Article
Energy & Fuels
He Liu, Bernard Wiafe Biney, Junlian Shi, Shiguang Fan, Aijun Guo, Feng Wang, Shouhui Jiao, Kun Chen
Summary: This study investigates the coking propensity and radical evolution of heavy residue and SARA fractions at different temperatures to understand the coke induction process. Results show that residue starts to form coke at higher temperatures while resins and asphaltenes produce coke at lower temperatures without an induction period. The solubility gap between reactant and coke influences the coke induction. The coking process can be described by different kinetics for residue and heavy fractions, while asphaltenes generate reactive radicals and contribute to the radical evolution. Maltene subfractions can inhibit the coking of asphaltenes by solvation and hydrogen donation behavior.
Article
Energy & Fuels
Yanhong Wang, Yongzhao Zhou, Shuanshi Fan, Xuemei Lang, Gang Li
Summary: The coking characteristics of heavy oil play a crucial role in the in situ combustion process. After low temperature oxidation, the pyrolysis coking characteristics of heavy oil change significantly, resulting in a higher coke yield but lower oxidation activity and heat value.
Article
Chemistry, Multidisciplinary
Azadeh Karevan, Mohsen Zirrahi, Hassan Hassanzadeh
Summary: A fully automated standardized SARA analysis for bitumen and heavy crudes has been developed, which is more efficient, cost-effective, and consistent compared to the conventional method.
Article
Energy & Fuels
Ya-fei Chen, Hong Yin, Dong-lin He, Hai-feng Gong, Zhe-zhi Liu, Yun-qi Liu, Xian-ming Zhang, Wan-fen Pu
Summary: This study investigates the evolution of low temperature oxidized coke generated from the pyrolysis of ultra-heavy oil during in-situ combustion. The results show that low temperature oxidation leads to the formation of oxidation groups and promotes the evolution of aromatic structures and functional groups. Additionally, low temperature oxidation reactions have a significant impact on the morphology, oxidizability, and exothermicity of the coke.
Article
Spectroscopy
Fatemeh Ahmadinouri, Parviz Parvin, Ahmad Reza Rabbani
Summary: In this paper, a modified Beer-Lambert method of laser-induced fluorescence spectroscopy is proposed for rapid identification and differentiation of crude oil fractions, which is of great significance in marine pollution research.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Energy & Fuels
Qing-An Xiong, Yu-Ming Zhang, Pei Qiao, Guo-Tong Li, Jia-Zhou Li, Wei Zhang
Summary: The pyrolysis behaviors and kinetics of Qingdao vacuum residue and its SARA fractions were evaluated. The results showed that the pyrolysis behavior was influenced by temperature range and interaction between fractions, and exhibited certain regularities.
Article
Energy & Fuels
Liqun Ma, Syed Shatir A. Syed-Hassan, Zhe Xiong, Yuanjing Chen, Jun Xu, Long Jiang, Sheng Su, Song Hu, Yi Wang, Jun Xiang
Summary: Stable free radicals generated during bio-oil pyrolysis are related to bio-oil polymerization and coke structure change. These free radicals have different activation energies, mainly generated from the polymerization of bio-oil.
Article
Energy & Fuels
Yunyun Li, Guangzhi Liao, Zhengmao Wang, Rigu Su, Shuai Ma, Hui Zhang, Liangang Wang, Xusheng Wang, Jingjun Pan, Quan Shi
Summary: This study investigated the molecular changes associated with coke formation during in-situ combustion (ISC) by conducting a thermal oxidation experiment on heavy crude oil. The results showed that oxidation and thermal cracking are both important reactions in the simulated ISC process, and the molecular composition provides valuable insights into the behavior of coke formation from crude oil.
Article
Chemistry, Multidisciplinary
Jun Woo Park, Min Yong Kim, Soo Ik Im, Kang Seok Go, Nam Sun Nho, Ki Bong Lee
Summary: This study conducted a quantitative analysis to predict the yields of deasphalted oil (DAO) in the solvent deasphalting (SDA) process. The effects of temperature and solvent-to-oil ratio (SOR) on the DAO yield were explained using simple and accurate correlations. The results showed that temperature and SOR have a significant impact on the DAO yield.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2022)
Article
Energy & Fuels
Guillermo Felix, Alexis Tirado, Alexander Quitian, Vicente Samano, Mikhail A. Varfolomeev, Chengdong Yuan, Jorge Ancheyta
Summary: The characterization of SARA fractions of heavy crude oils during hydrocracking reactions is usually focused on asphaltenes, with limited studies on the structural differences of all SARA fractions. In this study, a heavy crude oil was upgraded by non-catalytic and catalytic hydrocracking, and it was found that the hydrogenation capacity of each catalyst affects the average molecular weight of all SARA fractions, with Fe2O3 (analytical grade) having the most significant impact. The hydrocracking reactions also resulted in a reduction in the number of aliphatic carbons in aromatics, resins, and asphaltenes fractions, increasing their aromaticity.
Article
Energy & Fuels
Aliyu Adebayo Sulaimon, Habineswaran A. L. Rajan, Ali Qasim, Nwankwo Princess Christiana, Pearl Isabellah Murungi
Summary: This study developed new correlations to estimate the stability of asphaltenes in crude oil and proposed new asphaltene stability plots based on oil density. The results showed that the density-based correlations were relatively more accurate than the viscosity-based correlations. The newly developed correlations can be used to predict the stability of asphaltenes based on the physical properties of crude oil.
GEOENERGY SCIENCE AND ENGINEERING
(2023)
Article
Energy & Fuels
Paolo Guida, Eleonora Colombo, Elia Colleoni, Saumitra Saxena, Alessio Frassoldati, William L. Roberts, Tiziano Faravelli
Summary: This study introduces a predictive and generally applicative method for asphaltene pyrolysis modeling, showing good agreement with recent experimental data and providing a foundation for a more comprehensive project in the future.
Article
Energy & Fuels
Liang-Liang Wang, Teng-Fei Wang, Yang Yang, Xiao-Qiang Peng, Jie-Xiang Wang, Wan-Fen Pu
Summary: The study found that aromatics can reduce heat enthalpy and change activation energy in multivariate mixtures of SARA fractions, playing an important role in oxidation reactivity.
PETROLEUM SCIENCE AND TECHNOLOGY
(2022)
Article
Energy & Fuels
Zarrin Nasri
Summary: This study investigated the effects of operational conditions on SARA fractions during the upgrading of vacuum residue using microwave irradiation. The results showed that under the optimal conditions, the chemical composition of the feedstock was substantially improved.
PETROLEUM SCIENCE AND TECHNOLOGY
(2021)
Article
Thermodynamics
Junyu Yang, Qianghui Xu, Hang Jiang, Lin Shi
Summary: This study investigated the reaction kinetics of China Xinjiang crude oil through Ramped Temperature Oxidation experiments and numerical simulations, and proposed a simplified reaction model to simulate the behaviors. Acceptable consistency was achieved between the experiments and simulations, demonstrating the predictive capability of the proposed model.