4.7 Article

Instantaneous trace detection of nitro-explosives and mixtures with nanotextured silicon decorated with Ag-Au alloy nanoparticles using the SERS technique

期刊

ANALYTICA CHIMICA ACTA
卷 1101, 期 -, 页码 157-168

出版社

ELSEVIER
DOI: 10.1016/j.aca.2019.12.026

关键词

Surface-enhanced Raman scattering; Femtosecond laser ablation; Ag-Au alloy NPs; Methylene blue; Explosives detection

资金

  1. DRDO, India [ERIP/ER/1501138/M/01/319/D(RD)]

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The development of recyclable surface enhanced Raman scattering (SERS) based sensors has been in huge demand for trace level explosives detection. A simple, hybrid Silicon (Si) nanotextured target-based SERS platform is fabricated through patterning micro square arrays (MSA) on Si using femtosecond (fs) laser ablation technique at different fluences. Using the hybrid target Si MSA substrate loaded/decorated with Ag-Au alloy NPs (obtained using femtosecond ablation in liquids) we demonstrate the trace level detection of organic nitro-explosives [picric acid (PA), 2,4-dinitrotoluene (DNT), and 1, 3, 5-trinitroperhydro-1, 3, 5-triazine (RDX)] and their mixtures. The microstructures/nanostructures of MSA fabricated at an input fluence of 9.55 J/cm(2), and decorated with Ag-Au alloy NPs, exhibited exceptional SERS enhancement factors (EFs) up to similar to 10(10) for MB, similar to 10(-)(6) for PA, and similar to 10(4) for RDX with the detection limits obtained being similar to 5 pM, similar to 36 nM, and similar to 400 nM for MB, PA and RDX respectively. Furthermore, we demonstrate these SERS substrates possess good reproducibility (RSD values < 15%) and a superior performance compared to a commercial Ag substrate (SERSitive, Poland). Three binary mixtures, i.e. MBPA, MB-DNT, PA-DNT at different concentrations, were also investigated using the same SERS substrate to test the efficacy. Further, the SERS spectra of dyes, explosives, and complex mixtures were utilized for discrimination/classification using principal component analysis. (C) 2019 Elsevier B.V. All rights reserved.

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