Article
Chemistry, Physical
Patric Berger, Hans Flandorfer
Summary: Lithium containing alloy systems, especially the ternary Li-Sb-Sn system, are studied as potential electrode materials for lithium ion batteries. Experimental results show that SbSn can uptake up to 15 at.% Li, forming Li3Sb and confirming the ternary phase Li8SbxSn3-x.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Electrochemistry
Smobin Vincent, Jin Hyun Chang, Juan Maria Garcia Lastra
Summary: The main advantage of Mg batteries lies in their ability to work with a pure metallic anode, but the brittleness of pure Mg makes it difficult to produce thin foils. Alloying Mg with doping elements enhances its ductility, but dopants should not interfere with the electrochemical process. Preferably, dopants should stay in bulk or at a stacking fault to avoid surface migration. Among 34 dopants screened, only 12 energetically prefer to stay in bulk, including Y and Nd which are beneficial for Mg battery anode materials.
BATTERIES & SUPERCAPS
(2021)
Article
Nanoscience & Nanotechnology
Xize Chen, Shanghai Wei, Yigang Yan, Fanglei Tong, Geoffrey I. N. Waterhouse, Tilo Sohnel, Mark P. Taylor, Peng Cao
Summary: Magnesium rechargeable batteries (MRBs) are attracting attention due to their low cost, high safety, and high theoretical volumetric capacity. The use of eutectic and hypereutectic Mg-Sn alloys as anodes for MRBs was explored. The alloys exhibited unique microstructures and the dissolution processes were studied in an all-phenyl-complex (APC) electrolyte. Hypereutectic alloys showed better battery performance due to their superior mechanical properties.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Materials Science, Multidisciplinary
Hua-bao Yang, Liang Wu, Bin Jiang, Bin Lei, Ming Yuan, Hong-mei Xie, Andrej Atrens, Jiang-feng Song, Guang-sheng Huang, Fu-sheng Pan
Summary: The microstructure of Mg-Sn-Y alloys, including small grain size, uniform distribution of small second phase particles, and specific grain orientation, plays a crucial role in determining their discharge properties in Mg-air batteries. The presence of effective cathodes like Sn3Y5 and MgSnY phases promotes micro-galvanic corrosion, leading to the dissolution of the Mg matrix during discharge process.
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
(2021)
Article
Electrochemistry
Xize Chen, Shanghai Wei, Fanglei Tong, Mark P. Taylor, Peng Cao
Summary: In this study, the electrochemical performance of hypoeutectic Mg-Sn alloy anodes with all-phenyl complex (APC) electrolyte was investigated. The Mg14Sn alloy anode displayed different electrochemical behaviors compared to pure Mg, with lower resistance observed after 30 cycles.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Meijia Song, Yan Wang, Conghui Si, Wenrun Cui, Wanfeng Yang, Guanhua Cheng, Zhonghua Zhang
Summary: A strategy to regulate the electrochemical reactivity and performance of tin-based anodes for magnesium-ion batteries (MIBs) was proposed by introducing a second phase and phase boundary. Tin-aluminum (Sn-Al), tin-lead (Sn-Pb) and tin-zinc oxide (Sn-ZnO) films were fabricated and it was found that the addition of aluminum effectively stimulated the electrochemical reaction of tin with magnesium. The Sn-Al electrode exhibited superior long-term stability and good compatibility with magnesium salt-based electrolytes. This strategy was also applicable to lead and zinc oxide. These findings provide valuable insights for the development of alloy-type anodes for MIBs.
SCIENCE CHINA-CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
H. Khelidj, A. Portavoce, M. Bertoglio, M. Descoins, L. Patout, K. Hoummada, A. Hallen, A. Charai, M. C. Benoudia, D. Mangelinck
Summary: By depositing Ge1-xSnx thin films at higher temperatures using magnetron sputtering, it is possible to produce low-cost and CMOS-compatible layers with improved crystallinity. This method allows for the integration of optoelectronic and photonic devices based on Ge1-xSnx alloys in the CMOS technology, showing promise for future applications.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Energy & Fuels
Dong-Xing Song, Yan-Zheng Du, Wei-Gang Ma, Xing Zhang
Summary: In this study, functionalized MXene/graphene heterostructures are evaluated as promising anode materials for MIBs, showing great potential for two-layer Mg intercalation with low interlayer expansion and positive open-circuit voltages. The decreased Mg diffusion barriers in functionalized MXene/graphene heterostructures are expected to enhance the specific capacity and charge/discharge rate of MIBs.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Electrochemistry
Fanglei Tong, Xize Chen, Teik Ee Teoh, Shanghai Wei, Geoffrey I. N. Waterhouse, Wei Gao
Summary: The study found that the addition of tin to Mg alloys improves the operational voltage and battery discharge performance in magnesium-air batteries, with Mg-5Sn performing best at low current densities and Mg-1Sn delivering the best performance at high current densities.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Shuting Sun, Wenhui Wang, Fanrong Kong, Lin Li, Changsong Dai
Summary: Tin phosphide (Sn-P) based materials, including Sn4P3, are being explored as alternative anodes for alkali-ion batteries due to their stable phase and high theoretical capacity. However, the rapid capacity decay remains a challenge. Various strategies have been proposed to address this issue, such as designing nanostructures, constructing physical barriers, doping, and modifying the solid-electrolyte interphase layer. Future research directions and challenges in the development of Sn-P based anodes were also discussed in the review.
ENERGY STORAGE MATERIALS
(2021)
Article
Multidisciplinary Sciences
Alice J. Merryweather, Christoph Schnedermann, Quentin Jacquet, Clare P. Grey, Akshay Rao
Summary: The key to advancing lithium-ion battery technology, especially fast charging, lies in understanding dynamic processes in functioning materials under realistic conditions in real time. A laboratory-based optical interferometric scattering microscope was introduced to study nanoscopic lithium-ion dynamics in battery materials, allowing for high-throughput material screening. This methodology was applied to study various processes in battery materials, providing insights into battery degradation mechanisms.
Article
Metallurgy & Metallurgical Engineering
Fanglei Tong, Xize Chen, Shanghai Wei, Jenny Malmstrom, Joseph Vella, Wei Gao
Summary: The addition of Sn improves the electrochemical activity and efficiency of Mg-Zn alloy anodes, with Mg-2Zn-3Sn alloy showing the best performance at low current densities. The mixed film formed on the alloy surface reduces self-corrosion during discharging.
JOURNAL OF MAGNESIUM AND ALLOYS
(2021)
Article
Chemistry, Physical
Hui Liu, Yang Yan, Xiaohan Wu, Hongjie Fang, Xin Chu, Jiefeng Huang, Jiaxi Zhang, Juemin Song, Kun Yu
Summary: The study shows that the addition of Al and Sn can improve the microstructure of Mg-Al based anodes and reduce hydrogen evolution rate. Different effects were observed in different alloys, with the addition of Al promoting the dissolution of magnesium matrix, while Sn propagation of Mg2Sn phases along the grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Reyhan Solmaz, B. Deniz Karahan
Summary: This study presents a methodology to produce electrodes with superior performance for batteries, utilizing a ternary transition metal oxide anode material and a novel design involving magnetron sputtering of a Ni underlay thin film onto a Cu foil. Characterization results demonstrate improved adhesion, stress accommodation, and charge transfer resistance, leading to enhanced discharge capacities of the Ni/NMCO anodes compared to the NMCO anodes in galvanostatic tests. The results are expected to pave the way for designing electrodes for various battery applications, particularly solid state batteries, by considering the industrial applications of magnetron sputtering.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Xuehong Xu, Jin Zhang, Yunlai Deng
Summary: This paper investigates the discharge performance of Al-Mg-Sn alloy anodes with different Sn content for Al-air batteries in a 4 mol L-1 NaOH solution, and discusses their microstructure, corrosion behavior and discharge properties. It is found that Sn-rich phases in the Al matrix act as cathode, promoting the anode dissolution of the Al matrix and increasing electrochemical activity. The addition of Sn improves corrosion resistance and reduces the hydrogen evolution rate. However, excessive Sn-rich phases worsen hydrogen evolution corrosion and intergranular corrosion, leading to unsatisfactory discharge performance.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Meijia Song, Jiazheng Niu, Kuibo Yin, Hui Gao, Chi Zhang, Wensheng Ma, Fakui Luo, Zhangquan Peng, Zhonghua Zhang
Article
Chemistry, Applied
Fakui Luo, Congcong Wei, Chi Zhang, Hui Gao, Jiazheng Niu, Wensheng Ma, Zhangquan Peng, Yanwen Bai, Zhonghua Zhang
JOURNAL OF ENERGY CHEMISTRY
(2020)
Article
Nanoscience & Nanotechnology
Ying Wang, Lei Zhang, Kuibo Yin, Jie Zhang, Hui Gao, Na Liu, Zhangquan Peng, Zhonghua Zhang
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Chemistry, Physical
Yujun Shi, Meijia Song, Ying Zhang, Chi Zhang, Hui Gao, Jiazheng Niu, Wensheng Ma, Jingyu Qin, Zhonghua Zhang
JOURNAL OF POWER SOURCES
(2019)
Article
Chemistry, Physical
Congcong Wei, Fakui Luo, Chi Zhang, Hui Gao, Jiazheng Niu, Wensheng Ma, Yanwen Bai, Zhonghua Zhang
Article
Engineering, Environmental
Hui Gao, Xuejiao Yan, Jiazheng Niu, Ying Zhang, Meijia Song, Yujun Shi, Wensheng Ma, Jingyu Qin, Zhonghua Zhang
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Chemistry, Physical
Shengzhen Wang, Wensheng Ma, Wanfeng Yang, Qingguo Bai, Hui Gao, Zhangquan Peng, Zhonghua Zhang
Summary: Hierarchically nanoporous Ge (np-Ge) was fabricated as an anode material for lithium-ion batteries, showing excellent cycling stability and rate capability, providing a new solution to overcome the lifespan issue caused by volume variations.
JOURNAL OF CHEMICAL PHYSICS
(2021)
Article
Electrochemistry
Wenrun Cui, Meijia Song, Bin Yu, Fuquan Tan, Wanfeng Yang, Guanhua Cheng, Hui Gao, Zhonghua Zhang
Summary: A multiphase alloying strategy is proposed to improve the electrochemical performance of Sn-based anodes for magnesium ion batteries. The triphase Sn-Al-Bi alloys show significant performance improvement due to accelerated ion transport and structural damage alleviation.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Review
Biochemistry & Molecular Biology
Meijia Song, Hui Gao, Zhonghua Zhang
Summary: This article summarizes the advantages, challenges, and progress of Bi-based anodes in MIBs. Theoretical evaluations, battery configurations, electrode designs, electrochemical properties, and Mg storage mechanisms are discussed. Furthermore, key issues and views on the future development of Bi-based anodes in MIBs are provided.
Article
Chemistry, Multidisciplinary
Hui Gao, Jeongyeon Lee, Qixiao Lu, Yoonbin Kim, Kang Ho Shin, Ho Seok Park, Zhonghua Zhang, Lawrence Yoon Suk Lee
Summary: This study reports the use of N-doped carbon-wrapped antimony nanoparticles as anode materials for potassium- and sodium-ion batteries. The material exhibits superior rate capabilities and excellent cycle stabilities, demonstrating its potential for practical energy storage applications.
Article
Chemistry, Applied
Hui Gao, Yan Wang, Zhiyuan Guo, Bin Yu, Guanhua Cheng, Wanfeng Yang, Zhonghua Zhang
Summary: Nanoporous InSb with dual-scale phases was fabricated and investigated as an anode material for sodium/potassium ion batteries. The dealloying/alloying mechanisms and the formation of dual-scale microstructures/phases were well rationalized by operando XRD and ex-situ characterizations. The np-InSb electrode exhibited superior reversible capacities and lifespan compared with the monometallic porous In electrode, attributed to the dealloying-induced nanoporous architecture and alloying strategy.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Chemistry, Physical
Wensheng Ma, Bin Yu, Fuquan Tan, Hui Gao, Zhonghua Zhang
Summary: In this study, bimetallic Bi-Sb solid solutions in a porous carbon matrix were synthesized as anode material for sodium-ion batteries, effectively addressing the issue of performance degradation caused by volume expansion in alloy-type anodes during cycling.
Article
Multidisciplinary Sciences
Hui Gao, Kuibo Yin, Zhiyuan Guo, Ying Zhang, Wensheng Ma, Wanfeng Yang, Ke Sun, Zhangquan Peng, Zhonghua Zhang
Summary: A facile one-step dealloying protocol was utilized to prepare Bi-Sb alloys with an exotic nanoporous microstructure ideal for potassium ion batteries, exhibiting decent reversible capacities and superior lifespan. Operando XRD and DFT calculations further rationalized the robust two-step electrochemically-driven phase transformations of the (Bi,Sb) alloys, substantiating their outstanding reversibility in PIBs.
FUNDAMENTAL RESEARCH
(2021)
Article
Chemistry, Physical
Meijia Song, Jiazheng Niu, Hui Gao, Tianyi Kou, Zekun Wang, Zhonghua Zhang
JOURNAL OF MATERIALS CHEMISTRY A
(2020)
Article
Chemistry, Physical
Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu
Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen
Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu
Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing
Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen
Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang
Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo
Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu
Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas
Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov
Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei
Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur
Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea
Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang
Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu
Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.
JOURNAL OF POWER SOURCES
(2024)