Article
Materials Science, Ceramics
Ali Talimian, H. F. El-Maghraby, Monika Michalkova, Dusan Galusek
Summary: Adding 0.3 wt% lithium hydroxide can promote densification and limit grain growth of MgAl2O4, while also affecting the activation energy of sintering. The formation and disappearance of secondary phases were observed, with magnesium oxide and lithium aluminum oxide produced at certain temperatures.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Ceramics
Somnath Sinhamahapatra, Chandrima Ghosh, Himansu Sekhar Tripathi, Sunanda Mukhopadhyay
Summary: The magnesium aluminate spinel was prepared from constituent oxides through a solid-state sintering process at temperatures ranging from 1550 to 1700 degrees C in a normal air atmosphere. The addition of TiO2 and Yb2O3 improved the densification and mechanical properties of the magnesia-rich spinel, with Yb2O3 showing better performance in room temperature flexural strength.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
L. Zarazua-Villalobos, G. Fantozzi, G. Bonnefont, L. Tellez-Jurado, H. Balmori-Ramirez
Summary: Transparent magnesium aluminate spinel was obtained through one-step spark plasma reaction-sintering (SPRS) using different precursor powders. The HT450 and HT850 powders showed better sinterability and transparency, likely due to the higher reactivity of their precursor particles.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Aref Basiri, Amir Hossein Nassajpour-Esfahani, Mohammad Reza Haftbaradaran-Esfahani, Amir Alhaji, Ali Shafyei
Summary: This study investigated the granulation process of magnesium aluminate spinel powders using spray freeze drying method. The optimal amount of binder was found to be 3%, and the ideal solid load was determined to be 35 wt%, resulting in granules of 10-50 μm in size. Powder granulation increased density by approximately 20% and improved the in-line transmission for the IR range by over 15%.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Wenyu Zan, Beiyue Ma, Yutong Cao, Jialong Tian, Zhangyan Zhou, Lulu Wang, Zhouhua Jiang
Summary: In this study, MgAl2O4 spinel materials were synthesized using a single-step reaction sintering method. The effects of (MgO + Al2O3) content, molding pressure, and YSZ additive on the properties of the material were investigated. The results showed that increasing (MgO + Al2O3) content and molding pressure favored the formation of the second MgAl2O4 spinel but also increased the apparent porosity. YSZ addition induced defects and improved the sintering and mechanical properties. The optimal material was obtained with the addition of 1 wt% YSZ, 80 wt% of (MgO + Al2O3), and molding at 200 MPa, followed by sintering at 1600 degrees C for 2 h. The material exhibited high strength retention and comprehensive performance after thermal shock.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Man Zhang, Jianhua Liu, Junwen Zhou
Summary: The effect of Eu2O3 doping amount on the densification behavior of MgAl2O4 and its corrosion resistance to aluminum electrolyte was studied. The results showed that Eu2O3 doping contributed to the densification of MgAl2O4, and the sample with 3 wt.% Eu2O3 had the highest relative density and hardness. Additionally, this sample exhibited the best corrosion resistance to aluminum electrolyte.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Biswajit Baruah, Ritwik Sarkar
Summary: This study investigated the effect of samarium oxide (Sm2O3) as an additive on the properties of stoichiometric magnesium aluminate spinel using different raw material sources. Six spinel batches were prepared with commercially available alumina and magnesia, and the effect of Sm2O3 addition on the properties of the spinel compositions was studied. The results showed that 1% of Sm2O3 addition led to improved densification and strength of the spinel compositions.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2023)
Article
Materials Science, Ceramics
Brian M. Rogers, Isabella L. M. Costa, Weidi Zhu, Sabyasachi Sen, Ricardo H. R. Castro
Summary: Beryllium-magnesium aluminate (Be0.1Mg0.9Al2O4 and Be0.2Mg0.8Al2O4) nanoparticles were synthesized and sintered to achieve near full density ceramics at the nanoscale. The sintered nanoceramics showed reduced optical transmission in the infrared range compared to beryllium-free MgAl2O4 nanoceramics. The Vickers hardness of the samples remained constant regardless of grain size. Beryllium ions formed solid solutions with the MgAl2O4 spinel structure and did not significantly affect grain boundaries or mechanical properties.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Wenyu Zan, Beiyue Ma, Jianhuai Tang, Kun Liu, Yutong Cao, Jialong Tian, Zhouhua Jiang
Summary: Co-doping of CeO2 and La2O3 can improve the densification and mechanical properties of MgAl2O4 spinel ceramics.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Ahmed A. M. El-Amir, Shufeng Li, Mahmoud Abdelgawad, Emad M. M. Ewais
Summary: c-zirconia ceramic composites were successfully synthesized by SPS technique with MA addition, resulting in improved stability and strength. The SPS sintering process led to dense compacts with refined microstructure and superior compaction resistance, showing great potential for high-tech engineering applications.
JOURNAL OF THE KOREAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Multidisciplinary
Isabella L. M. Costa, Joice Miagava, Ricardo H. R. Castro
Summary: This study proposes that sodium can be used as a dopant to effectively reduce the processing requirements for manufacturing nanoceramics, and successfully produces fully dense transparent sodium-doped magnesium aluminate with grain sizes below 15 nm. The sodium-doped samples exhibit higher indentation fracture toughness compared to undoped samples with similar grain sizes.
Article
Engineering, Biomedical
Mehran Ghodrati, Seyed Mahdi Rafiaei, Lobat Tayebi
Summary: In this study, magnesium aluminate spinel (MgAl2O4) nanoparticles were synthesized using a combustion approach and then incorporated into PLA to prepare scaffolds. The crystal structure, microstructure, biodegradability, and thermal characteristics of the materials were investigated using XRD, FESEM, ICP, STA, and compressive strength analyses. The results showed that PLA/6 wt% MgAl2O4 scaffolds exhibited the highest compressive strength. Immersion of the scaffolds in SBF revealed improved biodegradability, while improper particle dispersion occurred at higher MgAl2O4 loadings.
JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Markus Mader, Richard Prediger, Karl G. Schell, Gabriela Schmidt, Alex Dorn, Sophie Jenne, Sebastian Kluck, Leonhard Hambitzer, Manuel Luitz, Claudia Schwarz, Marcel Milich, Christian Greiner, Bastian E. Rapp, Frederik Kotz-Helmer
Summary: This study develops a thermoplastic nanocomposite that can be shaped into transparent ceramics using polymer injection molding. The process involves several steps to achieve high density, high optical transmission, and high mechanical strength in the transparent ceramics. By making transparent ceramics accessible to high-throughput polymer processing techniques, this research enables fast and cost-efficient manufacturing of macroscopic and microstructured components, opening up a wide range of potential applications.
Article
Materials Science, Ceramics
Ming Shi, Ying Li, Junjie Shi
Summary: A novel method for fabricating periclase and magnesium aluminate spinel refractory from secondary aluminum dross was proposed. The study analyzed the fabrication mechanism and studied the effects of MgO addition and sintering temperature on the properties of refractories. The results showed significant improvement in purity, crystallinity, densification, flexural strength, and impact toughness with increasing sintering temperature and MgO addition.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Iqra Nazir, Farhan Javaid, Mutawara Mahmood Baig, Muhammad Shoaib Butt, Iftikhar Hussain Gul
Summary: In this study, Mg1-xZnxFe2O4 (MZFO) nanoparticles with varying Zn substitution were synthesized and their structural, dielectric, and gas-sensing properties were investigated. The results showed that Zn substitution decreased the dielectric constant and loss of MZFO with increasing frequencies, reaching a saturation value at higher frequencies. Additionally, MZFO exhibited high sensitivity and a good response time for CO2.
Article
Materials Science, Ceramics
Nasima Afsharimani, Ali Talimian, Emilia Merino, Alicia Duran, Yolanda Castro, Dusan Galusek
Summary: A study compared the morphology and electrochemical properties of pure and graphene-modified hybrid silica sol-gel coatings on anodized magnesium alloys. The presence of graphene in the coatings improved the corrosion resistance of the alloys significantly, with a significant passive region observed in the graphene-containing coatings.
INTERNATIONAL JOURNAL OF APPLIED GLASS SCIENCE
(2022)
Article
Materials Science, Ceramics
Tomas Spusta, Vladimir Prajzler, Karel Maca
Summary: This paper investigates the capsule free hot isostatic pressing (HIP) process of alumina and yttria-stabilized zirconia ceramics and provides important insights. It is found that rapid heating does not affect pore closure behavior or restrict grain growth compared to conventional heating. The study also reveals the optimal HIP conditions for producing nearly fully dense compacts with minimal grain growth. Additionally, applied pressure does not enhance grain boundary mobility during the HIP process.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Daniel Drdlik, Vojtech Marak, Karel Maca, Katarina Drdlikova
Summary: This study investigated the effect of rare-earth dopants on the shaping, sintering, and microstructure of barium titanate. The results showed that the addition of dopants reduced the deposition kinetics and green body density of barium titanate. However, small amounts of Tb and Er dopants increased the onset temperature of sintering, indicating their potential application in layered ceramic harvesters. Furthermore, doping had a positive impact on the microstructure, leading to higher sintered densities and smaller grain sizes compared to pure barium titanate.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Rahaf M. Ahmad, Yaser E. Greish, Hesham F. El-Maghraby, Loay Lubbad, Yahia Makableh, Fayez T. Hammad
Summary: Chitosan-alginate nanoparticles loaded with Nerolidol were successfully fabricated and characterized, showing potential encapsulation and delivery using an in vitro model. Various techniques including Fourier transform infrared spectroscopy, scanning and transmission electron microscopy were used for nanoparticle characterization.
Article
Materials Science, Ceramics
Robert Klement, Katarina Drdlikova, Daniel Drdlik, Karel Maca
Summary: Transparent alumina doped with rare-earth or transition metal oxides is a group of materials suitable for optical applications. The preparation process requires high-quality starting materials, advanced shaping techniques, and pressure-assisted sintering. Spark plasma sintering and hot isostatic pressing have been proven effective in producing pore-free fine microstructures with high in-line transmission and sufficient intensity of light emission. This review aims to summarize and compare published results on this topic, as well as propose other possible and appropriate approaches for future research.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
Vijay Bijalwan, Jaroslav Kastyl, Vladimfr Prajzler, Jirf Erhart, Vaclav Pouchly, Karel Maca
Summary: This work presents a promising approach to synthesize multifunctional-translucent BCZT-CeO2 ceramic for electro-mechanical/optical conversion. The ceramics achieved high dielectric permittivity, low dielectric loss, and extraordinary optical transmittance. Post-processing method further improved the piezoelectric properties of the ceramics.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
A. Najafzadehkhoee, A. Talimian, J. Sedl, M. Lisnichuk, P. Hvizdos, D. Galusek
Summary: This study successfully fabricated highly dense translucent Y2O3 by utilizing the high sinterability of nano Y2O3 powder, achieving high-density sintering and eliminating pores through improved particle rearrangement from low-density green bodies.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2022)
Article
Materials Science, Ceramics
Vaclav Pouchly, Ali Talimian, Jaroslav Kastyl, Martin Chvila, Erik Scasnovic, Ana M. Betlran, Juan G. Lozano, Dusan Galusek
Summary: The effects of LiOH doping and different SPS schedules on densification behavior and final transparency of polycrystalline magnesium aluminate spinel were investigated. Slow heating rate was optimal for undoped spinel with the highest transmittance, while fast heating rate was beneficial for LiOH-doped spinel with reduced carbon contamination.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
Zdenek Chlup, Daniel Drdlik, Hynek Hadraba, Oldrich Sevecek, Filip Siska, Jiri Erhart, Karel Maca
Summary: The purpose of this article is to clarify the fundamental processes that occur near the Curie temperature, with a focus on the fracture behavior of pure polycrystalline barium titanate. The study combines experimental methods with numerical simulations to investigate the effects of grain size on the material's temperature, lattice transformation, and mechanical properties. Understanding this behavior is essential for the processing and correct application of lead-free barium titanate materials.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Biochemistry & Molecular Biology
Sulafa Ibrahim, Badriya Baig, Soleiman Hisaindee, Hussein Darwish, Ashraf Abdel-Ghany, Hesham El-Maghraby, Amr Amin, Yaser Greish
Summary: Liver cancer remains a major cause of cancer-related deaths, partly due to limitations of available drugs and late diagnosis. Targeted drug delivery systems using nanoparticles, especially magnetic nanoparticles (MNPs), show promise in improving therapeutic value by reducing drug resistance. In this study, PEG-coated MNPs were successfully synthesized and coated with crocetin at different concentrations. The crocetin-coated pegylated MNPs demonstrated good release kinetics under acidic and neutral conditions and showed potential in reducing the proliferation of HepG2 cells in vitro.
Article
Biochemistry & Molecular Biology
Ashraf Ali, Ahmed Alzamly, Yaser E. Greish, Reem H. Alzard, Hesham F. El-Maghraby, Naser Qamhieh, Saleh T. Mahmoud
Summary: Developing new materials for energy and environment-related applications is highly important. Organic and metal-organic framework (MOF) materials, such as the zeolitic imidazole framework (ZIF-67) mixed with a conductivity-controlled chitosan polymer, have shown great potential for sensing hazardous gases and saving energy. The developed gas sensor, which operates at room temperature, has a fast response time, eliminates the need for an additional heating element, and minimizes external energy requirements, making it suitable for real-time detection of harmful gases for a healthy and clean environment.
Article
Materials Science, Ceramics
Nibu Putenpurayil Govindan, Aliasghar Najafzadehkhoee, Ali Talimian, Vaclav Pouchly, Monika Michalkova, Peter Svancarek, Robert Klement, Dusan Galusek
Summary: Ce3+ doped yttrium oxide nanoparticles were synthesized using precipitation method, with different Ce3+ concentrations. The sintered yttrium oxide samples showed high relative density, and the increase in cerium concentration resulted in higher sintering activation energy.
Article
Materials Science, Ceramics
A. Najafzadehkhoee, A. Talimian, V. Girman, R. Sedlak, P. Hvizdos, K. Maca, D. Galusek
Summary: In this study, liquid-phase sintering was used to produce dense Y2O3 bodies with fine-grained microstructure. The addition of sintering aids increased the relative density and suppressed grain growth. The dissolution of Y2O3 into the liquid phase resulted in the formation of isolated grains, leading to the suppression of yttria grain growth.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)