4.8 Article

Microbial aging of hydrochar as a way to increase cadmium ion adsorption capacity: Process and mechanism

期刊

BIORESOURCE TECHNOLOGY
卷 300, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2019.122708

关键词

Sawdust hydrochar; Microbially aged process; Cadmium; Adsorption mechanisms; Biochar aging

资金

  1. National Key Research and Development Program of China [2018YFD0800206]
  2. National Natural Science Foundation of China [41877090, 31901195]
  3. Major Science and Technology Program for Water Pollution Control and Treatment [2017ZX07202004-003]
  4. Shandong Provincial Natural Science Foundation [ZR2019BD062]
  5. NSF [CBET 1739884]

向作者/读者索取更多资源

Microbially-aged hydrochar were prepared to investigate how aging affected their ability to remove Cd2+ from aqueous solutions. Based on aging time in an anaerobic fermenter, four samples were produced: HC, M20-HC, M40-HC, and M60-HC. Results indicated increases in specific surface area, pH, and negative charge on hydrochar surface with aging process. Also, there were a decrease in O/C and an increase in surface functional groups, such as -COOH. The adsorption experiments confirmed the positive correlation between aging time and adsorption performance. The 60-day-aged M60-HC treatment displayed the maximum adsorption capacity, which was 3.8 times higher than that of HC. The Langmuir and pseudo-second-order kinetic equations fitted well with isothermal and kinetic data, respectively. Thermodynamic study indicated that Cd(2+ )adsorption is dominated by chemisorption. This study showed that microbial aging process is an effective and promising measure to improve hydrochar adsorption capacity for Cd2+.

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