4.5 Article

Improved magnetic properties of Co0.5LaxFe2.5-xO4/FeCo composite powders by magnetic exchange-coupling effect

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DOI: 10.1016/j.jmmm.2019.165596

关键词

Ferrite; Hard/soft magnetic composites; Magnetic properties; Exchange-coupling

资金

  1. Open Foundation of Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, Guangxi University [2019GXYSOF05]
  2. Innovation Project of Guangxi Graduate Education of China [YCSW2019030]

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Hard/soft Co0.5LaxFe2.5-xO4/CoFe composites have been synthesized by reduction process at 550 degrees C in 5% H-2-Ar atmosphere. As the precursor, Co0.5LaxFe2.5-xO4 is prepared by the ball-milling-assisted ceramic process. High-crystallized spinel Co(0.5)La(x)Fe(2.5-x)O(4 )ferrites are formed after calcined at 900 degrees C in air for 2 h. The Co0.5Fe2.5O4 shows the highest specific saturation magnetization (78.48 emu/g), remanence (30.82 emu/g), and effective anisotropy constant (62323.48 erg/g) compared with La3+ -doped Co0.5LaxFe2.5-xO4. By contrast, the specific saturation magnetization for Co0.5LaxFe2.5-xO4/CoFe composite, reduced at 550 degrees C for 20 min, exhibits an enhanced specific saturation magnetization (81.00 emu/g). The hysteresis loop for Co0.5LaxFe2.5-xO4/CoFe composites exhibits a good single-phase magnetic behavior. The improvement in magnetic properties for Co0.5LaxFe2.5-xO4/CoFe composites is attributed to the exchange-coupling interaction between the hard and soft phases.

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