期刊
CHEMCATCHEM
卷 12, 期 7, 页码 1948-1952出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201902302
关键词
catalytic selectivity; hydrogenation; adsorption conformation; Pt nanoparticle; zeolite encapsulation
资金
- National Natural Science Foundation of China [21706204]
- China Petroleum & Chemical Corporation
- CAS Pioneer Hundred Talents Program
With thermodynamically favorable prevailing flat-lying adsorption of aromatic ketone molecules on Pt/Y catalyst via pi-electron interaction, the 100 % selective hydrogenation toward aromatic alcohols is hardly achieved because of competitive hydrogenation on benzene rings. Here we developed a general method to prepare encapsulated Pt nanoparticles into Y Zeolite (Pt@Y), which provided a novel method to retard hydrogenation of benzene rings via thermodynamically unfavorable end-on adsorption conformation for almost 100 % selectivity from aromatic ketones to aromatic alcohols even at conversion close to 100 %.
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