期刊
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
卷 122, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.trac.2019.115719
关键词
Pesticide; Enantiomer; Enantioselective; Chiral analysis; Chiral stationary phase; Liquid chromatography; Supercritical fluid chromatography; Gas chromatography; Mass spectrometry; Capillary electromigration techniques
资金
- Sao Paulo Research Foundation [2014/50945-4, 2016/15680-5, 2018/14668-7, 2018/07534-4]
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq - INCT-DATREM) [465571/2014-0]
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
The potential of chiral pesticides to exhibit stereoselective behavior in regards to activity, toxicity, degradation, bioaccumulation, and/or metabolism has inspired numerous studies, e.g., several works have investigated the contamination of water, food, and soil by chiral pesticides and the consequences of non-targeted species (including human) exposure to these chemicals. As these studies typically rely on enantioselective separation methods such as liquid chromatography, supercritical fluid chromatography, gas chromatography, and capillary electromigration techniques, this review aims to provide a critical point of view on these analytical techniques used for the enantioselective analysis of pesticides. Accordingly, we selected papers from different areas and several issues (as chiral stationary phases or chiral selectors, mobile phases, and method detectability) regarding each technique were critically discussed. Finally, we outlined the future trends for each technique in the chiral analysis of pesticides. (C) 2019 Elsevier B.V. All rights reserved.
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