期刊
INORGANIC AND NANO-METAL CHEMISTRY
卷 50, 期 8, 页码 630-636出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/24701556.2020.1723028
关键词
Triazenido compound; silver complex; photoluminescence; electrocatalyst for hydrogen evolution
资金
- National Science Foundation of China [21271073, 21875074]
- Student Research Program (SRP) of South China University of Technology
The reaction of 2-bromoaniline with sodium nitrite affords a triazenido compound, 1,3-bis[(2-bromo)benzene]triazene (HL). Spectroscopic investigations show that HL bears a high selectivity for silver(I) ion in the presence of other metal ions. In the presence of Et3N, the reaction of HL and AgNO3 gives a binuclear triazenido-silver complex, [Ag-2(L)(2)], which has been determined by X-ray diffraction analysis. Electrochemical studies show this silver complex can act as an electrocatalyst for hydrogen generation from neutral water with a turnover frequency (TOF) of 874.14 moles of hydrogen per mole of catalyst per hour (mol H-2/mol catalyst/h) at an over potential (OP) of 837.6 mV.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据