期刊
NANO ENERGY
卷 69, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2019.104398
关键词
Polymer electrolyte; Aramid nanofiber; Ion conductance; Mechanical property; Lithium ion battery
类别
资金
- Natural Science Foundation of Beijing Municipality [L172036]
- Ministry of Education [6141A020225]
- Par-Eu Scholars Program
- Science and Technology Beijing 100 Leading Talent Training Project
- China Postdoctoral Science Foundation [2018M631419]
- Fundamental Research Funds for the Central Universities [2017ZZD02, 2019QN001]
- NCEPU Double First-Class Graduate Talent Cultivation Program
- Joint Funds of the Equipment Pre-Research [6141A020225]
Satisfactory ionic conductivity and mechanical stability are the prerequisites for the applications of solid polymer electrolytes in Li-ion batteries. Herein, by using aramid nanofibers (ANFs) as multifunctional nano-additives, comprehensively-upgraded polyethylene oxide (PEO)-LiTFSI electrolytes with 3D ANF network frames are achieved through the hydrogen-bond interactions between the 1D ANFs. The hydrogen-bond interactions between the ANFs and the PEO chains and TFSI- anions can greatly prevent the ANF agglomeration, suppress the PEO crystallization, facilitate the LiTFSI dissociation, and prolong the ion transport paths at the 3D ANF framework/PEO-LiTFSI interfaces. Thus, the ANF-modified electrolytes show superior room-temperature conductivity of 8.8 x 10(-5) S cm(-1). The ANF-containing composite electrolytes also display greatly-enhanced mechanical strength, thermostability, electrochemical stability and interfacial resistance against Li dendrites, attributed to the 3D ANF framework. In consequence, the composite electrolyte-based LiFePO4/Li cells exhibit better rate performance and cycling stability (e.g., 135 mAh g(-1) after 100 cycles at 0.4 C). This work offers a novel and effective strategy to comprehensively upgrade polymer electrolytes by employing organic nanofillers in the composite electrolyte design and revealing the ion transport mechanism for promising all-solid-state Li-ion battery applications.
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