期刊
PROGRESS IN ORGANIC COATINGS
卷 138, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2019.105428
关键词
Sol-gel coating; AA2024; Corrosion; Montmorillonite; Cerium salts; EIS
资金
- ARES-CCD (Belgium)
This work presents a new approach to develop protective pre-treatment for AA2024 based on the inhibitor efficiency of cerium ions which are considered as a promising alternative to replace chromate compounds. The inhibition properties of cerium salts for improving the anti-corrosion performance of AA2024 have been characterized by polarization curves and EIS measurements. Cerium ions were inserted into nanoclays platelets by cationic-exchange reactions (CeMMT). XRD analysis proved the presence of cerium ions intercalated into clay structure. EIS measurements and polarization curves highlighted a high corrosion inhibition effect of cerium-modified nanoclays. This effectiveness can be related to the release of 60% of cerium ions from CeMMT structure in sodium chloride as determined by UV-vis measurements. Salt spray test made on scratched sol-gel samples indicated a self-healing effect of cerium ions which provide an active corrosion protection to aluminum substrate. EIS measurements revealed that hybrid sol-gel films doped with CeMMT improve barrier properties and anticorrosion protection of aluminum 2024 substrate.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据