期刊
ADVANCED FUNCTIONAL MATERIALS
卷 30, 期 17, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202000484
关键词
energy; Nafion; photovoltaic; SWCNT; thin-film
类别
资金
- Deutsche Forschungsgemeinschaft (DFG) [FL 834/2-1, FL 834/2-2, FL 834/5-1, FL 834/7-1]
- China Scholarship Council
- National Natural Science Foundation of China [61804041]
- Outstanding Youth Science Foundation of Hebei province [F2019201367]
In the past, the application of carbon nanotube-silicon solar cell technology to industry has been limited by the use of a metallic frame to define an active area in the middle of a silicon wafer. Here, industry standard device geometries are fabricated with a front and back-junction design which allow for the entire wafer to be used as the active area. These are enabled by the use of an intermixed Nafion layer which simultaneously acts as a passivation, antireflective, and physical blocking layer as well as a nanotube dopant. This leads to the formation of a hybrid nanotube/Nafion passivated charge selective contact, and solar cells with active areas of 1-16 cm(2) are fabricated. Record maximum power conversion efficiencies of 15.2% and 18.9% are reported for front and back-junction devices for 1 and 3 cm(2) active areas, respectively. By placing the nanotube film on the rear of the device in a back-junction architecture, many of the design-related challenges for carbon nanotube silicon solar cells are addressed and their future applications to industrialized processes are discussed.
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