期刊
SCIENCE ADVANCES
卷 5, 期 11, 页码 -出版社
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/sciadv.aax6707
关键词
-
资金
- National Natural Science Foundation of China [91856116, 21772173]
- Natural Science Foundation of Zhejiang Province [LR18B020001]
- Fundamental Research Funds for the Central Universities [2019FZA3007]
By using click chemistry, a hexacationic cage was synthesized. The cage contains two triscationic pi-electron-deficient trispyridiniumtriazine (TPZ(3+)) platforms that are bridged in a face-to-face manner by three ethylene-triazole-ethylene linkers. A diversity of pi-electron-rich guests can be recognized within the pocket of the cage, driven by host-guest pi-pi interactions. The cage cavity acts as a protecting group, preventing an anthracene guest from undergoing Diels-Alder reaction. Under ultraviolet (UV) light, the pyridinium C-N bonds in TPZ(3+) platforms are polarized and weakened, resulting in the occurrence of cage decomposition via beta-elimination. Guest recognition could help to prevent this UV-stimulated cage decomposition by suppressing the excitation of the TPZ(3+) units.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据