期刊
CHEMICAL ENGINEERING JOURNAL
卷 380, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.122491
关键词
Multi-color emission; Double perovskite; Pr3+; Fluorescence intensity ratio; Self-calibrated; Optical temperature sensors
资金
- National Natural Science Foundation of China [21571162, 51672259]
Currently, non-contact fluorescence intensity ratio (FIR)-based luminescent thermometry has been extensively attracted great attention for its promising applications in electromagnetic field, micro-temperature field and thermally harsh environments. In this work, the double-perovskite LaMg0.402Nb0.598O3: Pr3+ (LMNO: Pr3+) thermometric phosphor is firstly designed and successfully synthesized via a high-temperature solid-state method. Under 450 nm excitation, the as-prepared samples simultaneously exhibit blue emission (P-3(0) -> H-3(4)), green emission (P-3(1 )-> H-3(4)) and red emission (D-1(2) -> H-3(4), P-3(0) -> F- 3(2)) of Pr3+. They present different dependence on the temperature due to the intervalence charge transfer state (IVCT). Accordingly, the four FIR models between P-3(1 )-> H-3(4) and P-3(0 )-> H-3(4) (G/B), P-3(1 )-> H-3(4) and P-3(0) -> F-3(2) (G/R2), D-1(2) -> H-3(4) and P-3(0) -> H-3(4) (R1/B) and D-1(2) -> H-3(4) and P-3(0) -> F- 3(2) (R1/R2) are used as temperature detecting signal in the range of 298-523 K, and the maximum absolute and relative sensitivity of LaMg0.402Nb0.598O3: 1.2% Pr3+ sample reached 0.0597K(-1) at 523 K and 0.7250% K-1 at 473 K, respectively. Excellent temperature sensing features are also demonstrated in the LaMg0.402Nb0.598O3: 0.3% Pr3+ and LaMg0.402Nb0.598O3: 2.0% Pr3+ samples. Except for high sensitivity for temperature sensing, the designed Pr3+-doped double-perovskite materials also realize the self-calibration by simultaneous monitoring of four models of FIR. Moreover, after five cycles, the relative luminescence intensity of LaMg0.402Nb0.598O3: 1.2% Pr3+ sample remains stable. These results indicate that LaMg0.402Nb0.598O3: Pr3+ phosphors have great promising application as self-calibrated optical temperature sensors.
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