-acceptor heterojunction. The copolymer exhibits ambipolar transistor characteristics and distinctive photocurrents, making it suitable for optoelectronic memory devices.
ORGANIC ELECTRONICS
(2022)
Article
Chemistry, Multidisciplinary
Po-Hsun Ho, Yu-Ying Yang, Sui-An Chou, Ren-Hao Cheng, Po-Heng Pao, Chao-Ching Cheng, Iuliana Radu, Chao-Hsin Chien
Summary: In this study, chloroauric acid was used as a strong p-dopant for high-performance WSe2 monolayer transistors. By designing a suitable doping spacer length, a normally off, high-performance underlap top-gate device can be achieved without the need for additional gating in the contact and spacer regions.
Article
Chemistry, Multidisciplinary
Bowen Ding, Gunwoo Kim, Youngseok Kim, Flurin D. Eisner, Edgar Gutierrez-Fernandez, Jaime Martin, Myung-Han Yoon, Martin Heeney
Summary: Two new glycolated semiconducting polymers, PgBT(F)2gT and PgBT(F)2gTT, with different backbone curvatures were designed and synthesised for application in p-type accumulation mode organic electrochemical transistors (OECTs). While PgBT(F)2gT achieved a higher volumetric capacitance due to its curved backbone geometry, PgBT(F)2gTT exhibited superior OECT performance overall thanks to its enhanced order, resulting in faster charge mobility.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Astronomy & Astrophysics
Hui-Zhen He, Wei Liang, Qi-Fang Lu
Summary: In this work, the P-3 (0) model was used to investigate the strong decays of low-lying doubly bottom baryons systematically. The results show that some states are narrow and can potentially be observed in future experiments. Future experiments can test the phenomenological predictions at the quark level.
Article
Nanoscience & Nanotechnology
Ting-Wei Chang, Yu-Ching Weng, Yi-Ting Tsai, Yuanwen Jiang, Naoji Matsuhisa, Chien-Chung Shih
Summary: The manipulation of the polymer backbone structure has a profound influence on the crystalline behavior and charge transport characteristics of polymers. This study proposes a universal strategy to boost the stretchability of polymers by incorporating a nonlinear conjugated linker (NCL) into the main chain. The introduction of the NCL disrupts the linearity and central symmetry of the conjugated polymer backbone, reshaping the polymer conformation and increasing its stretchability. This method is applicable to a wide range of donor-acceptor pair polymers and does not compromise the mobility of the polymer.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Fan Wang, Rui Liao, Feng Wang
Summary: This study presents an effective strategy for controlling the pathways of p-conjugated supramolecular polymers. By incorporating donor and acceptor units on the monomeric structure, it is possible to achieve parallel-stacked metastable polymers that convert to thermodynamically stable slip-stacked polymers. The presence of donor-acceptor functionality on the seed structure is crucial for accelerating the pathway conversion.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Qidi Huang, Jianai Chen, Shuanma Yan, Xiongchao Shao, Yujie Dong, Junlei Liu, Weijun Li, Cheng Zhang
Summary: A new donor-acceptor-donor monomer CDB-EDOT with a torsion angle of 39 degrees is designed and synthesized, leading to a conjugated polymer pCDBEDOT with excellent capacitive properties and reversible electrochromic capabilities. The polymer shows high specific capacitance and stability, making it a promising material for energy-sustainable intelligent devices.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Materials Science, Multidisciplinary
Guobing Zhang, Hao Yu, Yue Sun, Weiwei Wang, Yao Zhao, Lichun Wang, Longzhen Qiu, Yunsheng Ding
Summary: Four conjugated polymers based on NDI and aza-substituted thiophene-phenyl-thiophene were synthesized, with a gradual decrease in energy levels due to aza-substitutions. The polymer with four aza-substitutions showed the deepest LUMO/HOMO energy levels. OFETs exhibited unipolar electron transport characteristics and maintained n-type behavior even after long-term exposure to air.
JOURNAL OF MATERIALS CHEMISTRY C
(2021)
Article
Chemistry, Multidisciplinary
Jiancheng Rao, Liuqing Yang, Xue Li, Lei Zhao, Shumeng Wang, Hongkun Tian, Junqiao Ding, Lixiang Wang
Summary: A novel steric locking strategy was proposed by introducing methyl groups into D-A conjugated polymers, leading to efficient TADF with extremely low energy splitting. Devices fabricated using this strategy exhibited record-high external quantum efficiency.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Applied
Xiaomin Wu, Xiangyu Hao, Ping Deng, Huipeng Chen
Summary: A newly designed and synthesized polymerized small-molecule acceptor, NC-PY6, showed promising results in polymer solar cells with the polymer donor D18, demonstrating the potential of this molecular design strategy for high-performance all-polymer solar cells.
Article
Materials Science, Multidisciplinary
Xue Zhao, Shi-Yu Wei, Xiao-Hong Wang, Long-Zhen Qiu
Summary: A novel nonvolatile solar-blind DUV photoelectric memory based on an organic field effect transistor is investigated in this paper, showing promising path toward highly selective and advanced multilevel solar-blind DUV monitors.
ADVANCED OPTICAL MATERIALS
(2021)
Article
Chemistry, Physical
Siyu Yan, Kaixin Tang, Yuejian Lin, Yuanhang Ren, Wanli Tian, Hua Chen, Tingting Lin, Longzhen Qiu, Xiaoyong Pan, Weizhi Wang
Summary: The formability of antiperovskite [MX4]XA(3)-type can be predicted using analysis theory. A series of cesium-manganese antiperovskite single crystals were synthesized to validate the prediction model, showing high luminescence efficiency and stable luminescent color over a wide temperature range. The first all-inorganic cesium-manganese halide antiperovskite light-emitting diode was reported, demonstrating high external quantum efficiency, luminance, and operational stability.
ACS ENERGY LETTERS
(2021)
Article
Polymer Science
Ye Yuan, Fengsheng Zhao, Yafei Ding, Guobing Zhang, Xiaohong Wang, Longzhen Qiu
Summary: This study provides an efficient strategy for the design and synthesis of CPs with high carrier transport properties and mechanical stability by modifying the symmetry of the side chains. The silicon-carbon asymmetric side chains can enhance the aggregation degree of polymer chains while maintaining good mobility and mechanical performance. Additionally, the P(C-Si) polymer exhibits superior tensile properties even when highly stretched, retaining a majority of its properties.
MACROMOLECULAR RAPID COMMUNICATIONS
(2022)
Article
Nanoscience & Nanotechnology
Longlong Jiang, Chenyin Xu, Xiaocheng Wu, Xue Zhao, Lijun Zhang, Guobing Zhang, Xiaohong Wang, Longzhen Qiu
Summary: Deep ultraviolet-light-stimulated artificial synaptic devices have potential applications in various fields and can simulate various synaptic behaviors. The proposed artificial synaptic structures on flexible substrates also successfully simulate typical synaptic behaviors.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Yafei Ding, Yingman Zhu, Xiaohong Wang, Yunfei Wang, Song Zhang, Guobing Zhang, Xiaodan Gu, Longzhen Qiu
Summary: In this study, a side chain engineering strategy was developed to enhance the molecular orientation and charge transport of polymer semiconductors during stretching. Increasing the length of silicon chains improved the charge mobility and stretchability of the material.
CHEMISTRY OF MATERIALS
(2022)
Article
Polymer Science
Gang Huang, Ning Wu, Xiaohong Wang, Guobing Zhang, Longzhen Qiu
Summary: Molecular weight is a key factor influencing the properties of conjugated polymers. It has been found that below the critical molecular weight, conjugated polymers exhibit high crystallinity and low ductility; when the molecular weight approaches the critical value, the crystallinity decreases and ductility increases; when the molecular weight is much higher than the critical value, the polymer films show significant ductility.
MACROMOLECULAR RAPID COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Can Zhang, Chenyin Xu, Cuifen Chen, Junjie Cheng, Hongli Zhang, Fan Ni, Xiaohong Wang, Gang Zou, Longzhen Qiu
Summary: A fundamentally novel approach in designing a programmable circularly polarized light photodetector utilizing the chiral properties of achiral polymers and high-quality film was demonstrated, achieving switchable detection of left- and right-handed CPL signals. This device also exhibited excellent discrimination between different CPL signals, making it a promising tool in various scientific fields and imaging applications.
Article
Polymer Science
Yafei Ding, Yingman Zhu, Heng Wang, Yunfei Wang, Xiaodan Gu, Xiaohong Wang, Longzhen Qiu
Summary: Blending semiconductor polymers with insulator polymers is an effective strategy for preparing high-performance stretchable electronics. Optimizing the solution-processable technique and controlling the semiconductor molecular weight are promising strategies for developing blend films with good electrical and mechanical properties.
Article
Nanoscience & Nanotechnology
Longlong Jiang, Hua Huang, Can Zhang, Ye Yuan, Xiaohong Wang, Longzhen Qiu
Summary: A semiconductor/dielectric bilayer structure was used in a flexible biomimetic photonic synaptic transistor device for the first time. Various biomimetic synaptic behaviors were successfully simulated, and ultra-low energy consumption was achieved.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
Hui Shi, Banghu Wang, Xiaohong Wang, Longzhen Qiu, Lei Zheng
Summary: An optically readable electrochromic-based microfiber synaptic device was designed by combining a multimode fiber and an electrochromic device, which can control the transmission of light in the fiber using an external voltage. This device has the ability to imitate various basic functions of biological synapses, such as synaptic plasticity, paired-pulse facilitation (PPF), and the transition from short-term memory to long-term memory. Additionally, the device decodes the output optical signal with the international Morse code and can be integrated into a more complex and versatile photonic neuromorphic system.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
Ye Yuan, Haoran Zhu, Xiaohong Wang, Guobing Zhang, Longzhen Qiu
Summary: A method to control the elastic properties of stretchable conjugated polymers (CPs) by regulating the spacer length between the siloxane side-chain and the backbone has been proposed. CP films with different spacer lengths were prepared and their aggregation state, electrical and elastic properties were investigated. Adjustable lamellar spacing and improved elastic properties were achieved by changing the spacer length, providing evidence that tuning the spacer length is an effective way to enhance the stretchability of CPs.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Polymer Science
Ning Wu, Gang Huang, Hua Huang, Yunfei Wang, Xiaodan Gu, Xiaohong Wang, Longzhen Qiu
Summary: A backbone engineering strategy is developed to tune the properties of conjugated polymer semiconductors. Four Donor-Acceptor (D-A) polymers are synthesized and their effects on energy levels, film morphology, carrier transport properties, and tensile properties are examined. The replacement of the donor structure significantly improves the mobility of conjugated polymers, but leads to reduced stretchability. PTDPPBT exhibits moderate stretchability and excellent electrical properties, with a higher mobility than most stretchable conjugated polymers.
MACROMOLECULAR RAPID COMMUNICATIONS
(2023)
Article
Polymer Science
Xiaohong Wang, Chenyin Xu, Ning Xu, Longlong Jiang, Yunfei Wang, Fan Ni, Guobing Zhang, Xiaodan Gu, Longzhen Qiu
Summary: Introducing hydrogen bonding structures into semiconducting polymers is an effective method to improve their performance. In this study, DPP-based random copolymers with quadruple hydrogen bonding were constructed by copolymerization of a ring-like UPy with alkyl chain-substituted DPP. The resulting polymers showed improved mechanical properties and retained 27.9% mobility under 100% stretching. This study also introduced quadruple intramolecular hydrogen bonding into the backbone of conjugated polymers, providing a new strategy for the introduction of multiple intramolecular hydrogen bonds into stretchable semiconducting polymers.
Article
Engineering, Electrical & Electronic
Yuge Liang, Yumeng Wang, Mengmeng Zhu, Longzhen Qiu, Jun Zhu, Bo Zhang, Ying Liu, Hongbo Lu, Miao Xu
Summary: By modifying the surface wettability of PI films through oxygen plasma treatment, this paper achieved control of the pretilt angle of liquid crystals. A new mode for GHLC smart windows with intermediate initial transmittance was established by controlling the pretilt angle.
ACS APPLIED ELECTRONIC MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Xiang Xia, Yuge Liang, Xuelian Liu, Le Yang, Jun Zhu, Miao Xu, Guobing Zhang, Longzhen Qiu, Hongbo Lu
Summary: In this study, dense and flat films were formed in liquid crystal media using surface initiation, resulting in low-surface-energy components being forced to segregate on the liquid crystal-polymer interface during polymerization. A decrease in UV light intensity during polymerization led to the accumulation of more low-surface-energy components on the polymer wall surface, reducing both the anchoring energy and the threshold voltage of liquid crystal devices using this polymer wall.
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
(2022)