期刊
CERAMICS INTERNATIONAL
卷 46, 期 10, 页码 14488-14495出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.02.247
关键词
Ni0.85CO2.15V2O8; Porous-nanosheet; Bubble-sheet-like; High-rate; Lithium-ion batteries
资金
- National Natural Science Foundation of China [51772331]
- National Key Technologies RD Program [2018YFB1106000]
Transition-metal vanadates (TMVs) are widely acknowledged as promising anode candidates for lithium-ion batteries (LIBs). Nevertheless, it is a great challenge to synthesize TMVs with complex nanostructures and multinary compositions. In this work, quaternary Ni0.85CO2.15V2O8 with a bubble-sheet-like morphology is facilely synthesized by a self-template method. Moreover, the novel synthesis strategy for Ni0.85CO2.15V2O8 only involves an anion-exchange reaction and a subsequent topotactic conversion. Owing to the porous nano-architecture and the synergistic effect of multinary compositions, the as-prepared Ni0.85CO2.15V2O8 porous nanosheet (PNS) anode exhibits remarkable electrochemical properties with a high specific capacity up to 1633 mA h g(-1) at 0.2 A g(-1), superior rate capability (583 mA h g(-1) at 10 A g(-1)) and excellent cyclic stability (627 mA h g(-1) after 2000 cycles at 5 A g(-1)). Such outstanding electrochemical properties make Ni0.85CO2.15V2O8 PNS a promising high-rate anode for LIBs. This strategy of designing bubble-sheet-like architecture can also be applied to other multinary TMVs.
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