期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 816, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.152556
关键词
Morphology control; Coating; Polymerized complex method; Mg battery; Positive electrode
资金
- Advanced Low-Carbon Technology Specially Promoted Research for Innovative Next-Generation Batteries Program(ALCA-SPRING) of the Japan Science and Technology Agency
A structured spinel oxide as a positive-electrode active material for magnesium rechargeable batteries was produced using a propylene-oxide-driven sol-gel method and subsequent vanadium oxide coating. Porous frameworks consisting of MgMn2O4 nanoparticles having diameters of similar to 10 nm exhibited a large specific surface area of similar to 150 m(2) g(-1) and interconnected bimodal pores distributed in the micrometer (1-10 mu m) and nanometer (10-100 nm) regions. Hierarchical conduction paths constructed by mixing the porous frameworks with carbon nanoparticles reduced the overpotential for the insertion and extraction of magnesium ions and increased the redox capacity in an ionic-liquid electrolyte system. Moreover, the surface coating of vanadium oxide on the spinel oxide nanoparticles enhanced the extraction of magnesium ions and suppressed the decomposition of the electrolyte. The electrochemical properties, such as the capacities, rate capabilities, and cyclabilities, of the positive electrodes were largely improved by the structured spinel oxide frameworks. (C) 2019 Elsevier B.V. All rights reserved.
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