期刊
JOURNAL OF CONTAMINANT HYDROLOGY
卷 229, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jconhyd.2019.103583
关键词
Biological soil crusts; Nanoparticles; Heavy metals; Irrigation water; Zeta potential
资金
- National Key Research and Development Program of China [SQ2017YFNC060064]
- National Natural Science Foundation of China [41401260]
- Natural Science Foundation of Hunan Province [2017JJ2112]
- Changsha plan project of science and technology [kq1801025]
- 1515 Talent Fund of Hunan Agricultural University
Biological soil crusts (BSCs), which are ubiquitous in paddy fields, are known to remove pollutants from paddy fields systems. The Nano-TiO2 enhanced the removal of Cd(II) by BSC under acidic irrigation water was found, and its mechanism was investigated. After the addition of nano-TiO2, the Cd(II) removal efficiency of BSCs increased by 26.70% than that of pure BSCs, and the Nano-TiO2 induced faster removal velocity as well. Zeta potential and potentiometric titration results revealed that BSCs generated more negative charges and sites concentration after addition of Nano-TiO2 at acidic environment. The carboxyl and amino/hydroxyl groups were the main functional groups on BSC and the BSC + TiO2. The higher concentration of amino/hydroxyl groups in BSC + TiO2 (0.33 +/- 0.08 mmol/g) was present than that of pristine BSCs (0.62 +/- 0.02 mmol/g), and they were with similar concentration of phosphate groups and carboxyl groups. This result was attributed to the Nano-TiO2 stimulated the BSCs to produce more extracellular polysaccharides and proteins. Our findings would provide novel strategy for the removal of cadmium from acidic irrigation water.
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