期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2020, 期 8, 页码 1046-1049出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202000049
关键词
Rhodium; Transfer hydrogenation; Diboron; Alkenes; Carbonyls
资金
- Double First-Class University project of China Pharmaceutical University [CPU2018GY35]
- Six Talent Peaks Plan of Jiangsu Province
A diboron-mediated rhodium-catalysed transfer hydrogenation system using water as the hydrogen donor is developed. In addition to a series of alkenes with good functional group tolerance, this rhodium-based catalytic system also effectively reduces aldehydes and ketones. A plausible mechanism involving the Rh-I-catalysed hydrogen generation and Rh-0-catalysed hydrogenation is proposed for the reaction.
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