期刊
ORGANIC LETTERS
卷 22, 期 2, 页码 505-509出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04269
关键词
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资金
- National Natural Science Foundation of China [21871234]
- Natural Science Foundation of Zhejiang Province for Distinguished Young Scholars [LR15H300001]
Various functionalized tribenzo[b,d,f]azepines were prepared efficiently with the readily available 2-aminobenzoic acids and cyclic hypervalent diaryliodonium reagents as starting materials under Pd(II) catalysis. The key of this step-economical protocol is that the carboxylic acid functionality was employed as both a traceless directing group for the N-H activation/arylation and a functional handle for the tandem pi-extended decarboxylative annulation.
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