期刊
ORGANOMETALLICS
卷 39, 期 1, 页码 165-171出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.9b00716
关键词
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资金
- National Natural Science Foundation of China [21962004, 21961002, 21562004]
- Jiangxi Education Hall Science and Technology Foundation [GJJ180801, GJJ170867, GJJ150944]
- Jiangxi provincial department of science and technology [20192BAB203004, 20161BAB213059]
- Fundamental Research Funds for Gannan Medical University [PY201301, QD201810, QD201816, QD201832]
An efficient chemoselective iridium-catalyzed method for the hydroxylation and alkoxylation of organosilanes to generate hydrogen gas and silanols or silyl ethers was developed. A variety of sterically hindered silanes with alkyl, aryl, and ether groups were tolerated. Furthermore, this atom-economical catalytic protocol can be used for the synthesis of silanediols and silanetriols. A one-pot silane oxidation and chemoselective reduction of aldehydes/ketones was also realized.
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