Article
Chemistry, Physical
Lina Yan, Xing Cheng, Yueshuai Wang, Zhaozhao Wang, Lirong Zheng, Yong Yan, Yue Lu, Shaorui Sun, Wenge Qiu, Ge Chen
Summary: The electrochemical production of hydrogen peroxide through the two-electron oxygen reduction reaction offers an environmentally friendly alternative to the industrial anthraquinone process. Developing catalysts with high activity and selectivity for H2O2 production is essential for efficient and sustainable synthesis.
MATERIALS TODAY ENERGY
(2022)
Article
Biochemistry & Molecular Biology
Xuan Wang, Wei Liang, Changqing Lin, Tie Zhang, Jing Zhang, Nan Sheng, Zhaoning Song, Jie Jiang, Bing Sun, Wei Xu
Summary: In this study, a catalyst Co3O4@CeO2-IE was synthesized through inverse loading, and a strategy of oxygen vacancy was proposed for its high catalytic oxidation activity. It showed better performance than the traditional supported catalyst Co3O4/CeO2-IM. This work provides a doping strategy to effectively boost the propane catalytic oxidation performance and presents a bright outlook for efficient environmental catalysts.
Article
Engineering, Environmental
Huayu Gu, Jintong Lan, Haolu Hu, Falong Jia, Zhihui Ai, Lizhi Zhang, Xiao Liu
Summary: This study investigates the influence of oxygen vacancy concentration on the molecular oxygen activation behavior of a-MnO2 catalysts. It is found that increasing the concentration of oxygen vacancies can lead to a reconfiguration of the oxygen activation configuration, making oxygen molecules more suitable for adsorbing organic compounds and activating bonds. These findings are important for the development of efficient catalysts.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Engineering, Chemical
Wei Liu, Wenjie Xiang, Nana Guan, Ruoyang Cui, Hao Cheng, Xi Chen, Zhongxian Song, Xuejun Zhang, Yinmin Zhang
Summary: The study found that constructing Co3O4-MnO2 interfaces significantly enhanced the catalytic activity of Co3O4/MnO2 catalysts, especially for Co3O4/α-MnO2 and Co3O4/γ-MnO2. The best catalyst Co3O4/α-MnO2 achieved a toluene conversion rate of 90% at 248 degrees Celsius and complete oxidation of toluene at 260 degrees Celsius, demonstrating great potential for practical applications.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Physical
Weilu Wang, Xudong Gong, Fang Wang, Xinyi Wei, Yanliu Dang, Yun Wu, Xianming Zhang
Summary: Ce-doped LaBO3 and its incorporation with 3d transition metals have shown great potential in eliminating propane. The addition of transition metals promotes the density of oxygen vacancies, enhancing the reduction and acidity of the material. This leads to a high conversion rate of propane.
Article
Chemistry, Physical
Ganggang Li, Ziyi Shui, Xiaoxiao Duan, Hongling Yang, Zeyu Zhao, Ting Zhao, Zhongshen Zhang, Guoxia Jiang, Hongna Ren, Jie Cheng, Zhengping Hao
Summary: In this study, Co3O4 materials with different morphologies were fabricated and the effect of water on their catalytic activity was investigated. The results showed that spherical Co3O4 displayed the best catalytic activity under dry conditions, while rod-like Co3O4 exhibited the best water resistance under humid conditions. Correlative characterizations and DFT calculations were used to reveal the mechanism behind water's effect.
Article
Chemistry, Physical
Yahan Wang, Saifei Wang, Jingyu Bai, Long Zhang, Shiguang Zhao, Jiguang Deng, Xiaolong Tang, Erhong Duan
Summary: A Co3O4/La2O2CO3/ LaCoO3 heterostructure catalyst with excellent catalytic performance, resistance to water, and resistance to poisoning was prepared using a simple solvent-thermal method. Experimental characterization and DFT calculations showed that La2O2CO3 provides more reactive oxygen species to enhance the oxidation of methane, while also protecting the active site of Co3O4 from water and SO2 adsorption. The structure of the catalyst promotes electron transfer, enhancing the adsorption and dissociation of oxygen and methane.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Physical
Mingchao Zhang, Xin Sui, Xin Zhang, Mang Niu, Cuiqing Li, Haiqin Wan, Zhen-An Qiao, Haijiao Xie, Xingyun Li
Summary: By using a mechano-chemical strategy with Na assisted milling, a multi-defective spinel catalyst D-NiCo2O4 was developed, which exhibited significantly elevated oxygen vacancies, raised active oxygen species, enhanced oxygen mobility, and increased specific surface area. This catalyst showed superb activity for propane catalytic oxidation, outperforming pristine NiCo2O4 and Co3O4 catalyst, making it one of the most outstanding non-noble metal catalysts for propane oxidation. This work set a paradigm for enhancing the VOCs oxidation performance of metal oxide catalyst by multi-defects engineering.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Qi Zhang, Pengju Yang, Hongxia Zhang, Jianghong Zhao, Hu Shi, Yamin Huang, Hengquan Yang
Summary: A novel non-equilibrium photochemical strategy was developed for preparing OV-rich Co3O4, promoting CO2 activation, and a series of defect-rich metal oxides and metal sulfides were successfully synthesized using this method, suggesting its universality. The concentration of OVs in Co3O4 can be tuned by controlling the light-irradiation time.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Engineering, Environmental
Xixi Chen, Wanyi Fu, Zhichao Yang, Yulong Yang, Yanjun Li, Hui Huang, Xihui Zhang, Bingcai Pan
Summary: This study demonstrates the preparation of a Ti-doped Mn3O4/Fe3O4 ternary catalyst, which creates abundant oxygen vacancies, enhances electrical conductivity, and accelerates the activation of O2 to produce H2O2. The catalyst achieved a 100% removal of tiamulin with a high H2O2 utilization efficiency, and demonstrated excellent stability and resistance to leaching.
Article
Engineering, Electrical & Electronic
Hsing- Hsiang, Chih-Cheng Chen, Chia-Chin Kao
Summary: This study investigated the effects of additives and cooling rate on the densification, microstructure, and varistor performance of ZnO-Co3O4-Mn3O4 varistors. Adding ZnBi2O4 promoted densification and lowered the sintering temperature. Slow cooling rate improved the alpha value. Adding ZnBi2O4 facilitated electron transfer and oxygen reaction, resulting in a higher Schottky barrier and alpha value.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Green & Sustainable Science & Technology
R. Zeng, G. Jin, D. He, L. Zhang, D. Chen, Y. Zhang, L. Zhu, Y. Mei, W. Wu, Y. Luo
Summary: Utilizing propane and CO2 for syngas production via dry reforming offers advantages, and creating efficient catalytic systems is crucial. Acidic H2O2 treatment of LaCoO3 catalyst yields highly dispersed Co3O4, enhancing catalytic activity for propane and CO2 conversion.
MATERIALS TODAY SUSTAINABILITY
(2022)
Article
Nanoscience & Nanotechnology
Yuxin Shi, Sirui Liu, Chen Ouyang, Zhikun Xu, Hongxu Su, Jing Yao, Mingyi Zhang, Xinzhi Ma
Summary: The study successfully enhanced the performance of one-dimensional nanowires in oxygen evolution reaction by introducing oxygen vacancies and boron elements. The Co3O4/BOx nanowire array electrode showed higher current density and lower overpotential compared to spinel Co3O4.
ACS APPLIED NANO MATERIALS
(2022)
Article
Engineering, Environmental
Junli Liu, Kaitao Zhang, Rongrong Shang, Hua Zhang, Jiahao Shen, Hui Liu, John Tressel, Yan Bao, Aiping Hui, Haijiao Xie, Shaowei Chen
Summary: The doping of Ce and Al can induce the formation of oxygen vacancies in LaCoO3 and enhance the adsorption ability of oxygen and water molecules. This doping also leads to the generation of abundant oxygen vacancies and Ce4+/Ce3+ species, fast electron transport, as well as a reduced band gap. The Ce and Al codoped LaCoO3 exhibits excellent photocatalytic antibacterial activity, with a 98.8% elimination rate of Escherichia coli compared to only 46.8% for undoped LaCoO3.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Sufeng Zhang, Ning Wei, Zijie Yao, Xinyu Zhao, Min Du, Qiusheng Zhou
Summary: In this study, ultrathin Co3O4 nanosheets with abundant oxygen vacancies were prepared through a simple two-step method and showed excellent catalytic performance for oxygen evolution reaction (OER). The nanosheets exhibited a small overpotential and fast reaction kinetics in alkaline media, making them a promising electrocatalyst.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Oncology
Liwei Lv, Yuchen Wu, Han Shi, Xuefei Sun, Zixin Deng, Hongjia Huo, Ruonan Li, Yuanbo Liu
Summary: This meta-analysis examines the effectiveness and safety of CAR-T cell therapy in the treatment of central nervous system lymphoma (CNSL). The results show that CAR-T cell therapy achieves a high short-term remission rate and controllable side effects but has a high recurrence rate after remission. Long-term follow-up data with large sample sizes are needed to further evaluate the effectiveness and safety of CAR-T cell therapy.
CANCER IMMUNOLOGY IMMUNOTHERAPY
(2023)
Article
Mechanics
Jiayin Liu, Hao Zhang, Jingyu Zhai, Qingkai Han
Summary: This paper proposes a 12-degree-of-freedom dynamic model to investigate the nonlinear dynamic behavior of the central bevel gear transmission system in an aero-engine. The effects of input power change, driven shaft speed fluctuation excitation and high-pressure rotor unbalance excitation on the complex nonlinear dynamic behavior of the system are analyzed.
MECHANICS BASED DESIGN OF STRUCTURES AND MACHINES
(2023)
Article
Radiology, Nuclear Medicine & Medical Imaging
Guanjie Yuan, Weinuo Qu, Shichao Li, Ping Liang, Kangwen He, Anqin Li, Jiali Li, Daoyu Hu, Chuou Xu, Zhen Li
Summary: Histogram analysis based on diffusion kurtosis imaging (DKI) is feasible for the noninvasive assessment of renal function and fibrosis in CKD patients.
JAPANESE JOURNAL OF RADIOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Yating Peng, Peng Wang, Jiawei Li, Jiajia Wu, Feng Lin, Dun Zhang
Summary: Underwater optical instruments are often affected by biofouling. Electrochemical chlorination is an effective antifouling strategy, but its limited activity and selectivity restrict its practical application. This study focuses on optimizing the chlorine evolution reaction (CER) performance of cobalt-based catalysts. The results show that α-Co(OH)2 exhibits better CER performance than β-Co(OH)2, and the manipulation of α-Co(OH)2 morphology further enhances the CER performance. The findings not only enhance our understanding of synthetic conditions on CER performance but also provide insights into the development of electrochemical antifouling strategies.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Na Li, Qinqin Wang, Congli He, Jiawei Li, Xiuzhen Li, Cheng Shen, Biying Huang, Jian Tang, Hua Yu, Shuopei Wang, Luojun Du, Wei Yang, Rong Yang, Dongxia Shi, Guangyu Zhang
Summary: Artificial retina implantation is an effective approach for vision recovery. However, current artificial retinas based on silicon technology are not compatible with the human biosystem. In this study, flexible photoresponsive ring oscillators (PROs) based on 2D semiconductor MoS2 were developed. These PROs efficiently produce light-intensity-dependent electrical pulses under natural light illuminations, providing a potential alternative for clinical trials due to their low power consumption and high tunability.
Article
Chemistry, Multidisciplinary
Yue Fu, Meng Yuan, Yingjie Zhao, Meiqiu Dong, Yangwu Guo, Kui Wang, Chunqi Jin, Jiangang Feng, Yuchen Wu, Lei Jiang
Summary: In this study, gradient bandgap-tunable perovskite microwire arrays with excellent crystallinity and pure crystallographic orientation were fabricated by the capillary-bridge assembly method and mild component engineering processing. The integrated color-cognitive devices achieved a spectral resolution of 14 nm ranging from 405 nm to 760 nm, responsivities over 10(3) A W-1, and detectivities over 10(15) Jones. Furthermore, the integrated flexible color-cognitive devices demonstrated accurate recognition of similar colors, which can be applied in color blindness correction. The efficient color recognition performances and flexible processing provide new opportunities for on-chip integration of wearable devices based on microwire arrays.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Instruments & Instrumentation
Jiawei Li, Jinyuan Liu, Shihua Zhou, Qiang Zhang, Nikola K. Kasabov
Summary: This paper proposes an end-to-end model based on deep learning for infrared and visible image fusion. The model utilizes residual dense blocks for feature extraction and reconstruction, and enhances texture details in the fused image through gradient loss and special weight blocks.
INFRARED PHYSICS & TECHNOLOGY
(2023)
Article
Engineering, Electrical & Electronic
Jiawei Li, Chupeng Lu, Fei Zeng, Yangrui Zhang, Song Li, Weimin Sun
Summary: The reflective-matched FBG is an interrogation method that realizes automatic temperature compensation but has a small measurement range. A range extension method has been proposed to extend the measurement range while maintaining system sensitivity. In the experiment, the system's performance with different bandwidth sensors and filters was studied, achieving a maximum strain sensitivity of 0.261 mV/mu epsilon. After range extension, the sensitivity remained at 0.248 mV/mu epsilon. The temperature compensation capability of the system was also confirmed, with temperature effects reduced to 7.8% of the uncompensated system.
OPTICAL FIBER TECHNOLOGY
(2023)
Article
Chemistry, Physical
Huanling Liu, Kai Zhang, Haipei Zou, Qingfang Mu, Yuzhi Song, Lili Lin, Yuanyuan Xu, Chuan-Kui Wang, Jianzhong Fan
Summary: This study reveals the relationship between molecular structures and luminescence properties by theoretical calculations and experimental verifications. Four promising red and near-infrared thermally activated delayed fluorescence (TADF) molecules are proposed, which exhibit fast radiative decay rates and reverse intersystem crossing (RISC) rates, as well as excellent TADF luminescence properties. These findings are of great significance for the development of red and near-infrared TADF emitters and organic light-emitting diodes (OLEDs).
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Bufu Tang, Jinyu Zhu, Yajie Wang, Weiqian Chen, Shiji Fang, Weiyang Mao, Ziwei Xu, Yang Yang, Qiaoyou Weng, Zhongwei Zhao, Minjiang Chen, Jiansong Ji
Summary: This study demonstrates that xCT-specific knockout in macrophages can limit tumor progression and metastasis by reducing TAM recruitment and infiltration, inhibiting M2-type polarization, and enhancing ferroptosis activity. It also reveals the association between macrophage ferroptosis and PD-L1 expression, leading to improved antitumor efficacy of anti-PD-L1 therapy.
Article
Telecommunications
Huimin Chen, Jiajia Liu, Jiadai Wang, Yijie Xun
Summary: Intelligent Connected Vehicle (ICV) is the goal pursued by the automotive industry, and lightweight and real-time solutions are needed to enhance its security. Intra-vehicle communication serves as the last line of defense for ICV security. It is necessary to conduct a comprehensive technical investigation on the security issues of intra-vehicle communications, understand the activities and contributions of standardization organizations, and discuss next-generation intra-vehicle communication technologies and new solutions.
VEHICULAR COMMUNICATIONS
(2023)
Article
Spectroscopy
Mingcong Gao, Jiawei Li, Lei Qiu, Xinyi Xia, Xia Cheng, Feifei Xu, Guanhong Xu, Fangdi Wei, Jing Yang, Qin Hu, Yao Cen
Summary: In this study, silicon-coated CsPbBr3 quantum dots (CsPbBr3@SiO2) were synthesized to improve their stability in ambient air. The SiO2 coating effectively protected the PQDs from water and oxygen, maintaining their structural stability. CsPbBr3@SiO2 showed excellent dispersibility in aqueous solution and remained stable for more than 2 months. It exhibited high sensitivity to pH and was successfully applied to the detection of glucose in human serum with satisfactory performance.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Computer Science, Artificial Intelligence
Xiang Shi, Yinpeng Liu, Jiawei Liu, Qikai Cheng, Wei Lu
Summary: Scientific papers are crucial for academic communication, but many of them lack in-depth research and present core content ambiguously, hindering the progression of science and technology. To address this challenge, the INTEGrity vERification (INTEGER) task is introduced to help researchers assess the integrity of their papers and verify the clarity of each knowledge unit. A multi-task learning model utilizing Tucker decomposition and span-level attention mechanism is proposed to accurately identify terms and their integrity. Experimental results show the effectiveness of the model.
EXPERT SYSTEMS WITH APPLICATIONS
(2024)
Article
Plant Sciences
Aijun Huang, Peipei Gu, Ying Wang, Jiali Li, Zhixun Yang, Long Yi
Summary: A multiplex RT-PCR assay was developed for the simultaneous detection and differentiation of four viruses infecting passion fruit. The assay showed high specificity and sensitivity, and was able to accurately detect the viruses in field samples.
TROPICAL PLANT PATHOLOGY
(2023)
Review
Chemistry, Physical
Hongyuan Xu, Zhao Kong, James Siegenthaler, Bocong Zheng, Yihong Tong, Jiawei Li, Thomas Schuelke, Qi Hua Fan, Keliang Wang, Hui Xu, Hong Jin
Summary: This paper provides a comprehensive review of the research and application of two-dimensional nanomaterials in lithium-sulfur batteries, with a focus on the advantages and challenges of materials such as graphene, MXenes, and 2D compounds.