Article
Chemistry, Physical
Muhammad Humayun, Wenbo Pi, Yang Yuan, Lang Shu, Junhao Cao, Abbas Khan, Zhiping Zheng, Qiuyun Fu, Yahui Tian, Wei Luo
Summary: The ternary composite based on g-C3N4 (CeO2/CN/NH2-MIL-101(Fe)) exhibited superior photocatalytic activities for H2O reduction to produce H-2 and degradation of 2,4-dichlorophenol (2,4-DCP). The enhanced photoactivities were attributed to the synergistic effects of proper band alignment and close interfacial contact of the three components, which significantly promoted charge transfer and separation. The degradation of 2,4-DCP over the composite was found to be primarily dominated by (OH)· radical, as confirmed by scavenger trapping experiments and electron para-magnetic resonance (EPR) study.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Review
Chemistry, Multidisciplinary
Xiao Zhang, Ping Yang
Summary: This review summarizes the latest progress in the development of few-layered graphitic carbon nitride (g-C3N4) nanosheets based composite materials for photocatalytic H-2 generation and CO2 reduction, with a focus on nanoarchitectonics. The photocatalytic activity of these composites depends on the composition, morphology, and microstructure of the material. The review covers the enhanced photogenerated carrier separation and transfer, extended light absorption, mechanism, and progress in the study of various g-C3N4 based heterostructures, as well as the challenges and recommendations for future studies.
Article
Chemistry, Physical
Syed Ul Hasnain Bakhtiar, Amir Zada, Fazal Raziq, Sharafat Ali, Muhammad Ishaq Ali Shah, Muhammad Ateeq, Muhammad Khan, Dang Alei, Perveen Fazil, Mohammad Naeem, Waliullah Khan, Javed Ali Khan, Ruqia Nazir, Wen Dong, Qiuyun Fu
Summary: In this study, the high charge conductivity and wide range solar light absorption of metal phthalocyanines were utilized for enhanced photocatalysis. Graphitic carbon nitride was synthesized from melamine and loaded with zinc phthalocyanine to form ZPCN nanocomposites. These nanocomposites demonstrated exceptional catalytic activity in liberating hydrogen and decomposing a pollutant under visible-light irradiation, which is attributed to the efficient generation of superoxide ions and holes through charge transfer between g-C3N4 and ZnPc.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Balaji B. Mulik, Balasaheb D. Bankar, Ajay Munde, Parag P. Chavan, Ankush Biradar, Bhaskar R. Sathe
Summary: In this study, highly efficient g-C3N4 and ZnO decorated g-C3N4 hybrid nanostructures were synthesized for electrochemical and thermal reduction of CO2 reactions, with excellent yields. A plausible reaction mechanism for hydrogenation of CO2 to formate synthesis was proposed based on the investigations.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Chao Yang, Yanting Hou, Guoqiang Luo, Jiaguo Yu, Shaowen Cao
Summary: The hydrophobic alkyl groups planted onto g-C3N4 enhance its photocatalytic CO2 reduction performance by increasing its CO2 capture capacity, increasing active sites, and improving the separation of photoinduced excitons.
Review
Chemistry, Multidisciplinary
Qingqing Lu, Kamel Eid, Wenpeng Li, Aboubakr M. Abdullah, Guobao Xu, Rajender S. Varma
Summary: The article discusses the advantages and applications of graphitic carbon nitride (g-C3N4) as a catalyst for the carbon dioxide reduction reaction. It highlights the rational structural engineering and mechanistic analysis, providing a comprehensive summary of research in this area.
Article
Materials Science, Multidisciplinary
Junxia Wang, Changliang Guo, Yong Jiang, Jiafeng Wan, Bing Zheng, Yuxin Li, Baojiang Jiang
Summary: This study has developed an efficient and environmentally friendly strategy for H2O2 production and improved photocatalytic activity through the formation of a heterojunction. This method has scientific and practical value for environmental remediation.
SCIENCE CHINA-MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Weinan Xing, Yichi Zhang, Ke Cheng, Jinghui Zou, Guangyu Wu
Summary: Novel carbon species were incorporated into porous g-C3N4 nanosheet framework using a sustainable and ecofriendly strategy, resulting in enhanced light adsorption, reduced band gap energy, increased separation efficiency of photoproduction charge carriers, and superior photocatalytic performance.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Physical
Daochuan Jiang, Taotao Wang, Muqing Chen, Jinbao Wu, Pingwu Du
Summary: Accelerating charge separation and transfer and increasing visible light absorption are crucial for efficient photocatalytic hydrogen production via water splitting. In this study, we fabricated an in-plane graphited nanocarbon-conjugated polymeric carbon nitride (GNC-C3N4) nanosheet heterostructure photocatalyst for the first time. The incorporation of GNC into the conjugate network of C3N4 significantly enhanced light harvesting and improved charge separation and transfer through the built-in electric field and intimate interface. The optimized GNC-C3N4 photocatalyst exhibited over 15-fold enhancement in photocatalytic hydrogen evolution from water under visible light irradiation compared to C3N4.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Inorganic & Nuclear
Manas Ranjan Pradhan, Dharitri Rath, Ratikanta Sethi, Braja B. Nanda, Binita Nanda
Summary: The introduction of MnO2 onto the g-C3N4 nanosheets significantly enhances the photocatalytic performance, with 3 wt% MnO2 modification showing the highest oxidation efficiency towards aromatic alcohols. This enhancement is attributed to heterojunction formation and the generation of active charged species responsible for the oxidation of aromatic alcohols through a free radical mechanism under visible light.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Xiaoli Wu, Xulin Cui, Qi Wang, Jingtao Wang, Wenjia Wu, Wenpeng Li, Zhongyi Jiang
Summary: Functionalized g-C3N4 nanosheets were used to build lamellar membranes with highly elevated polar solvent permeance and selectivity by subtly tuning the properties of cross-layer channels. The 'gate effect' of cross-layer channels can be intensified by increasing the thickness and total length, paving a way to designing efficient 2D nanochannel membranes.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Engineering, Environmental
Linhai Yang, Xuechang Ren, Yujie Zhang, Zuoyan Chen, Jianxin Wan
Summary: Cu+/g-C3N4 catalysts with unique structures, formed by embedding Cu+ in triazine-based g-C3N4 nanosheets, exhibit excellent Fenton-like catalytic performance under neutral conditions, showing great potential for applications in wastewater treatment.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Han Li, Fang Li, Jiaguo Yu, Shaowen Cao
Summary: The synthesis of g-C3N4 nanosheets with a large specific surface area and loading a 2D FeNi layered double hydroxide (FeNi-LDH) cocatalyst onto them effectively enhances the CO2 reduction performance. The FeNi-LDH/g-C3N4 composite photocatalyst exhibits enhanced photo-absorption and CO2 adsorption capacity, leading to increased methanol production rate. The formation of a 2D/2D heterojunction on the surface of CN nanosheets promotes charge carrier separation and inhibits recombination, resulting in improved CO2 photo-reduction activity.
ACTA PHYSICO-CHIMICA SINICA
(2021)
Article
Engineering, Environmental
Yisa Zhou, Ya Zhang, Jian Xue, Rui Wang, Zongjie Yin, Li Ding, Haihui Wang
Summary: In this study, a continuous g-C3N4-GO membrane with excellent H2 permeation performance and good stability was successfully prepared by utilizing graphene oxide nanosheets to cover and repair defects in two-dimensional graphitic carbon nitride (g-C3N4) nanosheets.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Pengyan Li, Li Liu, Weijia An, Huan Wang, Wenquan Cui
Summary: By coupling thermal field and ionic liquids, a Cu2O/g-C3N4 heterojunction was constructed for photocatalytic CO2 reduction to ethanol, achieving higher efficiency. The ILs, specifically 1-aminopropyl-3-methylimidazolium bromide, showed superior CO2 reduction performance with a higher current density than KHCO3 electrolyte.
APPLIED SURFACE SCIENCE
(2021)
Review
Behavioral Sciences
Arshad Mehmood, Wajid Ali, Shuang Song, Zaheer Ud Din, Ruo-Yi Guo, Wahid Shah, Ikram Ilahi, Bowen Yin, Hongjing Yan, Lu Zhang, Murad Khan, Wajid Ali, Liaqat Zeb, Hamidreza Safari, Bin Li
Summary: The study demonstrates the potential of optical coherence tomography (OCT) in monitoring and diagnosing multiple sclerosis (MS) by showing changes in retinal structures that reflect the progression of the disease. OCT parameters serve as noninvasive and sensitive indicators for assessing neurodegeneration and inflammation in MS.
BRAIN AND BEHAVIOR
(2021)
Article
Chemistry, Physical
Muhammad Farooq Khan, Gerardo Cazzato, Hassan Anwar Saleemi, Romulo R. Macadangdang, Muhammad Nauman Aftab, Muhammad Ismail, Hira Khalid, Sharafat Ali, Syed ul Hasnain Bakhtiar, Ahmed Ismail, Muhammad Zahid
Summary: Sonophotocatalysis is an innovative technique for solar energy production and environmental remediation, with Pt/CeO2 nanocomposites showing high degradation efficiency and stability. This technology is credited to ultrasonic waves generating additional OH free radicals, making it a promising approach for future applications.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Multidisciplinary
Fazal Raziq, Amil Aligayev, Huahai Shen, Sharafat Ali, Rahim Shah, Sajjad Ali, Syedul H. Bakhtiar, Asad Ali, Naghat Zarshad, Amir Zada, Xiang Xia, Xiaotao Zu, Muslim Khan, Xiaoqiang Wu, Qingquan Kong, Chunming Liu, Liang Qiao
Summary: The construction of a one-photon Z-scheme system successfully stimulated two photocatalysts simultaneously, leading to a visible-light driven overall-water-splitting with enhanced performance. The utilization of density-functional theory helped understand the origin of this performance enhancement, providing a feasible strategy for practical applications of efficient one-photon Z-scheme.
Article
Chemistry, Physical
Sharafat Ali, Sajjad Ali, Pir Muhammad Ismail, Huahai Shen, Amir Zada, Asad Ali, Ismail Ahmad, Rahim Shah, Imran Khan, Junsong Chen, Chunhua Cui, Xiaoqiang Wu, Qingquan Kong, Jiabao Yi, Xiaotao Zu, Haiyan Xiao, Fazal Raziq, Liang Qiao
Summary: In this study, an efficient wide-spectrum solar light-driven photocatalyst based on solar UV-blind beta-Ga2O3 quadrilateral nanorods modified with cobalt phthalocyanine has been developed for H-2 evolution from water. The optimized 3CoPc/beta-GOR nanocomposite showed unprecedented quantum efficiency at 660 nm excitation wavelength, along with outstanding structural stability compared to the pristine beta-GOR.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Materials Science, Multidisciplinary
Tayiba Ilyas, Fazal Raziq, Nasir Ilyas, Liuxin Yang, Sharafat Ali, Amir Zada, Syedul Hasnain Bakhtiar, Yong Wang, Huahai Shen, Liang Qiao
Summary: This study designed a FeNi@CNS nanocomposite as an efficient nitrogen reduction catalyst, which showed excellent performance and stability under ambient conditions. The catalyst exhibited remarkable NRR activity, promoted N-2 adsorption and activation, and effectively suppressed competitive HER. Therefore, the FeNi@CNS catalyst has significant potential in industrial applications of nitrogen reduction.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Fazal Raziq, Khakemin Khan, Sajjad Ali, Sharafat Ali, Hu Xu, Ijaz Ali, Amir Zada, Pir Muhammad Ismail, Asad Ali, Habib Khan, Xiaoqiang Wu, Qingquan Kong, Muhammad Zahoor, Haiyan Xiao, Xiaotao Zu, Sean Li, Liang Qiao
Summary: Perovskite semiconductors with high symmetry anisotropic facets were synthesized using a flux-assisted technique. By surface doping of sulfur and carbon, the photocatalytic CO2 reduction activity of Sr2CoTaO6 was significantly enhanced.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Applied
Sajjad Ali, Pir Muhammad Ismail, Fazli Wahid, Anuj Kumar, Muhammad Haneef, Fazal Raziq, Sharafat Ali, Muhammad Javed, Riaz Ullah Khan, Xiaoqiang Wu, Haiyan Xiao, Gulam Yasin, Liang Qiao, Hu Xu
Summary: This study explores the electrocatalytic performance of two-dimensional metal-organic frameworks in CO2RR using density functional theory, and finds that the catalytic performance can be altered by changing the metal atom or organic ligands. The research provides important insights for designing and screening efficient CO2RR catalysts, and suggests the development of metal-organic frameworks with beneficial properties.
FUEL PROCESSING TECHNOLOGY
(2022)
Article
Chemistry, Inorganic & Nuclear
Umar Arif, Farman Ali, Ali Bahader, Sharafat Ali, Amir Zada, Fazal Raziq
Summary: This study developed a three-component photocatalyst hetero-junction of Ag-ZnO/g-C3N4 for efficient CO2 reduction. The optimized nano-composite exhibited exceptional visible-light photoactivity, increasing the conversion efficiency of CO2 to CO and methane production.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Review
Chemistry, Inorganic & Nuclear
Rahim Shah, Sharafat Ali, Fazal Raziq, Sajjad Ali, Pir Muhammad Ismail, Sayed Shah, Rashid Iqbal, Xiaoqiang Wu, Weidong He, Xiaotao Zu, Amir Zada, Adnan, Fazal Mabood, Ajayan Vinu, Sung Hwa Jhung, Jiabao Yi, Liang Qiao
Summary: Metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) have attracted significant attention as highly crystalline advanced permeable materials with large surface area, ordered pores/channels, and controllable structure. However, their low structural stability and electrical conductivities limit their applications in photocatalysis and energy storage/conversion. Extensive research has focused on maximizing their advantages and overcoming these limitations. This review article provides a background and timeline of COF/MOF development, discusses synthetic procedures, recent achievements, and milestones in CO2 reduction, hydrogen production, lithium-ion batteries, and supercapacitors, and explores the challenges and future prospects for high-performance COF/MOF materials in photocatalysis and electrochemical energy storage.
COORDINATION CHEMISTRY REVIEWS
(2023)
Article
Chemistry, Physical
Syed Ul Hasnain Bakhtiar, Amir Zada, Fazal Raziq, Sharafat Ali, Muhammad Ishaq Ali Shah, Muhammad Ateeq, Muhammad Khan, Dang Alei, Perveen Fazil, Mohammad Naeem, Waliullah Khan, Javed Ali Khan, Ruqia Nazir, Wen Dong, Qiuyun Fu
Summary: In this study, the high charge conductivity and wide range solar light absorption of metal phthalocyanines were utilized for enhanced photocatalysis. Graphitic carbon nitride was synthesized from melamine and loaded with zinc phthalocyanine to form ZPCN nanocomposites. These nanocomposites demonstrated exceptional catalytic activity in liberating hydrogen and decomposing a pollutant under visible-light irradiation, which is attributed to the efficient generation of superoxide ions and holes through charge transfer between g-C3N4 and ZnPc.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Rahim Shah, Sajjad Ali, Sharafat Ali, Pengfei Xia, Fazal Raziq, Adnan, Fazal Mabood, Sayed Shah, Amir Zada, Pir Muhammad Ismail, Asif Hayat, Ata Ur Rehman, Xiaoqiang Wu, Haiyan Xiao, Xiaotao Zu, Sean Li, Liang Qiao
Summary: Advanced electrode design is crucial for the development of flexible energy storage devices in flexible electronics. In this study, Ni(BDC-NH2)/reduced graphene oxide (rGO) composites were synthesized through a solvothermal method. The unique laminar and porous structure of Ni(BDC-NH2) MOFs facilitated Li-ion diffusion, leading to faster electrode activation and improved electrochemical performance. The freestanding Ni(BDC-NH2)/rGO composite electrode exhibited a reversible capacity of 813 mAh g-1 at a current density of 200 mA g-1 after 100 cycles, surpassing the performance of Ni(BDC)/rGO MOFs.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Pir Muhammad Ismail, Sajjad Ali, Sharafat Ali, Jiahao Li, Min Liu, Dong Yan, Fazal Raziq, Fazli Wahid, Guojing Li, Shuhua Yuan, Xiaoqiang Wu, Jiabao Yi, Jun Song Chen, Qingyuan Wang, Li Zhong, Ye Yang, Pengfei Xia, Liang Qiao
Summary: Constructing Van der Waals heterojunction is crucial for achieving excellent photocatalytic activity. In this study, a phosphate-bridged Van der Waals heterojunction of cobalt phthalocyanine (CoPc)/tungsten disulfide (WS2) was designed and prepared, creating an efficient electron transfer channel and achieving significant enhancement in photocatalytic CO2 reduction.
ADVANCED MATERIALS
(2023)
Review
Energy & Fuels
Fazli Wahid, Sajjad Ali, Pir Muhammad Ismail, Fazal Raziq, Sharafat Ali, Jiabao Yi, Liang Qiao
Summary: With the increase in energy crisis and greenhouse effect, the development of efficient solar-driven photocatalytic systems for fuels/chemicals production is crucial. Single atom photocatalytic (SAP) systems, consisting of isolated single atoms (SAs) coordinated with a suitable support, have shown superior catalytic efficiency. This review discusses SAPs and the confining of metal SAs on 2D supports, highlighting recent advances, challenges, and future perspectives, aiming to provide ideas for the discovery of novel photocatalytic systems.
PROGRESS IN ENERGY
(2023)
Review
Materials Science, Multidisciplinary
Xiang Ding, Menglu Li, Pei Chen, Yan Zhao, Mei Zhao, Huaqian Leng, Yong Wang, Sharafat Ali, Fazal Raziq, Xiaoqiang Wu, Haiyan Xiao, Xiaotao Zu, Qingyuan Wang, Ajayan Vinu, Jiabao Yi, Liang Qiao
Summary: Bismuth oxyselenide (B(i)2O(2)Se) is a promising quasi-2D material with unique physical properties and excellent performance, making it suitable for applications such as field-effect transistors and photodetectors. Its ability to grow on various substrates establishes a connection between traditional epitaxy and emerging van der Waals epitaxy. This review provides an overview of its fundamental structure, physics, and physical properties, highlighting the correlation between electronic structure and material performance, and identifying current problems and challenges.
Article
Engineering, Environmental
Zaheen Ullah Khan, Wasid Ullah Khan, Bakhtar Ullah, Wajid Ali, Bilal Ahmad, Wajid Ali, Pow-Seng Yap
Summary: The study successfully developed an advanced PVC/PPD/GO composite paper-like material for efficient removal of heavy metals from wastewater, exhibiting strong stability, high recyclability, and simple preparation process. The enhanced morphology and formation of micro- and nano-channels contributed to the significantly improved heavy metal adsorption efficiency.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Materials Science, Multidisciplinary
A. Aly, M. Ghali, A. Osman, M. K. El Nimr
Summary: This study reports the discovery of naturally occurring luminescent graphene quantum dots (GQDs) in coconut water for the first time. The GQDs were identified through various measurements and were found to have dual sizes and emit different wavelengths of light. The GQDs were also utilized as an efficient optical sensor for aniline liquid detection.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Zehua Chen, Wencheng Ma, Qinglu Fan, Yanhua Liu, Min Sun, Shuo Wang
Summary: The nanoscale e-VOPO4 materials were successfully prepared by hydrothermal synthesis and calcination, showing high purity and suitable particle size. It exhibited satisfactory electrochemical performance as cathode material for sodium ion batteries, making it a potential candidate for high energy storage systems.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Tao Liu, Yahui Liu, Le Ling, Zhongxi Sheng, Zao Yi, Zigang Zhou, Yongjia Yang, Bin Tang, Qingdong Zeng, Tangyou Sun
Summary: In this paper, a terahertz (THz) micronano device that can switch between bimodal absorption and plasmon-induced transparency (PIT) is proposed. The device consists of layers of graphene, silica, and vanadium dioxide, and has a simple structure, easy tuning, and wide-angle absorption. The device achieves perfect absorption at specific frequencies and is highly sensitive to environmental refractive index. It also has the functions of a three-frequency asynchronous optical switch and slow light effect.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Xiaobo Luo, Songhan Hu, Qiudong Duan, Dacheng Zhou, Jialin Chen, Yugeng Wen, Jianbei Qiu
Summary: The exploration of solar light absorption by a material is important in photonics and optoelectronics. This study reveals the potential of Ba3-xGa2O6:xBi3+ as a promising candidate for various photonic and optoelectronic applications, and demonstrates the use of the material in double-sided laser printing for three-dimensional optical imaging.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Hemin Wang, Yanling Hao, Lele Xiang, Xiaosi Qi, Lei Wang, Junfei Ding, Yunpeng Qu, Jing Xu, Wei Zhong
Summary: This study designed Fe3O4-FeCO3/MWCNTs/RGO MCNCs composites and fabricated large-scale samples using hydrothermal and freeze-drying methods. The microstructural investigation showed that these materials had a mixed-dimensional structure, which improved impedance matching features, polarization, and conduction loss abilities, leading to significantly enhanced electromagnetic absorption properties.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Zhenshan Yu, Hao Chen, Xuequan Chen, Yu-Sheng Lin
Summary: This study presents a silicon dielectric metamaterial (SDM) composed of two outer symmetric semi-circular rings and two inner symmetric split-ring resonators (SRRs). The electromagnetic responses of the SDM device in different modes were studied through numerical simulations and experiments. Increasing the structure height of the SDM device resulted in red-shifted resonances and stronger intensities. This study provides a new design strategy for the development of frequency filtering, polarization switching, and resonance modulation characteristics in THz-wave applications.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Yiming Qi, Na Zhang, Meng Zong, Yangxianzi Liu, Weixing Chen
Summary: This study prepares dielectric/carbon fiber based nanocomposites wave-absorbing materials using liquid diffusion and high temperature carbonization strategies. By tuning the element type, drying mode, and filling amount, the electromagnetic parameters and absorbing properties can be adjusted. The best synthesized sample shows excellent absorbing performance, making it suitable for a wide range of electromagnetic wave absorption applications.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Carlos D. Gonzales-Lorenzo, T. K. Gundu Rao, Alberto A. Ccollque-Quispe, Jorge Ayala-Arenas, Monise B. Gomes, Betzabel N. Silva-Carrera, Roseli F. Gennari, Valeria S. Pachas, F. Monzon-Macedo, H. Loro, Jose F. D. Chubaci, Nilo F. Cano, Rene R. Rocca, Shigueo Watanabe
Summary: In this study, CaSiO3 doped with different ppm of Eu was synthesized using the devitrification method. Various physical properties were analyzed, revealing that the intensity and temperature of the high-temperature TL peak increased with higher dopant amounts. Fluorescence measurements indicated the presence of Eu2+ and Eu3+ ions in the samples. EPR spectra confirmed the existence of two defect centers.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Yanning Qu, Xinyang Li, Mei Cui, Renliang Huang, Wanquan Ma, Yunting Wang, Rongxin Su, Wei Qi
Summary: In this study, a new molybdenum disulfide/N,S-doped carbon quantum dots (MoS2/N,S-CQDs) heterojunction with enhanced light absorption and electrons transfer di-functional properties was constructed via a facile one-pot hydrothermal method. The heterojunction showed remarkable efficiencies in degrading methylene blue (MB) and malachite green (MG) in an actual water system under simulated sunlight irradiation. The facile synthetic technique and effective multifunctional properties of the composite have the potential for further research and industrial applications.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Jiayi Wang, Penggang Ren, Xueyan Zhao, Zhengyan Chen, Yanling Jin, Zengping Zhang
Summary: In this study, a novel homojunction photocatalyst was developed by combining defective g-C3N4 and flaked g-C3N4, which showed excellent degradation performance and cycling stability, and exhibited practicality in several simulation experiments.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Jing Yan, Xiaoxiao Zhao, Weixing Chen, Panbo Liu
Summary: This research presents a self-templated strategy to prepare a spherical superstructure of carbon nanorods through material modification and pyrolysis. The resulting material exhibits a large controllable radius of curvature and shows excellent microwave absorbing properties due to its high specific surface area and mesoporous structure.
MATERIALS RESEARCH BULLETIN
(2024)
Review
Materials Science, Multidisciplinary
Qinglin Zeng, Zepeng Lv, Shaolong Li, Bin Yang, Jilin He, Jianxun Song
Summary: Liquid metal batteries possess stable safety performance, high rate performance, and thermal stability. The electrolyte, an important component of the battery, plays a significant role in achieving these remarkable performance characteristics. This paper reviews the important research progress of liquid metal batteries electrolyte and discusses the influence of different electrolyte types on energy efficiency. It also highlights the limitations and challenges of existing electrolytes and proposes key development directions for liquid metal electrolytes.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Song Wu, Junli Wang, Xuanbing Wang, Di Jiang, Jinlong Wei, Xiaoning Tong, Zhenwei Liu, Qingxiang Kong, Naixuan Zong, Ruidong Xu, Linjing Yang
Summary: In this study, a composite electrode composed of Ti/TiH2/beta-PbO2_Mn3O4@C was fabricated and investigated for zinc electrowinning. The composite electrode exhibited low overpotential, Tafel slope, icorr, and high voltage stability, outperforming most reported Ti-based PbO2 electrode materials. The excellent catalytic activity can be attributed to the low resistance and porous interlayer of TiH2 nanosheets, as well as the addition of Mn3O4@C micro-flakes to the active layer.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
E. Tsoutsoumanos, T. Karakasidis, N. Laskaris, P. G. Konstantinidis, G. S. Polymeris, G. Kitis
Summary: This study investigates the correlation between nanocrystal dimensions and thermoluminescence signal magnitude through simulations conducted in Python. Two mathematical models, OTOR and IMTS, were used to derive theoretical luminescence signals. The obtained results were compared with experimental data and a thorough comparative discussion was conducted.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Materials Science, Multidisciplinary
Vishnu Aggarwal, Sudhanshu Gautam, Aditya Yadav, Rahul Kumar, Bipul Kumar Pradhan, Brajesh S. Yadav, Govind Gupta, Senthil Kumar Muthusamy, Sumeet Walia, Sunil Singh Kushvaha
Summary: Recently, there has been a great demand for highly responsive photodetectors that can detect a wide range of wavelengths. Researchers have successfully fabricated a broadband metal-semiconductor-metal photodetector by integrating sputtered Bi2Se3 with laser molecular beam epitaxy grown GaN film. This photodetector shows high responsivity in both the ultraviolet and near-infrared regions.
MATERIALS RESEARCH BULLETIN
(2024)
