期刊
MATERIALS CHARACTERIZATION
卷 161, 期 -, 页码 -出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2019.110099
关键词
Tin oxide; Kirkendall effect; Nanostructured material; Anode material; Lithium ion battery; Electrospinning
类别
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2019R1A2C2088047]
Hollow nanoplates-aggregated SnO2 nanofibers were fabricated from electrospinning process and two-step heat treatment. Se particles were dissolved in electrospinning solution and played a critical role in the formation of small-sized SnSe nanoplates during the selenization heat treatment. During the oxidation heat treatment, due to the well-known Kirkendall diffusion process, the dense SnSe nanoplates were transformed into hollow SnO2 nanoplates. Three other SnO2 nanostructures including SnO2 hollow nanoplates, hollow nanofiber with hierarchical SnO2 nanocrystals, and SnO2 hollow nanofibers were prepared as comparison. The capacity of hollow nanoplate-aggregated SnO2 nanofibers after the 700th discharge process was 375 mA h g(-1) when cycled at a high current density of 3 A g(-1), whereas those of the comparison SnO2 nanostructured electrodes in the order listed were 78, 277, and 262 mA h g(-1), respectively. The high structural stability of the synthesized hollow nanoplate-aggregated SnO2 nanofiber during repeated lithiation and delithiation processes resulted in lithiumion battery anode with longer cycle life.
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