4.7 Article

Barium tungstate doped with terbium ion green nanophosphor: Low temperature preparation, characterization and potential applications

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2019.117928

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Ultrasound assisted hydrothermal method; Lanthanide; Green phosphor; Latent fingerprint; Anti-counterfeiting

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Production of Nano-Terbiumdoped bariumtungstate and its potential applications as a phosphor in forensic science and anti-counterfeiting ink applications have not been reported in the literature to now. Herein, simple, sensitive and bi-functional green Nanophosphor based on BaWO4: xTb(3+) was prepared and characterized for latent prints and anti-counterfeiting ink applications. High crystalline tetragonal BaWO4 phase was obtained with nano-spherical morphology. BWO: xTb(3+) Nanophosphors emits a strong and dual green and bluish green colors which appear to the human eye upon UVC and UVA excitation resources, respectively. The lifetime values were increasedwith rising Tb3+ ion concentrations from 0.01 to 0.07 mol. BWO: xTb(3+) Nanophosphor has successfully visualized latent print from various forensic non-porous and porous surfaces. Moreover, BWO: xTb(3+) Nanophosphor was used to develop luminescent ink for anti-counterfeiting application. (C) 2018 Elsevier B.V. All rights reserved.

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