期刊
ACS CATALYSIS
卷 10, 期 2, 页码 1621-1627出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b04222
关键词
photoredox; chromium; dual catalysis; 1,3-diene; alkene difunctionalization; radical-polar crossover
资金
- Alfried Krupp von Bohlen and Halbach Foundation
- Alexander von Humboldt Foundation
- Deutsche Forschungsgemeinschaft (Leibniz Award)
The direct conversion of feedstock chemicals into value-added products is of broad interest in chemical research. Herein, we present a regioselective and diastereoselective three-component dialkylation of feedstock 1,3-dienes with Hantzsch esters and aldehydes for the synthesis of homoallylic alcohols. The reaction is enabled by dual photoredox and chromium catalysis and can also be performed enantioselectively by employing chromium-bisoxazoline complexes.
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