Article
Materials Science, Coatings & Films
Benjamin W. Lamm, Jake W. McMurray, Ercan Cakmak, Michael J. Lance, David J. Mitchell
Summary: In this study, the CALPHAD approach was used to investigate zirconium carbide deposition. Phase equilibria were calculated and used to explore the chemical vapor deposition (CVD) processing space in the ZrCl4-CH3SiCl3-CH4-H-2 system. The results showed that the most important factor in controlling the composition was the ratios of CH4:ZrCl4, which determined the nature of the composition - either carbide or silicide.
SURFACE & COATINGS TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Yuan Cheng, Yang Lyu, Yongshuai Xie, Chi Zhang, Jiaxin Feng, Liancai Xun, Wengzheng Zhang, Wenbo Han, Shanbao Zhou, Ping Hu, Xinghong Zhang, Jiecai Han
Summary: The ablation behavior and mechanism of ZrC-SiC ceramic matrix, carbon fiber, and ceramic-fiber interface layer under 1800 degrees C ablation are investigated in this study. Chemical reactions and oxidative damage models under 1800 degrees C oxidizing airflow are established, revealing the formation of ZrC and SiC causing grain erosion, and the reaction between carbon fiber and SiO2 and O-2 resulting in pit erosion. The construction of a nanocarbon interface around the fiber is found to inhibit microstructure damage. This work provides fundamental understanding and engineering guidance for the anti-ablation and toughening of 3D C-f/ZrC-SiC.
Article
Materials Science, Ceramics
Jing Xu, Lingjun Guo, Jingan Kong, Yuan Ma, Hanhui Wang, Jiancheng Wang
Summary: The bending property of C/C-ZrC-SiC, C/C-SiC, and C/C composites after ablation was studied, and it was found that C/C-ZrC-SiC composites exhibited better laser ablation resistance and higher bending strength retention compared to the other two. The excellent ablation resistance and residual bending strength of C/C-ZrC-SiC composites were attributed to the lowest ablative temperature and the effective protection of ZrO2 grain and ZrO2-SiO2 layer. However, the ablation damage induced a fracture behavior transformation in the composites.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Multidisciplinary
Lei Zheng, Xiao Luo, Cunqian Fang, Chen Zeng, Xiaxiang Zhang, Ze Zhang, Mingyu Zhang, Qizhong Huang
Summary: In this study, a fully dense Mg-modified ZrC-SiC composite was prepared and its microstructure, phase evolution, and ablation behavior were investigated. The results showed that the introduction of Mg significantly improved the ablation resistance and the integrity of the oxide layer.
Article
Materials Science, Ceramics
Xinfa Tian, Xiaohong Shi, Li Yang, Hejun Li, Hongjiao Lin
Summary: The modified precursor infiltration pyrolysis (PIP) method was used to prepare an integrated doped ceramic matrix and coating with SiC nanowires, resulting in a composite with improved bonding strength and ablation resistance. The integration of the coating and matrix enabled the formation of a continuous oxide layer in the ablation process, effectively blocking oxygen and heat. This systematic improvement led to significantly lower mass and linear ablation rates compared to traditional composites.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Zhigang Zhao, Kezhi Li, Wei Li
Summary: ZrC-SiC-ZrB2 and ZrC-SiC inhibited carbon/carbon composites wedge shaped components were fabricated by reactive melt infiltration and tested on an oxyacetylene torch at a heat flux of 2.38 MW/m2 for 120 s. Compared with C/C composites, both inhibited composites components exhibited better ablation resistance with tip temperatures reaching about 2500 degrees C. Structural evolution on the surfaces of the inhibited composites components included a porous ZrO2 layer near the tip, layered structure of the outer ZrO2 layer, subsurface ZrO2-SiO2 layer in the intermediate region, and SiO2 layer in the tail.
Article
Materials Science, Multidisciplinary
Lei Zhong, Lingjun Guo, Yunyu Li, Chuanyun Wang
Summary: To reduce cost and preparation time, uneven-density C/C composites are designed and prepared using thermal gradient CVI process, followed by local modification of ZrC-SiC composite ceramics to enhance anti-ablation performance. Ablation tests demonstrate that the microstructure of ZrO2 grains can be influenced by adjusting ablation temperature and ZrO2 grains' melting point. Optimum performance is achieved with approximately 20 wt% SiC content in the ZrC-SiC composite ceramics and improves the uneven C/C composites prepared. Additionally, the dense C/C matrix prevents liquid ZrO2-SiO2 phase runoff and allows for protection of carbon fibers and the dense C/C matrix beneath.
MATERIALS CHARACTERIZATION
(2023)
Article
Metallurgy & Metallurgical Engineering
Wei Feng, Yan Zhang, Lei Liu, Bo-yan LI, Jia-ping Zhang, Xi Chen, Zi-bo He, Cheng-wei Tang, Hai-jun Zhang, Qin-xin Han
Summary: The high-frequent pulsing ablation of C/C-SiC-ZrB2-ZrC composites under millisecond-scaled single loading for different cycles was studied. The sample was ablated and cooled by plasma and airflow alternately on a self-developed bench. Results indicated that the ablation rates decreased quickly before 1000 cycles and then declined gradually until impact for 2000 cycles. Microstructure, phase and surface temperature analyses suggested that an incomplete layer of mixed ceramic ablation product was formed on the surfaces of the tested composites and the amount of the bare carbon tended to be steady after 1000 cycles. The ablation product layer weakened the thermal stress-induced mechanical erosion and protected the carbon from erosion, which led to the evolution of ablation rates.
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
(2023)
Article
Materials Science, Multidisciplinary
Dou Hu, Qiangang Fu, Mingde Tong, Xiaoxuan Li
Summary: This study investigates the improvement of multiple cyclic ablation performance of ablation resistant coating through the design and fabrication of (ZrC-TaC)/(ZrC-SiC) multilayer coating. The results showed that the linear variation rate of the multilayer coating decreased by 75% compared to the monolayer ZrC-TaC coating, which was attributed to the control of low Ta/Zr ratio to increase the temperature resistance of Zr-Ta-O oxide film and the interfacial crack deflection induced by the ZrC-SiC interface layer.
Article
Materials Science, Ceramics
Rongjun Liu, Xingyu Liu, Yanfei Wang, Huaming Miao, Changqing Song, Gongjin Qi, Fan Wan
Summary: The C-f/SiC-ZrC ultra-high temperature ceramic matrix composites exposed to high-energy laser ablation exhibited specific ablation region divisions. ZrO2 played a key role in anti-ablation during laser exposure, and dense structure with high melting point components was crucial for improving the anti-laser ablation performance of the materials.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Yong Gao, Bai-Lin Zha, Jin-Jin Wang, Zhen-Sheng Sun, Zhao-Fu Zhang, Yi-Ang Shi
Summary: In this study, C/C-SiC and C/C-SiC-ZrC composites were prepared and their ablation resistance under hypersonic oxygen-rich environmental conditions was investigated. The results showed that C/C-SiC composites exhibited excellent ablation resistance at relatively low temperature and speed, while the high-temperature ablation resistance of ZrC-modified C/C-SiC-ZrC composites significantly improved.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Yuqi Wang, Lingxiang Guo, Yuyu Zhang, Xuemeng Zhang, Hongkang Ou, Jia Sun
Summary: To improve the ablation performance of C/C composite at 3000 degrees C, a ZrC-SiC-Si/SiC-Si double-layered coatings (ZSS/SS) was prepared. The ZSS/SS coating showed the lowest linear ablation rate of 0.53 μm/s in 90 s with a parabolic rate constant Kp (0.053 μm/s^3), attributed to good self-sealing of oxidation derived glassy. However, for long-term ablation, the Kp became worse (0.131) due to dominant mechanical denudation.
Article
Metallurgy & Metallurgical Engineering
Meng-meng Shao, Zhao-ke Chen, Xin-shuang Wang, Qing-bo Wen, Xiang Xiong
Summary: To enhance the anti-ablation property of C/C composites, ZrC-SiC-MoSi2 coatings with different Zr contents were prepared on C/C-SiC-ZrC ceramic matrix composites. The ablation behavior of the coated composites was studied in an oxyacetylene torch environment with varying oxygen and acetylene fluxes. The results showed that the particle sizes of ZrC and SiC in the coatings decreased and distributed more homogeneously with the increase of Zr content. The ablation mechanisms of the coatings changed from oxidation to oxidation plus evaporation and then to the combination of oxidation, evaporation, and denudation with the increase of oxygen and acetylene fluxes.
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
(2023)
Article
Materials Science, Ceramics
Rida Zhao, Chenglong Hu, Yuanhong Wang, Shengyang Pang, Jian Li, Sufang Tang, Hui-Ming Cheng
Summary: Sandwich-structured C/C-SiC and C/C-SiC-ZrC composites with or without a SiC interphase were fabricated using a joint process of ECVI and PIP. The composites exhibited low density, high strength, and low ablation rate, with the interphase and matrix constituents playing a significant role in their mechanical and ablation properties.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2022)
Article
Materials Science, Multidisciplinary
Jingchao Ma, Sijie Kou, Shaobo Yang, Yinghao Liu, Chenghua Luan, Peng Wang, Shangwu Fan
Summary: C/C-ZrC-SiC composites with different coatings were prepared and their ablative behavior was studied. The results showed that the coating with YSi2 doping improved the ablative resistance of the composites.