期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 384, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2019.121288
关键词
Simultaneous removal; Heavy metal ions; Magnetic mesoprous nanomaterials; Multiple adsorption sites; Competitive adsorption
资金
- Tianjin Science and Technology Plan Project [16PTGCCX00070]
- Science and Technology Plans of Tianjin [18PTSYJC00180]
In order to achieve the purpose of simultaneous removal of coexisting heavy metal ions, in this work, functionalized magnetic mesoprous nanomaterials (Fe3O4 -HBPA-ASA) with high density and multiple adsorption sites were designed and prepared. The obtained Fe3O4-HBPA-ASA was characterized by SEM, FTIR, VSM, TGA and zeta potential. Cu(II), Pb(II) and Cd(II) were chosen as the model heavy metal ions, the adsorption experiments showed that Fe3O4-HBPA-ASA showed hightheoretical adsorption capacitiesin individual system, and the maximum adsorption capacity was 136.66 mg/g, 88.36 mg/g and 165.46 mg/g, respectively. In the binary and ternary systems, the competitive adsorption leads to a decrease in the adsorption capacity of Cu(II), Pb(II) and Cd(II). However, in the ternary system with a concentration lower than 15 mg/L, the simultaneous removal rate was still higher than 90%. The adsorption isotherms and kineticswere well fitted by Langmuir and pseudosecond-order models, respectively. The XPS and density functional theory (DFT) analysis have confirmed that the adsorption of metal ions was related to various types of functional groups on the surface of Fe3O4-HBPA-ASA, while the adsorption mechanisms of Cu(II), Cd(II) and Pb(II) were different.
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