Atomic Modulation, Structural Design, and Systematic Optimization for Efficient Electrochemical Nitrogen Reduction

Computational Design of Single-Molybdenum Catalysts for the Nitrogen Reduction Reaction

(2019) Qinye Li et al.   Journal of Physical Chemistry C

Electrochemical Fabrication of Porous Au Film on Ni Foam for Nitrogen Reduction to Ammonia

(2019) Hongjing Wang et al.   Small

Over 56.55% Faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential

(2019) Mengfan Wang et al.   Nature Communications

Ambient Electrosynthesis of Ammonia on a Biomass-Derived Nitrogen-Doped Porous Carbon Electrocatalyst: Contribution of Pyridinic Nitrogen

(2019) Cuijiao Zhao et al.   ACS Energy Letters

Ammonia Detection Methods in Photocatalytic and Electrocatalytic Experiments: How to Improve the Reliability of NH3 Production Rates?

(2019) Yunxuan Zhao et al.   Advanced Science

High-Performance Electrocatalytic Conversion of N2 to NH3 Using Oxygen-Vacancy-Rich TiO2 In Situ Grown on Ti3 C2 T x MXene

(2019) Yanfeng Fang et al.   Advanced Energy Materials

Dramatically Enhanced Ambient Ammonia Electrosynthesis Performance by In-Operando Created Li-S Interactions on MoS2 Electrocatalyst

(2019) Yanyan Liu et al.   Advanced Energy Materials

Two-Dimensional Mosaic Bismuth Nanosheets for Highly Selective Ambient Electrocatalytic Nitrogen Reduction

(2019) Laiquan Li et al.   ACS Catalysis

Interfacial engineering of cobalt sulfide/graphene hybrids for highly efficient ammonia electrosynthesis

(2019) Pengzuo Chen et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Single-Boron Catalysts for Nitrogen Reduction Reaction

(2019) Chuangwei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ambient Electrosynthesis of Ammonia on a Core–Shell‐Structured Au@CeO 2 Catalyst: Contribution of Oxygen Vacancies in CeO 2

(2019) Guoqiang Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Advanced Non‐metallic Catalysts for Electrochemical Nitrogen Reduction under Ambient Conditions

(2019) Lili Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Building up a Picture of the Electrocatalytic Nitrogen Reduction Activity of Transition Metal Single Atom Catalysts

(2019) xin liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triggering surface oxygen vacancies on atomic layered molybdenum dioxide for a low energy consumption path toward nitrogen fixation

(2019) Gong Zhang et al.   Nano Energy

Electrochemical Dinitrogen Reduction to Ammonia by Mo2N: Catalysis or Decomposition?

(2019) Bo Hu et al.   ACS Energy Letters

Nitrogen Vacancies on 2D Layered W 2 N 3 : A Stable and Efficient Active Site for Nitrogen Reduction Reaction

(2019) Huanyu Jin et al.   ADVANCED MATERIALS

Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride

(2019) Xuan Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Single Atoms Anchored in Porous Nitrogen-Doped Carbon as Efficient pH-Universal Catalysts for the Nitrogen Reduction Reaction

(2019) Wenjie Zang et al.   ACS Catalysis

Oxygen Vacancy–Enhanced Electrocatalytic Performances of TiO 2 Nanosheets toward N 2 Reduction Reaction

(2019) Caihong Fang et al.   Advanced Materials Interfaces

Activated TiO2 with tuned vacancy for efficient electrochemical nitrogen reduction

(2019) Zishan Han et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Multiscale Principles To Boost Reactivity in Gas-Involving Energy Electrocatalysis

(2018) Cheng Tang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrochemical Ammonia Synthesis via Nitrogen Reduction Reaction on a MoS2 Catalyst: Theoretical and Experimental Studies

(2018) Ling Zhang et al.   ADVANCED MATERIALS

Ambient Electrosynthesis of Ammonia: Electrode Porosity and Composition Engineering

(2018) Hong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Defect Engineering Metal-Free Polymeric Carbon Nitride Electrocatalyst for Effective Nitrogen Fixation under Ambient Conditions

(2018) Chade Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Nitrogen Fixation at Boron

(2018) Christian Hering-Junghans   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Amorphous Noble-Metal-Free Electrocatalyst that Enables Nitrogen Fixation under Ambient Conditions

(2018) Chade Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical nitrogen reduction to ammonia under mild conditions enabled by a polymer gel electrolyte

(2018) Benjamin L. Sheets et al.   CHEMICAL COMMUNICATIONS

Highly efficient electrochemical ammonia synthesis via nitrogen reduction reactions on a VN nanowire array under ambient conditions

(2018) Xiaoping Zhang et al.   CHEMICAL COMMUNICATIONS

Electrochemical N2 fixation to NH3 under ambient conditions: Mo2N nanorod as a highly efficient and selective catalyst

(2018) Xiang Ren et al.   CHEMICAL COMMUNICATIONS

Highly-Selective Electrochemical Reduction of Dinitrogen to Ammonia at Ambient Temperature and Pressure over Iron Oxide Catalysts

(2018) Xiaoyang Cui et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrochemical synthesis of ammonia using ruthenium–platinum alloy at ambient pressure and low temperature

(2018) Revanasiddappa Manjunatha et al.   ELECTROCHEMISTRY COMMUNICATIONS

Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH3) under ambient conditions

(2018) Chunxian Guo et al.   Energy & Environmental Science

Structural characterization of the P1+intermediate state of the P-cluster of nitrogenase

(2018) Stephen M. Keable et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Catalytic performance of Ru, Os, and Rh nanoparticles for ammonia synthesis: A density functional theory analysis

(2018) Atsushi Ishikawa et al.   JOURNAL OF CATALYSIS

Single Molybdenum Atom Anchored on N-Doped Carbon as a Promising Electrocatalyst for Nitrogen Reduction into Ammonia at Ambient Conditions

(2018) Chongyi Ling et al.   Journal of Physical Chemistry C

A Spectroscopic Study on the Nitrogen Electrochemical Reduction Reaction on Gold and Platinum Surfaces

(2018) Yao Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aqueous electrocatalytic N2 reduction under ambient conditions

(2018) Na Cao et al.   Nano Research

Ambient N2 fixation to NH3 electrocatalyzed by a spinel Fe3O4 nanorod

(2018) Qin Liu et al.   Nanoscale

Computational screening of a single transition metal atom supported on the C2N monolayer for electrochemical ammonia synthesis

(2018) Zhongxu Wang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Single transition metal atom embedded into a MoS2 nanosheet as a promising catalyst for electrochemical ammonia synthesis

(2018) Jia Zhao et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

A theoretical study of the effect of a non-aqueous proton donor on electrochemical ammonia synthesis

(2018) Linan Zhang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Nitrogen fixation and reduction at boron

(2018) Marc-André Légaré et al.   SCIENCE

Beyond fossil fuel–driven nitrogen transformations

(2018) Jingguang G. Chen et al.   SCIENCE

Facile Ammonia Synthesis from Electrocatalytic N2 Reduction under Ambient Conditions on N-Doped Porous Carbon

(2018) Yanming Liu et al.   ACS Catalysis

Suppression of Hydrogen Evolution Reaction in Electrochemical N2 Reduction Using Single-Atom Catalysts: A Computational Guideline

(2018) Changhyeok Choi et al.   ACS Catalysis

Anchoring PdCu Amorphous Nanocluster on Graphene for Electrochemical Reduction of N2 to NH3 under Ambient Conditions in Aqueous Solution

(2018) Miao-Miao Shi et al.   Advanced Energy Materials

A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions

(2018) Xiaoyang Cui et al.   Advanced Energy Materials

High-Efficiency Electrosynthesis of Ammonia with High Selectivity under Ambient Conditions Enabled by VN Nanosheet Array

(2018) Rong Zhang et al.   ACS Sustainable Chemistry & Engineering

Efficient Electrochemical N2 Reduction to NH3 on MoN Nanosheets Array under Ambient Conditions

(2018) Ling Zhang et al.   ACS Sustainable Chemistry & Engineering

Discovery of cobweb-like MoC6 and its application for nitrogen fixation

(2018) Z. W. Chen et al.   Journal of Materials Chemistry A

Nitrogen-doped porous carbon: highly efficient trifunctional electrocatalyst for oxygen reversible catalysis and nitrogen reduction reaction

(2018) Xiaoxuan Yang et al.   Journal of Materials Chemistry A

MoO3 nanosheets for efficient electrocatalytic N2 fixation to NH3

(2018) Jingrui Han et al.   Journal of Materials Chemistry A

Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N 2 and H 2 O in alkaline electrolytes

(2018) Shreya Mukherjee et al.   Nano Energy

Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages

(2018) Mohammadreza Nazemi et al.   Nano Energy

Atomically dispersed Au 1 catalyst towards efficient electrochemical synthesis of ammonia

(2018) Xiaoqian Wang et al.   Science Bulletin

Rational Electrode–Electrolyte Design for Efficient Ammonia Electrosynthesis under Ambient Conditions

(2018) Bryan H. R. Suryanto et al.   ACS Energy Letters

Achieving a Record-High Yield Rate of 120.9 μgNH3  mgcat.−1  h−1 for N2 Electrochemical Reduction over Ru Single-Atom Catalysts

(2018) Zhigang Geng et al.   ADVANCED MATERIALS

Emerging Applications of Plasmons in Driving CO2 Reduction and N2 Fixation

(2018) Jianhua Yang et al.   ADVANCED MATERIALS

Ammonia Synthesis from Electrocatalytic N2 Reduction under Ambient Conditions by Fe2 O3 Nanorods

(2018) Xiaojiao Xiang et al.   ChemCatChem

Nitrogen-free commercial carbon cloth with rich defects for electrocatalytic ammonia synthesis under ambient conditions

(2018) Wenyi Li et al.   CHEMICAL COMMUNICATIONS

Ag nanosheets for efficient electrocatalytic N2 fixation to NH3 under ambient conditions

(2018) Hehan Huang et al.   CHEMICAL COMMUNICATIONS

Ambient Electrochemical Synthesis of Ammonia from Nitrogen and Water Catalyzed by Flower-Like Gold Microstructures

(2018) Ziqiang Wang et al.   ChemSusChem

Energy-Efficient Nitrogen Reduction to Ammonia at Low Overpotential in Aqueous Electrolyte under Ambient Conditions

(2018) Dabin Wang et al.   ChemSusChem

Tuning nitrogen reduction reaction activity via controllable Fe magnetic moment: A computational study of single Fe atom supported on defective graphene

(2018) Xiangyu Guo et al.   ELECTROCHIMICA ACTA

Electrochemical Synthesis of Ammonia from N2 and H2O under Ambient Conditions Using Pore-Size-Controlled Hollow Gold Nanocatalysts with Tunable Plasmonic Properties

(2018) Mohammadreza Nazemi et al.   Journal of Physical Chemistry Letters

Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles

(2018) Xuan Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Impact of H-termination on the nitrogen reduction reaction of molybdenum carbide as an electrochemical catalyst

(2018) Qinye Li et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

High-performance artificial nitrogen fixation at ambient conditions using a metal-free electrocatalyst

(2018) Weibin Qiu et al.   Nature Communications

High-Performance Electrohydrogenation of N2 to NH3 Catalyzed by Multishelled Hollow Cr2O3 Microspheres under Ambient Conditions

(2018) Ya Zhang et al.   ACS Catalysis

Ambient Electrochemical Ammonia Synthesis with High Selectivity on Fe/Fe Oxide Catalyst

(2018) Lin Hu et al.   ACS Catalysis

Boosted Electrocatalytic N2 Reduction to NH3 by Defect-Rich MoS2 Nanoflower

(2018) Xianghong Li et al.   Advanced Energy Materials

Double-atom catalysts: transition metal dimer-anchored C2N monolayers as N2 fixation electrocatalysts

(2018) Xu Zhang et al.   Journal of Materials Chemistry A

TiO2 nanoparticles–reduced graphene oxide hybrid: an efficient and durable electrocatalyst toward artificial N2 fixation to NH3 under ambient conditions

(2018) Xiaoxue Zhang et al.   Journal of Materials Chemistry A

Ambient N2 fixation to NH3 at ambient conditions: Using Nb2O5 nanofiber as a high-performance electrocatalyst

(2018) Jingrui Han et al.   Nano Energy

Carbon-Based Metal-Free Catalysts for Key Reactions Involved in Energy Conversion and Storage

(2018) Shenlong Zhao et al.   ADVANCED MATERIALS

Molybdenum Carbide Nanodots Enable Efficient Electrocatalytic Nitrogen Fixation under Ambient Conditions

(2018) Hui Cheng et al.   ADVANCED MATERIALS

Guiding Principles for Designing Highly Efficient Metal‐Free Carbon Catalysts

(2018) Lipeng Zhang et al.   ADVANCED MATERIALS

Cover Picture: Discovery of Elusive K4 O6 , a Compound Stabilized by Configurational Entropy of Polarons (Angew. Chem. Int. Ed. 1/2019)

(2018) Christoph Freysoldt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation

(2018) Lili Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-Site Molybdenum on Solid Support Materials for Catalytic Hydrogenation of N2 -into-NH3

(2018) Luis Miguel Azofra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mo2TiC2 MXene: A Promising Catalyst for Electrocatalytic Ammonia Synthesis

(2018) Yijing Gao et al.   CATALYSIS TODAY

Enabling Electrocatalytic N2 Reduction to NH3 by Y2O3 Nanosheet under Ambient Conditions

(2018) Xianghong Li et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Nanostructured Bromide-Derived Ag Film: An Efficient Electrocatalyst for N2 Reduction to NH3 under Ambient Conditions

(2018) Lei Ji et al.   INORGANIC CHEMISTRY

Synthesis and Physicochemical Properties of Fluorinated Ionic Liquids with High Nitrogen Gas Solubility

(2018) Colin S. M. Kang et al.   Journal of Physical Chemistry C

Theoretical Evaluation of Possible 2D Boron Monolayer in N2 Electrochemical Conversion into Ammonia

(2018) Chuangwei Liu et al.   Journal of Physical Chemistry C

Graphene Oxide-Supported Transition Metal Catalysts for Di-Nitrogen Reduction

(2018) Tongtong Yang et al.   Journal of Physical Chemistry C

Mn3 O4 Nanocube: An Efficient Electrocatalyst Toward Artificial N2 Fixation to NH3

(2018) Xiufeng Wu et al.   Small

Rational Design of Fe–N/C Hybrid for Enhanced Nitrogen Reduction Electrocatalysis under Ambient Conditions in Aqueous Solution

(2018) Ying Wang et al.   ACS Catalysis

Boron-Doped TiO2 for Efficient Electrocatalytic N2 Fixation to NH3 at Ambient Conditions

(2018) Yuan Wang et al.   ACS Sustainable Chemistry & Engineering

Ambient Nitrogen Reduction to Ammonia Electrocatalyzed by Bimetallic PdRu Porous Nanostructures

(2018) Ziqiang Wang et al.   ACS Sustainable Chemistry & Engineering

Electrocatalytic Hydrogenation of N2 to NH3 by MnO: Experimental and Theoretical Investigations

(2018) Zao Wang et al.   Advanced Science

High-Performance N2-to-NH3 Conversion Electrocatalyzed by Mo2C Nanorod

(2018) Xiang Ren et al.   ACS Central Science

MoS2 Polymorphic Engineering Enhances Selectivity in the Electrochemical Reduction of Nitrogen to Ammonia

(2018) Bryan H. R. Suryanto et al.   ACS Energy Letters

Nitrogenase Bioelectrocatalysis: From Understanding Electron-Transfer Mechanisms to Energy Applications

(2018) Rong Cai et al.   ACS Energy Letters

La2O3 nanoplate: An efficient electrocatalyst for artificial N2 fixation to NH3 with excellent selectivity at ambient condition

(2018) Bo Xu et al.   ELECTROCHIMICA ACTA

Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids

(2017) Fengling Zhou et al.   Energy & Environmental Science

Computational Study of MoN2 Monolayer as Electrochemical Catalysts for Nitrogen Reduction

(2017) Qinye Li et al.   Journal of Physical Chemistry C

Single Mo Atom Supported on Defective Boron Nitride Monolayer as an Efficient Electrocatalyst for Nitrogen Fixation: A Computational Study

(2017) Jingxiang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ammonia Electrosynthesis with High Selectivity under Ambient Conditions via a Li+ Incorporation Strategy

(2017) Gao-Feng Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The structure of vanadium nitrogenase reveals an unusual bridging ligand

(2017) Daniel Sippel et al.   Nature Chemical Biology

Combining theory and experiment in electrocatalysis: Insights into materials design

(2017) Zhi Wei Seh et al.   SCIENCE

Ammonia Synthesis on Wool-Like Au, Pt, Pd, Ag, or Cu Electrode Catalysts in Nonthermal Atmospheric-Pressure Plasma of N2 and H2

(2017) Masakazu Iwamoto et al.   ACS Catalysis

Room-Temperature Electrocatalytic Synthesis of NH3 from H2O and N2 in a Gas–Liquid–Solid Three-Phase Reactor

(2017) Shiming Chen et al.   ACS Sustainable Chemistry & Engineering

Electrochemical Synthesis of NH3 at Low Temperature and Atmospheric Pressure Using a γ-Fe2O3 Catalyst

(2017) Jimin Kong et al.   ACS Sustainable Chemistry & Engineering

Progress and Perspective of Electrocatalytic CO2 Reduction for Renewable Carbonaceous Fuels and Chemicals

(2017) Wenjun Zhang et al.   Advanced Science

Thermodynamic Constraints in Using AuM (M = Fe, Co, Ni, and Mo) Alloys as N2 Dissociation Catalysts: Functionalizing a Plasmon-Active Metal

(2016) John Mark P. Martirez et al.   ACS Nano

Electrochemical Reduction of N2under Ambient Conditions for Artificial N2Fixation and Renewable Energy Storage Using N2/NH3Cycle

(2016) Di Bao et al.   ADVANCED MATERIALS

Electrochemical Ammonia Synthesis—The Selectivity Challenge

(2016) Aayush R. Singh et al.   ACS Catalysis

Engineering of Carbon-Based Electrocatalysts for Emerging Energy Conversion: From Fundamentality to Functionality

(2015) Yao Zheng et al.   ADVANCED MATERIALS

Recent Progress in Cobalt-Based Heterogeneous Catalysts for Electrochemical Water Splitting

(2015) Jiahai Wang et al.   ADVANCED MATERIALS

Carbon-Supported Pt-Based Alloy Electrocatalysts for the Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells: Particle Size, Shape, and Composition Manipulation and Their Impact to Activity

(2015) Yan-Jie Wang et al.   CHEMICAL REVIEWS

From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis

(2015) Andrew J. Medford et al.   JOURNAL OF CATALYSIS

Enabling electrochemical reduction of nitrogen to ammonia at ambient conditions through rational catalyst design

(2015) Younes Abghoui et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Galvanic deposition of Rh and Ru on randomly structured Ti felts for the electrochemical NH3 synthesis

(2015) Kurt Kugler et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Electroreduction of N2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments

(2015) Younes Abghoui et al.   ACS Catalysis

Challenges in reduction of dinitrogen by proton and electron transfer

(2014) Cornelis J. M. van der Ham et al.   CHEMICAL SOCIETY REVIEWS

Identification of a spin-coupled Mo(iii) in the nitrogenase iron–molybdenum cofactor

(2014) Ragnar Bjornsson et al.   Chemical Science

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

(2013) K. Cory MacLeod et al.   Nature Chemistry

Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction

(2013) Di Zhu et al.   NATURE MATERIALS

Electron transfer in nitrogenase catalysis

(2012) Lance C Seefeldt et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Electrochemical Hydrogen Evolution: Sabatier’s Principle and the Volcano Plot

(2012) Anders B. Laursen et al.   JOURNAL OF CHEMICAL EDUCATION

Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store

(2012) Masaaki Kitano et al.   Nature Chemistry

Theory of the transition from sequential to concerted electrochemical proton–electron transfer

(2012) Marc T. M. Koper   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Recent advances in electrocatalysts for electro-oxidation of ammonia

(2012) C. Zhong et al.   Journal of Materials Chemistry A

A theoretical evaluation of possible transition metal electro-catalysts for N2reduction

(2011) Egill Skúlason et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Reactivity Theory of Transition-Metal Surfaces: A Brønsted−Evans−Polanyi Linear Activation Energy−Free-Energy Analysis

(2009) Rutger A. van Santen et al.   CHEMICAL REVIEWS