Article
Materials Science, Coatings & Films
Xingyu Wang, Zhibin Lin
Summary: In this study, a nanocomposite coating was developed using hybrid nanofiller reinforcement and modified polymeric resin, significantly improving its overall performance, including chemical stability, mechanical robustness hydrophobicity, corrosion resistance, and mechanical properties.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Construction & Building Technology
Kaiyi Wang, Naijin Bu, Qiang Zhen, Jingbo Liu, Sajid Bashir
Summary: A transparent superhydrophobic organic-inorganic composite coating was prepared to protect ancient bricks from micro-organisms and weathering. The composite coating, consisting of fluorinated B72 and methyl-modified silica/titania, demonstrated enhanced performance against weathering, bacteria, and algae. By coating the bricks with the composite, the weathering process can be slowed without altering the bricks' outward appearance, providing a non-destructive way to protect ancient buildings.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Chemistry, Applied
Yangshuhan Xu, Daming Gao, Qiang Dong, Minghua Li, Anqiu Liu, Xiaochen Wang, Shufen Wang, Qiao Liu
Summary: In this study, hydrophobic and hydrophilic nano-silica modified epoxy coatings were used to protect carbon steel from corrosion. The results demonstrated that adding hydrophobic nano-silica significantly enhances the anticorrosive performance of epoxy coatings.
PROGRESS IN ORGANIC COATINGS
(2021)
Article
Chemistry, Applied
Xiaoyan Li, Xinsheng Niu, Yaowei Chen, Kai Yuan, Wenjun He, Shengbing Yang, Tingting Tang, Deng-Guang Yu
Summary: Chitosan-functionalized nanosilica was electrosprayed on a spin-coated base layer to form a composite coating with a micro-nano protruding surface, showing good antibacterial properties and sustained release effect. Nanosilica with uniform size was prepared by sol-gel method and coated with quaternized chitosan. The composite coating exhibited a unique micro-nano surface structure and the contact sterilization of chitosan quaternary ammonium salt played a synergistic effect, resulting in good sterilization effect on drug-resistant Staphylococcus aureus and controlled sustained release of quaternized chitosan.
PROGRESS IN ORGANIC COATINGS
(2023)
Article
Chemistry, Applied
Mateus Lenz Leite, Philipp Schlesinger, Michael Sheridan, Mohamad Zahedtalaban, Daniel Seitz, Stefan Schaffoener, Guenter Motz
Summary: The study combines hydrophobic properties with germicidal properties in a coating to prevent bacterial infection, providing an important approach for preventing the spread of bacteria.
PROGRESS IN ORGANIC COATINGS
(2022)
Article
Metallurgy & Metallurgical Engineering
M. Kalaiyarasan, S. Pugalmani, N. Rajendran
Summary: Biocompatible chitosan and chitosan/silica hybrid coatings were prepared to enhance the biocompatibility and corrosion resistance of biodegradable AZ31 Mg alloy. The optimized coatings showed high corrosion resistance and the chitosan/silica hybrid coating had a small globular rough structure. The presence of functional groups was confirmed by ATR-IR, and the chemical states were examined by XPS studies. The coated samples exhibited a dense layer of coral-like structure and less stoichiometric ratio of calcium-deficient apatite in Earle's solution. In-vitro cell culture studies showed good cell proliferation and the Ch-3/Si coating was non-hemolytic. Bacterial studies demonstrated the inherent antibacterial activity of the Ch-3/Si coating.
JOURNAL OF MAGNESIUM AND ALLOYS
(2023)
Article
Chemistry, Physical
I. A. Wonnie Ma, Sh Ammar, Shahid Bashir, Sachin S. A. Kumar, K. Ramesh, S. Ramesh
Summary: The study revealed that incorporating a hybrid of chitosan and silica into epoxy resin increased the wettability and transparency of the composite coatings, while also showing an active barrier effect on the metal surface when exposed to corrosive medium.
SURFACES AND INTERFACES
(2021)
Article
Chemistry, Physical
Hongyu Dong, Yingqing Zhan, Yiwen Chen, Yinlong Li, Ao Sun, Ximin Chen, Fei Zhu, Hongshan Jia
Summary: In this study, a hydrophobic and anticorrosive graphene oxide-based epoxy composite coating was developed using binary nano-fillers. The combination of graphene oxide and nano-silica improved the dispersion and compatibility of the epoxy coating, resulting in enhanced hydrophobicity and anti-corrosion performance.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Energy & Fuels
Jiawen Liu, Shibin Wang, Le He, Peng Hu, Yang Gao
Summary: A nanohybrid polymer (PAAM@SNP) was synthesized and showed excellent viscoelastic, temperature resistance, and shear resistance properties for polymer flooding. It tended to make rocks water wet and improved oil recovery performance, being more advantageous and cost-effective than traditional PAAM in enhanced oil recovery applications.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Biophysics
Mariangel Luna, Osvaldo Beltran, David A. Encinas-Basurto, Manuel G. Ballesteros-Monrreal, Antonio Topete, Natalia Hassan, Marco A. Lopez-Mata, Viviana Reyes-Marquez, Miguel A. Valdez, Josue Juarez
Summary: Bacterial infections have become a major global public health issue, especially with the rise of multi-drug resistant strains. The development of hydrophobic chitosan nanoparticles loaded with carvacrol showed promising antibacterial activity against both Gram-negative and Gram-positive bacteria, with potential application as novel biomaterials for treating bacterial infections.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2022)
Article
Engineering, Environmental
Li Long, Yaqian Fan, Xue Yang, Xiaokang Ding, Yang Hu, Guochao Zhang, Fu-Jian Xu
Summary: Flexible coating materials have been developed for the functionalization of biomedical devices. In this study, a cationic coating material called AQTA was constructed and used to functionalize medical devices for antibacterial and hemostatic applications. Stable AQTA coatings with tunable contents were easily achieved using a one-step soaking process. The high-content AQTA coating showed high blood compatibility and antibacterial ability on a polyurethane substrate. The hemostatic ability of AQTA was confirmed by improved properties of functionalized alginate dressing and gauze. The hemostatic mechanism of AQTA for negatively charged dressings was found to be optimized surface-activated platelet adhesion.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Applied
Ujjal Kumar Dey, Pradipta Sankar Maiti, Tapas Koley, Tapan Kumar Dhar, Tirthankar Jana
Summary: A novel organic-inorganic nanohybrid resin was synthesized through a sol-gel process using nano magnesium oxide and specially designed acrylic resin. The uniqueness of this process lies in the incorporation and dispersion of nano magnesium oxide into the acrylic resin matrix where it functions as a component. Magnesium oxide nanoparticles were successfully synthesized using magnesium nitrate as a precursor. The synthesized nanoparticles and their distribution in the acrylic resin matrix were confirmed through spectroscopic, X-ray diffraction, and SEM analysis. Coatings based on this hybrid resin demonstrated excellent antimicrobial activity, making it a potential candidate for antimicrobial coating applications.
JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH
(2023)
Article
Polymer Science
Jinglu Xu, Jihu Wang, Shaoguo Wen, Shengnan Ding, Jia Song, Sihong Jiang, Haopeng Wang
Summary: Hydrophobic fumed silica (HFS) was investigated for its dispersion technology in this study. The size and structure of HFS primary particles were observed using transmission electron microscopy (TEM). The particle size and dispersion performance of HFS were tested using dynamic light scattering (DLS), while the elemental distribution of the coatings was characterized using energy dispersive spectroscopy (EDS). The results showed that HFS in a non-ionic polymer dispersant exhibited the best dispersion performance, and the particle size of HFS in the aqueous dispersion was influenced by dispersion conditions. Under optimized conditions, a HFS aqueous dispersion with a particle size of D50 = 27.2 nm could be prepared, and it showed stable storage stability even after 47 days.
Article
Polymer Science
V. S. Benitha, K. Jeyasubramanian, B. Vijayakumari, V. S. Prabhin
Summary: The advent of organic polyester alkyd resin has revolutionized the coating industry, and the incorporation of CaF2 Nps in the polyester alkyd coating provides good antibacterial and anticorrosive properties, making it suitable for multifunctional coating applications.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Review
Biochemistry & Molecular Biology
Roohallah Saberi Riseh, Masoumeh Vatankhah, Mohadeseh Hassanisaadi, John F. Kennedy
Summary: The long-term and indiscriminate use of synthetic pesticides to mitigate plant pathogens has created serious issues of water health, soil contamination, non-target organisms, resistant species, and environmental and human health hazards. To reduce dependency on synthetic chemicals, scientists have developed alternative plant disease management strategies, with biological agents and resistance elicitors being the most important alternatives in the past two decades. Silica-based materials/chitosan with a dual mode of action have shown promise as alternatives to prevent plant diseases through direct and indirect mechanisms.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Applied
Heena, Komal Sharma, Kamlesh Kumar, Bhargab Das, Raj Kumar
Summary: In this study, holographic films were prepared using an automatic film applicator, and their performance was compared with films prepared by other methods. The results showed that holographic films prepared with the automatic film applicator had higher diffraction efficiency and more uniform thickness, making them suitable for holographic applications.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Athira S. Vijayan, Antony Joseph, Abey Joseph, T. S. Abhijith, Baiju G. Nair, V. Sajith
Summary: Novel polydopamine functionalized ceria-zirconia nanoparticles filled water-borne epoxy nanocomposite coatings were developed to prevent microbial-induced corrosion of mild steel. The coatings exhibited exceptional anti-biofouling and anti-biocorrosion properties due to the synergistic effect of PDA functionalization and zirconium incorporation, providing significant enhancement in charge transfer resistance and coating resistance.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yudan Yi, Qingyong Sun, Qijun Li, Bi Shi, Ya-nan Wang
Summary: Producing metal-free leather is an effective approach to eliminate Cr pollution and achieve sustainable development of the leather industry. However, current metal-free tanning technologies have limitations in terms of water sorption and charge properties. By using cationic amphiphilic acrylic copolymers (PSD) as retanning agents, the properties of metal-free leather can be significantly improved, including enhanced hydrophobicity, better dye absorption, and excellent filling effect.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yunqing Xia, Lifen Tong, Xiaofang Feng, Hubing Xiang, Yi He, Xiaobo Liu
Summary: By incorporating functionalized nanofillers, such as polydopamine-modified graphitic carbon nitride and cerium oxide, into epoxy coatings, their corrosion resistance can be improved and their protective period can be extended.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Weineng Lu, Guanhao Ma, Jinqing Qu
Summary: Four novel bis-chalcone-based carbazole derivative photoinitiators were designed and synthesized in this study. Their maximum absorption wavelengths were determined and found to exhibit high molar extinction coefficients. Furthermore, a three-component photoinitiation system including bis-chalcone/iodonium/amine was successfully used to trigger the rapid and efficient photopolymerization of acrylates. The photoinitiators also showed good photo bleaching and biocompatibility, making them suitable for applications such as 3D printing and deep coating curing.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Xingnan Zhou, Shixian Zhang, Yiheng Song, Hongmei Qin, Chuanxi Xiong, Shan Wang, Quanling Yang, Delong Xie, Rong Fan, Dan Chen
Summary: In this study, eco-friendly 3-amino-1,2,4-triazole (ATA) molecules were used to modify graphene oxide (GO) nanosheets for improving the anti-corrosion performance of water-borne epoxy (WEP) coating. The results show that ATA modification enhances the dispersion of GO in the polymer coating and significantly improves the barrier effect.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Hao Fu, Wei Bing, Xushibojie Liu
Summary: In this study, temperature-sensitive coatings with bacteria-killing and bacteria-releasing functions were prepared on silicone rubber surfaces by UV polymerization and UV photocatalysis. The modified surface exhibited strong and persistent bactericidal effect, inhibiting the formation of bacterial biofilm. Moreover, the smart surface can effectively release bacteria and resist bacterial adhesion through temperature changes. The modified silicone rubber surface showed good biocompatibility without cytotoxicity.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Lee Eyann, Zulkifli Mohamad Ariff, Mohamad Danial Shafiq, Raa Khimi Shuib, Muhamad Sharan Musa
Summary: By investigating the effect of MAA addition on the properties of the WEA core-shell emulsion, film and coating, it was found that MAA can significantly impact the structure and performance of the coatings, and has great potential for applications.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Jinkyu Choi, Kyung Hoon Min, Byeong Seok Kim, Sung-Hyeon Baeck, Sang Eun Shim, Yingjie Qian
Summary: A novel phosphorus-based flame retardant was designed by incorporating aryl groups, which effectively improved the flame retardancy and mechanical properties of polyurethanes.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Saowaluk Taechutrakul, Thananchai Piroonpan, Beata Paulina Rurarz, Slawomir Kadlubowski, Piotr Ulanski, Wanvimol Pasanphan
Summary: This study proposes the use of nanogels to disperse and stabilize water-insoluble organic pigment particles in water-based inks. The nanogels were prepared using electron beam-induced chemical reactions and showed good dispersion and stabilization properties. The use of nanogels in ink formulation improved the ink's hiding power, lightfastness, and resistance properties.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Shan Wan, Huikai Chen, Bokai Liao, Xingpeng Guo
Summary: In this study, 2-amino-5 mercapto-1,3,4-thiadiazole (ATT) was used as an intercalating agent to prepare ATT/BNNS nanofillers via a liquid-phase assisted ultrasound method. TEM results showed that ATT successfully exfoliated BNNS and reduced agglomeration. The WEP ATT/BNNS coating exhibited the best protective performance under saline immersion due to the combined action of ATT inhibitor and BNNS physical barrier.
PROGRESS IN ORGANIC COATINGS
(2024)
Review
Chemistry, Applied
Lijie Yin, Bo Zhang, Ming Tian, Nanying Ning, Wencai Wang
Summary: This paper reviews the recent progress in the synthesis of bio-based waterborne polyurethanes (BWPU) and focuses on its applications in coatings, adhesives, and antimicrobials. BWPU has attracted much attention due to its good physical and chemical properties, no VOCs emissions, exploitation of renewable substances, and structural design-ability.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yuyang Zhou, Yang Chen, Xinming Cao, Haodong Fu, Yun Li, Yonghui Zhang, Jun Ma, Xin Liu
Summary: This study proposes a strategy to fabricate a high-strength double-layer superhydrophobic actuator, which consists of a metal/glass-based superhydrophobic substrate and a polymer superhydrophobic coating. The coating has high adhesive strength, self-cleaning, anti-ultraviolet irradiation, and anti-stripping properties, along with photothermal and magnetic response capabilities, enabling its application in various fields.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Fengbiao Chen, Fei Gao, Xinru Guo, Yu Chen, Xuelang Gao, Liang Shen
Summary: In this study, various covalent adaptable networks (CANs) were synthesized using multifunctional amines and compared with CANs prepared from primary and secondary amines. The results showed that the performance of CANs is closely related to the crosslinking density, and increasing the content of secondary amines improves the performance but weakens the dynamics.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Qian Zhang, Mengyi Shen, Xingcai Liu, Hao Fu, Wenbo Yang, Jinyuan Zhao, Jian Wang, Yaping Du, Chunjie Ma
Summary: Rare earth-containing corrosion inhibitors were successfully synthesized and added into epoxy coatings for the anti-corrosion of steel materials. The results showed that the coatings with rare earth elements had better anti-corrosion performance, and this difference in performance could be explained by the inherent properties of rare earth elements.
PROGRESS IN ORGANIC COATINGS
(2024)